Deck 7: Energy,rate and Equilibrium

Question 1

Which of the following is FALSE about the energy diagram shown?

A)The activation energy is 100 kJ.
B)Point 2 on the diagram represents the activated complex.
C)This reaction is exothermic.
D)The energy of the products is lower than the energy of the reactants.
E)∆H = −50 kJ

Answer 1

The activation energy is 100 kJ.

Question 2

Which of the following statements concerning the reaction below is FALSE? 2HgO(s)→ 2Hg(l)+ O₂(g)∆H = 182 kJ

A)There is an increase in entropy in this reaction.
B)This reaction is endothermic.
C)182 kJ of energy are required for every two moles of HgO that react.
D)The energy of the reactants is greater than the energy of the products.
E)The system absorbs energy from the surroundings in this reaction.

Answer 2

The energy of the reactants is greater than the energy of the products.

Question 3

A carbohydrate sample weighing 0.235 g was found to have a fuel value of 3.84 kJ.What is the fuel value of one gram of this carbohydrate,in nutritional Calories? [1 cal = 4.18 J]

A)3,910 Cal
B)0.535 Cal
C)16.3 Cal
D)643 Cal
E)3.91 Cal

Answer 3

3.91 Cal

Question 4

Which statement concerning energy changes in chemical reactions is FALSE?

A)In an exothermic reaction,the system loses heat to the surroundings.
B)In an endothermic reaction,the system absorbs heat from the surroundings.
C)In an endothermic reaction,the reactants have a lower energy than the products.
D)In an exothermic reaction,the products have a higher energy than the reactants.
E)Exothermic reactions are characterized by a negative ∆H.

Question 5

The rate of a chemical reaction increases with an increase in concentration of one or more of the reactants.This is best explained by which of the following statements?

A)The increased concentration of the reactants increases the temperature of the molecules.
B)The increased concentration of the reactants increases the activation energy of the reaction.
C)The increased concentration of the reactants increases the speed of the molecules.
D)The increased concentration of the reactants increases the frequency of effective collisions.
E)The increased concentration of the reactants decreases the activation energy.

Question 6

The amount of heat necessary to raise 1 gram of a substance by 1 degree Celsius is known as which of the following?

A)enthalpy
B)activation energy
C)specific heat
D)heat of vaporization
E)free energy

Question 7

Which of the following is always necessary for a chemical reaction to occur between two reactants,A and B?

A)A and B must be present in the same physical state.
B)There must be equal amounts of A and B present.
C)A and B must collide with sufficient energy and the proper orientation.
D)The reaction must be carried out at room temperature.
E)The reaction must be carried out at a temperature higher than room temperature.

Question 8

What instrument is used for measuring the heat energy absorbed or released in a chemical reaction?

A)thermometer
B)calorimeter
C)thermos
D)balance
E)scale

Question 9

For the reaction shown below,Keq=2×10¹¹.Which of the following statements concerning this system at equilibrium is true? 2CO(g)+ O₂(g)⇌ 2CO₂(g)

A)The equilibrium lies to the left.
B)The equilibrium solution contains equal amounts of CO,O₂,and CO₂.
C)The reaction is very fast,due to the high value for Keq.
D)The equilibrium solution contains predominantly CO₂.
E)The equilibrium system contains almost twice as many reactant molecules as product molecules.

Question 10

The rate of a chemical reaction increases with an increase in temperature.Which of the following correctly explains why?

A)At higher temperatures,the activation energy is increased.
B)At higher temperatures,the activation energy is decreased.
C)At higher temperatures,more reactant molecules are present and collisions occur more frequently.
D)At higher temperatures,reactant molecules move faster,collide more often,and produce more effective collisions.
E)At higher temperatures,a catalyst is usually present.

Question 11

What thermodynamic quantity is the ultimate predictor of reaction spontaneity?

A)Enthalpy Change,∆H
B)Entropy Change,∆S
C)Free Energy Change,∆G
D)Entropy Change,∆S and Free Energy Change,∆G.
E)None of the choices are correct.

Question 12

Consider the decomposition of calcium carbonate shown below.Which of the following statements correctly describes this reaction as it occurs in a test tube? CaCO₃(s)+ 42.5 kcal → CaO(s)+ CO₂(g)

A)The test tube would feel warm,since the reaction would absorb heat from the surroundings.
B)The test tube would feel cold,since the reaction would absorb heat from the surroundings.
C)The test tube would feel cold,since the reaction would release heat to the surroundings.
D)The test tube would feel warm,since the reaction would release heat to the surroundings.
E)It is impossible to predict without actually performing the experiment.

