Exam 16: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions

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What is the major organic product produced by the following reaction? What is the major organic product produced by the following reaction?

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Draw the structure of the lactone product of the following reaction.Draw the structure of the lactone product of the following reaction.

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Draw the structure of polymer formed in the following reaction.Show only a single monomer.Draw the structure of polymer formed in the following reaction.Show only a single monomer.

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What is the correct assignment of the functional groups in the following compounds? What is the correct assignment of the functional groups in the following compounds?

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Instructions: Tell which spectroscopic technique you would use to distinguish between the two members of the pair.Tell what differences you would expect to see. -Identify spectroscopic technique:Instructions: Tell which spectroscopic technique you would use to distinguish between the two members of the pair.Tell what differences you would expect to see.  -Identify spectroscopic technique:

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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The product of the following reaction is a primary essence contained within bananas.The product of the following reaction is a primary essence contained within bananas.   a)Draw its structure. 	  b)The product of the above reaction could also be produced by the reaction of an acid and an alcohol. Draw their structures. a)Draw its structure. b)The product of the above reaction could also be produced by the reaction of an acid and an alcohol. Draw their structures.

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).    -Refer to instructions.The product of this reaction is: -Refer to instructions.The product of this reaction is:

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Instructions: Tell which spectroscopic technique you would use to distinguish between the two members of the pair.Tell what differences you would expect to see. -Identify spectroscopic technique:Instructions: Tell which spectroscopic technique you would use to distinguish between the two members of the pair.Tell what differences you would expect to see.  -Identify spectroscopic technique:

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Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry. -Provide missing structure(s):Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry.  -Provide missing structure(s):

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Circle any of the following structures that are not considered to be derivatives of carboxylic acids.Circle any of the following structures that are not considered to be derivatives of carboxylic acids.

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Which of the following is the correct order of decreasing acid strength of the following compounds (more acidic > less acidic)? Which of the following is the correct order of decreasing acid strength of the following compounds (more acidic > less acidic)?

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Draw the structure of polymer formed in the following reaction.Show only a single monomer.Draw the structure of polymer formed in the following reaction.Show only a single monomer.

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Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry. -Provide missing structure(s):Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry.  -Provide missing structure(s):

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Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry. -Provide missing structure(s):Instructions: Provide the missing structure(s)or reagent(s)for each reaction or sequences of reactions.Show all relevant stereochemistry.  -Provide missing structure(s):

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What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first)

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Draw the major products of the following biochemical reaction (where R = a fatty acid chain).Draw the major products of the following biochemical reaction (where R = a fatty acid chain).

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Rank the following compounds in order of increasing reactivity with a nucleophile.Rank the following compounds in order of increasing reactivity with a nucleophile.

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Which of the following is the correct order of decreasing reactivity in hydrolysis reactions (more reactive > less reactive)?

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What is the correct structure for phenylbenzoate?

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