Exam 17: Properties of Solutions
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Polyethylene is a synthetic polymer or plastic with many uses. 1.40 g of a polyethylene sample was dissolved in enough benzene to make 100. mL of solution, and the osmotic pressure was found to be 1.86 torr at 25°C. What is the molar mass of the polyethylene?
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(Multiple Choice)
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Correct Answer:
E
Calculate the freezing point when 25.0 g of ethanol, C2H5OH, is dissolved in 500.0 g of H2O.
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(Short Answer)
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Correct Answer:
Freezing point = -2.02°C
The osmotic pressure of a solution saturated with a salt M5X3 is 1.96 *10-2 atm at 25° C. Calculate Ksp for M5X3, assuming ideal behavior.
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Correct Answer:
8.6 *10-28
An aqueous solution of a compound with a molar mass of 34.02 g/mol is 25.5% by mass and has a density of 1.19 g/cm3. What is the molarity of the solution?
(Multiple Choice)
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Predict the deviation from Raoult's law when two liquids are mixed and the heat of the solution is large and the reaction endothermic.
(Multiple Choice)
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The freezing point (Tf) for t-butanol is 25.50°C, and Kf is 9.1°C/m. Usually t-butanol absorbs water on exposure to the air. If the freezing point of a 13.9-g sample of t-butanol is measured as 24.91°C, how many grams of water are present in the sample?
(Multiple Choice)
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Calculate the molarity of the solution made by dissolving 100.0 g of calcium nitrate in 450.0 mL of aqueous solution.
(Short Answer)
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At a given temperature, the vapor pressure of heptane is 92.0 torr and the vapor pressure of octane is 31.2 torr. Assuming ideal behavior, what is the vapor pressure of a solution that contains three times as many moles of octane as heptane?
(Multiple Choice)
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To calculate the freezing point of an ideal dilute solution of a single, nondissociating solute in a solvent, the minimum information one must know is
I.The molality (of the solute).
II.The molality (of the solute) and the freezing-point-depression constant of the solvent.
III.The freezing point of the pure solvent.
IV.The molecular weight of the solute.
V.The weight of the solvent.
(Multiple Choice)
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What is the molality of a solution of 39.8 g of ethanol (CH3CH2OH) in 441 mL of water if the density of water is 1.0 g/mL?
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How many milliliters of 12.4 M HNO3 are needed to prepare 360.6 mL of 0.20 M HNO3?
(Multiple Choice)
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The boiling point of pure benzene at 760. torr is 80.1°C. What is the vapor pressure of benzene over a solution containing 4.60 mol of nonvolatile hydrocarbon and 11.60 mol of benzene at 80.1°C?
(Multiple Choice)
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An aqueous solution contains 144.0 g of NaCl per liter. What is the molarity of the solution?
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Adding salt to water decreases the freezing point of the water because it lowers the vapor pressure of the ice.
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Liquid A has vapor pressure x. Liquid B has vapor pressure y, and x > y. What is the mole fraction of A in the liquid mixture if the vapor above the solution is 30% A?
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Using the data below, calculate the vapor pressure of benzene over a chloroform-benzene solution at 25°C, which contains 50.0 g of CHCl3 and 50.0 g of C6H6. Assume that the solution behaves ideally. 

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The term proof is defined as twice the percent by volume of pure ethanol in solution. Thus, a solution that is 95% (by volume) ethanol is 190 proof. What is the molarity of ethanol in a 92 proof ethanol/water solution? 

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