Question 13

A candy sample is completely combusted in a bomb calorimeter.The calorimeter contains 982 g of water,and the measured temperature increase is 2.62°C.What is the fuel value of the candy sample in nutritional Calories? [SHw = 1.00 cal/(g•°C)]

A)2573 Cal
B)2570 Cal
C)2.57 Cal
D)0.00267 Cal
E)2.67 × 10⁻⁶ Cal

Question 14

Which statement concerning a reversible reaction at equilibrium is FALSE?

A)The concentration of the products is equal to the concentration of the reactants.
B)The forward and reverse reaction rates are equal.
C)There is no further change in the amount of reactants and products.
D)A stress to the system would cause the system to shift in the direction that best relieves the stress.
E)All of the statements are true for a reversible reaction at equilibrium.

Question 15

What is the term used to describe the energy barrier the reactants must overcome in order to form products in a chemical reaction?

A)energy of inception
B)activation energy
C)enthalpy
D)free energy
E)energy of formation

Question 16

The formation of rust (Fe₂O₃)on an exposed piece of metal typically takes several months.Which of the following statements is NOT a reasonable assumption about this chemical reaction? 4Fe(s)+ 3O₂(g)→ 2Fe₂O₃(s)

A)The reaction has a low reaction rate.
B)The reaction has low activation energy.
C)The rusting of iron would occur faster in the warmer summer months than in the cooler winter months.
D)The rusting of iron would occur slower at higher altitudes where the concentration of oxygen is lower.
E)Adding a catalyst would increase the rate of the formation of rust.

Question 17

What is the equilibrium constant expression for the reaction shown below?

A)K_eq = $\frac { [ \mathrm { MgO } ] \left[ \mathrm { CO } _ { 2 } \right] } { \left[ \mathrm { MgCO } _ { 3 } \right] }$
B)K_eq = $\frac { \left[ \mathrm { MgCO } _ { 3 } \right] } { [ \mathrm { MgO } ] \left[ \mathrm { CO } _ { 2 } \right] }$
C)K_eq = $\frac { [ \mathrm { MgO } ] + \left[ \mathrm { CO } _ { 2 } \right] } { \left[ \mathrm { MgCO } _ { 3 } \right] }$
D)K_eq = [MgO][CO₂]
E)K_eq = [CO₂]

Question 18

Which statement concerning energy changes in chemical reactions is FALSE?

A)The breaking of bonds requires energy,and the formation of bonds releases energy.
B)Activation energy is the minimum amount of energy required to initiate a chemical reaction.
C)A reaction is exothermic if the products have a lower energy than the reactants.
D)A reaction is endothermic if the reactants have a lower energy than the products.
E)The overall change in enthalpy (∆H)for a reaction is determined by the difference in energy between the products and the activated complex.

Question 19

How many small calories are equivalent to one nutritional Calorie?

A)10
B)100
C)1,000
D)10,000
E)100,000

Question 20

What is the name and symbol of the thermodynamic quantity that represents the heat absorbed or liberated in a chemical reaction at constant pressure?

A)Enthalpy Change,∆H
B)Entropy Change,∆S
C)Free Energy Change,∆G
D)Enthalpy Change,∆H and Entropy Change,∆S.
E)None of the choices are correct.

Question 21

Under normal conditions,which of the following would have the highest entropy?

A)steam
B)liquid water
C)ice
D)solid sodium chloride
E)solid iron

Question 22

Which one of the following actions can alter the activation energy of a reaction?

A)changing the temperature
B)changing the concentration of reactants
C)changing the concentration of products
D)changing the size of the reaction vessel
E)adding a catalyst

Question 23

Consider the reversible reaction: N₂(g)+ 3H₂(g)? 2NH₃(g) What is the correct expression for the equilibrium constant,Keq,for this reaction?

