Exam 19: Ionic Equilibria in Aqueous Systems

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Which one of the following is the best representation of the titration curve that will be obtained in the titration of a weak acid (0.10 mol L1) with a strong base of the same concentration? Which one of the following is the best representation of the titration curve that will be obtained in the titration of a weak acid (0.10 mol L<sup>−</sup><sup>1</sup>) with a strong base of the same concentration?

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A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH. The following data were collected during the titration. A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH. The following data were collected during the titration.   What is the K<sub>a</sub> for HClO? What is the Ka for HClO?

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Calculate the solubility of silver oxalate, Ag2C2O4, in pure water. Ksp = 1.0 × 1011

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When 20.0 mL of 0.15 M hydrochloric acid is mixed with 20.0 mL of 0.10 M sodium hydroxide, the pH of the resulting solution is

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Calculate the solubility of silver phosphate, Ag3PO4, in pure water. Ksp = 2.6 × 1018

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Write the ion product expression for calcium phosphate, Ca3(PO4)2.

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Calculate the solubility of magnesium sulfate, MgSO4, when placed into a 0.10 M MgCl2 solution. Ksp = 5.9 × 103

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At the equivalence point in an acid-base titration

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Buffer solutions with the component concentrations shown below were prepared. Which of them should have the highest pH?

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Citric acid has an acid dissociation constant of 8.4 × 104. It would be most effective for preparation of a buffer with a pH of

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Which of the following acids should be used to prepare a buffer with a pH of 4.5?

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The solubility of silver chloride __________ when dilute nitric acid is added to it.

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The equivalence point in a titration is defined as the point when the indicator changes color.

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What mass of NaF must be added to 50.0 mL of a 0.500 M HF solution to achieve a pH of 3.25? For HF, Ka = 7.2 × 104.

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Equal volumes of the following pairs of solutions are mixed. Which pair will produce a buffer solution?

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Calculate the solubility of silver chromate, Ag2CrO4, in 0.005 M Na2CrO4. Ksp = 2.6 × 1012

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What is the pH of a buffer that consists of 0.20 M NaH2PO4 and 0.40 M Na2HPO4? For NaH2PO4, Ka = 6.2 × 108

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A change in pH will significantly affect the solubility of which, if any, of the following compounds?

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Which, if any, of the following aqueous mixtures would be a buffer system?

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Assuming that the total volume does not change after 0.200 g of KCl is added to 1.0 L of a saturated aqueous solution of AgCl, calculate the number of moles of Ag+ ion in the solution after equilibrium has been reestablished. For AgCl, Ksp = 1.8 × 1010.

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