A) $\frac { \left[ 2 \mathrm { NH } _ { 3 } \right] } { \left[ \mathrm { N } _ { 2 } \right] \left[ 3 \mathrm { H } _ { 2 } \right] }$
B) $\frac { 2 \left[ \mathrm { NH } _ { 3 } \right] } { \left[ \mathrm { N } _ { 2 } \right] 3 \left[ \mathrm { H } _ { 2 } \right] }$
C) $\frac { \left[ \mathrm { NH } _ { 3 } \right] ^ { 2 } } { \left[ \mathrm {~N} _ { 2 } \right] \left[ \mathrm { H } _ { 2 } \right] ^ { 3 } }$
D) $\frac { \left[ \mathrm { N } _ { 2 } \right] \left[ \mathrm { H } _ { 2 } \right] ^ { 3 } } { \left[ \mathrm { NH } _ { 3 } \right] ^ { 2 } }$
E) $\frac { \left[ \mathrm { N } _ { 2 } \right] 3 \left[ \mathrm { H } _ { 2 } \right] } { 2 \left[ \mathrm { NH } _ { 3 } \right] }$

Question 24

A granola bar contains 185 nutritional Calories.How many kilojoules is this? [1 cal = 4.18 J]

A)7.74 × 10^-1 kJ
B)4.42 × 10^-2 kJ
C)442 kJ
D)773 kJ
E)1.85 × 10⁵ Kj

Question 25

Ammonia is synthesized industrially by the reaction of nitrogen and hydrogen in the presence of an iron catalyst according to the reaction equation below.What effect would removing the iron catalyst have on this reaction? 3H₂(g)+ N₂(g) $\stackrel { \mathrm { Fe } } { \longrightarrow }$ 2NH₃(g)

A)The reaction would shift to the right,producing more ammonia.
B)The reaction rate would increase.
C)The reaction would shift to the left,and consume ammonia.
D)The reaction rate would decrease.
E)There would be no effect on the reaction since Fe is not consumed in the reaction.

Question 26

In kinetics,the order of a reaction

A)is the inverse of the entropy of the system.
B)must be measured experimentally.
C)can be deduced from the balanced equation for the reaction.
D)depends on the rate constant.
E)depends on the concentrations of reactants.

Question 27

Which term describes the measure of the randomness or disorder of a chemical system?

A)energy
B)calorimetry
C)entropy
D)enthalpy
E)free energy

Question 28

Which one of the following,if changed,would change the value of the equilibrium constant,Keq,of a reaction?

A)concentration of reactants
B)concentration of the products
C)temperature
D)catalyst
E)size of reaction vessel

Question 29

One effect of a catalyst being added to a reaction mixture is

A)to increase the equilibrium constant for the reaction.
B)to slow down the rate of the reverse reaction.
C)to raise the temperature of the mixture.
D)to provide a new pathway for the reaction.
E)None of the choices are correct.

Question 30

Ethylene glycol has a specific heat of 0.578 cal/(g•°C).If 23.2 g of ethylene glycol absorbs 75.6 cal of heat energy,what will the temperature increase be?

A)0.177°C
B)1.88°C
C)5.64°C
D)1.01 × 10³°C
E)3.03 × 10³ °C

Question 31

The reaction A + 2B + C → D + 2E is first order in reactant A,first order in B,and second order in C.What is the rate law equation for this reaction?

A)rate = k[A][B][C]²
B)rate = [A][B][C]²
C)rate = [A][B][2C]
D)rate = [A][2B][C]²
E)rate = [A][B]/2[C]

Question 32

In the potential energy diagram for a chemical reaction,what is the name used for the unstable species corresponding to the top of the energy barrier separating reactants from products?

A)catalyst
B)activated complex
C)intermediate
D)free radical
E)substrate

Question 33

When a cold-pack is activated,a chemical reaction occurs and the temperature of the pack contents drops sharply.Which of the following is a correct description of the reaction occurring in the pack?

A)The reaction is exothermic; ∆H ° > 0.
B)The reaction is exothermic; ∆H ° < 0.
C)The reaction is endothermic; ∆H ° > 0.
D)The reaction is endothermic; ∆H ° < 0.
E)None of the choices are correct.

Question 34

Consider the reversible reaction: A(g)⇌ 2B(g) At equilibrium,the concentration of A is 0.381 M and that of B is 0.154 M.What is the value of the equilibrium constant,Keq?

A)0.0622
B)0.404
C)1.06
D)2.47
E)16.1

Question 35

In general,which state of matter has the lowest entropy?

A)solid
B)liquid
C)gas
D)plasma
E)supercritical fluid

Question 36

When a sample of aqueous hydrochloric acid was neutralized with aqueous sodium hydroxide in a calorimeter,the temperature of 100.0 g of water surrounding the reaction increased from 25.0°C to 31.5°C.If the specific heat of water is 1.00 cal/(g•°C),calculate the quantity of energy in calories involved in this neutralization reaction.

A)1000 cal
B)100.0 cal
C)6.50 cal
D)1250 cal
E)650 cal

Question 37

Which of the following statements concerning the reversible reaction below is FALSE? N₂O₄(g)⇌ 2NO₂(g)

A)The forward reaction produces NO₂,and the reverse reaction produces N₂O₄.
B)At the start of the reaction,the forward reaction rate is greater than the reverse reaction rate.
C)As the reaction progresses and the concentration of N₂O₄ decreases,the rate of the forward reaction decreases.
D)As the reaction progresses and the concentration of NO₂ increases,the rate of the reverse reaction increases.
E)When the reaction reaches equilibrium,the concentrations of NO₂ and N₂O₄ are equal.

Question 38

A reversible reaction is said to have reached equilibrium when which of the following conditions is established?

A)The reverse reaction begins to occur.
B)The rates of the forward and reverse reactions become equal.
C)The rate of the forward reaction diminishes to zero.
D)The concentrations of reactants and products become equal.
E)The reactants are completely consumed.

Question 39

Which of the following is the equilibrium constant expression for the reaction? 2NO(g)+ O₂(g)? 2NO₂(g)

A)K_eq = $\frac{\left[\mathrm{NO}_{2}\right]}{\left[\mathrm{NO}^{2}\left[\mathrm{O}_{2}\right]\right.}$
B)K_eq = $\frac { \left[ \mathrm { NO } _ { 2 } \right] ^ { 2 } } { \left[ \mathrm { NO } ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] \right. }$
C)K_eq = $\frac { \left[ \mathrm { NO } _ { 2 } \right] ^ { 2 } } { [ \mathrm { NO } ] ^ { 2 } + \left[ \mathrm { O } _ { 2 } \right] }$
D)K_eq = $\frac { 2 \left[ \mathrm { NO } _ { 2 } \right] } { 2 [ \mathrm { NO } ] + \left[ \mathrm { O } _ { 2 } \right] }$
E)None of the choices are correct.

Question 40

In the industrial synthesis of ammonia,the equilibrium constant expression may be written as: Calculate the value of this equilibrium constant,if the equilibrium concentration of nitrogen in the reaction mixture at 600°C if [N₂] = 4.53 M; [H₂]
= 2.49 M; and [NH₃] = 7.62 M.
K_eq = $\frac { \left[ \mathrm { NH } _ { 3 } \right] ^ { 2 } } { \left[ \mathrm {~N} _ { 2 } \right] \left[ \mathrm { H } _ { 2 } \right] ^ { 3 } }$

A)5.15
B)2.07
C)0.830
D)0.676
E)1.44

Question 41

Lowering the activation energy of a reaction will increase its rate.

Question 42

A reaction that leads to a decrease in the enthalpy of the system is always spontaneous.

Question 43

10.0 grams of octane are burned in a bomb calorimeter containing 2.00 × 10² g H₂O.If the water temperature increases from 25.00^oC to 37.00^oC,how much energy was released by the system? [SHw = 1.00 cal/(g•°C)]

A)7.40 kcal
B)3.00 × 10³ kcal
C)2.52 kcal
D)1.65 kcal
E)2.40 kcal

Question 44

A reaction that leads to an increase in the entropy of the system is always spontaneous.

Question 45

Which of the following pairs of substances has the substance with the highest entropy listed first?

A)Ni(s),Br₂(l)
B)Hg(l),He(g)
C)Br₂(l),H₂O(g)
D)Ne(g),H₂O(l)
E)Ni(s),Br₂(l)and Ne(g),H₂O(l)are correct.

Question 46

In general,a liquid state will have higher entropy than a solid state.

Question 47

A reaction that leads to a decrease in the free energy of the system is always spontaneous.

Question 48

Which of the following is a TRUE statement concerning the specific heat of a substance?

A)Specific heat is the amount of heat required to raise one gram of a substance by one degree Celsius.
B)Specific heat is 1.00 cal for all substances.
C)Specific heat is the change in the temperature of a substance as it absorbs heat.
D)Specific heat is the amount of heat required to raise one mole of a substance by ten degrees.
E)Specific heat is the heat given off in a chemical reaction.

Question 49

Which of the following represents an exothermic reaction?

A)A(g)+ B(g)→ 2C(g)∆H = +100 kcal
B)A(g)→ B(g)+ 33 kcal
C)50 kcal + 2A(g)→ C(g)+ D(s)
D)A(g)+ B(g)→ 2C(g)∆H = +100 kcal and A(g)→ B(g)+ 33 kcal are exothermic reactions.
E)A(g)+ B(g)→ 2C(g)∆H = +100 kcal and 50 kcal + 2A(g)→ C(g)+ D(s)are exothermic reactions.

Question 50

A reaction will be spontaneous at all temperatures under which conditions?

A)The reaction is endothermic and accompanied by an increase of disorder.
B)The reaction is endothermic and accompanied by a decrease in disorder.
C)The reaction is exothermic and accompanied by an increase in disorder.
D)The reaction is exothermic and accompanied by a decrease in disorder.
E)The reaction has a positive value for free energy change.

Question 51

The reaction shown below is at equilibrium.Use LeChatelier's principle to predict the effect of adding ammonia gas to the equilibrium reaction mixture. N₂(g)+ 3H₂(g)⇌ 2NH₃(g)

A)The equilibrium position will remain unchanged.
B)The equilibrium position will shift to the right.
C)The equilibrium position will shift to the left.
D)The equilibrium constant will increase.
E)All of the nitrogen gas will be used up.

Question 52

According to the second law of thermodynamics,a system and its surroundings spontaneously tend toward increasing order.

Question 53

Which of the following will NOT increase the rate of a reaction?

A)increasing the size of the reaction vessel
B)adding a catalyst
C)increasing the temperature
D)increasing the concentration of the reactants
E)All of the above will increase the rate of a reaction.

Question 54

Exothermic reactions are always spontaneous.

Question 55

Endothermic reactions are never spontaneous.

Question 56

Thermodynamics is best described as which of the following?

A)the study of the rates at which reactions take place
B)the field of chemistry that determines the mechanisms of reactions
C)the study of LeChatelier's Principle
D)the study of energy,work,and heat
E)the study of the mass relationships in chemical reactions

Question 57

For the reaction A(g)→ 2B(g),K_eq = 4.5 × 10⁵.Which statement is TRUE for the system at equilibrium?

A)[A] >> [B]
B)There is twice as much B as there is A in the reaction vessel.
C)There is more than 100 times more B than there is A in the reaction vessel.
D)There is twice as much A as there is B in the reaction vessel.
E)Changing the temperature will have no affect on the equilibrium.

Question 58

45.Which of the following is a process with a negative ∆S?

A)H₂O(l)→ H₂(s)
B)CO₂(s)→ CO₂(g)
C)CaCO₃(s)→ CaO(s)+ CO₂(g)
D)dissolving sugar in water
E)None of the choices are correct; ∆S cannot be negative.

Question 59

For the reaction 2H₂(g)+ S₂(g)⇌ 2H₂S(g),determine the equilibrium constant at 700oC if at this temperature,the equilibrium concentrations are as follows: [H2] = 0.208 M,[S2] = 1.13 × 10-6M,[H2S] = 0.725 M

A)3.22 × 10⁶
B)1.08 × 10⁷
C)3.49
D)4.55 × 10^-7
E)441

Question 60

A collision between reactant molecules that produces one or more product molecules is called an effective collision.

Question 61

Removal of a gaseous product from an equilibrium reaction mixture shifts the equilibrium toward formation of more products.

Question 62

A catalyst increases the equilibrium constant for a reaction.

Question 63

Reactants and products that are aqueous solutions do not appear in the equilibrium constant expression.

Question 64

The equilibrium constant expression for a reaction can be written if the balanced equation is known.

Question 65

LeChatelier's principle states that if a stress is placed on a system at equilibrium,the system will respond by altering the equilibrium composition in such a way as to relieve the stress.

Question 66

The order of a reaction with respect to any reactant is shown in the rate equation.

Question 67

Changing the temperature alters the value of the equilibrium constant for a reaction.