Deck 6: The Structure of Atoms
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Deck 6: The Structure of Atoms
1
According to Max Planck, at low temperatures, radiation with only relatively low frequencies is emitted, corresponding to low-energy quanta.
True
2
What is wavelength?
A) The number of horizontal troughs in a wave.
B) The number of vertical peaks in a wave.
C) The number of oscillations in a wave.
D) The distance between two points in a wave.
E) The distance travelled by a wave per unit time.
A) The number of horizontal troughs in a wave.
B) The number of vertical peaks in a wave.
C) The number of oscillations in a wave.
D) The distance between two points in a wave.
E) The distance travelled by a wave per unit time.
The distance between two points in a wave.
3
Visible light has wavelengths between _____.
700 nm to 400nm
4
Which of the following has the largest wavelength?
A) Gamma rays
B) Infrared rays
C) Ultraviolet rays
D) Microwaves
E) Radiowaves
A) Gamma rays
B) Infrared rays
C) Ultraviolet rays
D) Microwaves
E) Radiowaves
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5
Electromagnetic radiation is transmitted through space by the periodic oscillations of _____.
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6
A laser pointer emits a deep red beam with a wavelength of 670 nm. What is the frequency of the deep red beam?
A) 894 Hz
B) 8.94 × 1014 Hz
C) 448 Hz
D) 4.48 × 1014 Hz
E) 6.70 × 10-9 Hz
A) 894 Hz
B) 8.94 × 1014 Hz
C) 448 Hz
D) 4.48 × 1014 Hz
E) 6.70 × 10-9 Hz
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7
The wavelength of radiation emitted by a substance is dependant on its composition.
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8
Gamma rays have the greatest energy and wavelength among all electromagnetic radiation.
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9
All electromagnetic radiation is propagated with the same _____.
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10
The frequency of a wave is directly proportional to the speed of the wave.
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11
The wavelength of a wave is the distance between a wave crest and the adjacent trough.
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12
Blackbody radiation is the radiation emitted by a body when it is heated.
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13
_____ is the SI unit for frequency which can also be represented as s-1.
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14
If a wave has a wavelength of 3256 m and a frequency of 9.180 × 104 s−1, its velocity is _____ m/s.
A) 354.68
B) 3256
C) 2.998 × 108
D) 29980
E) 3.540 × 108
A) 354.68
B) 3256
C) 2.998 × 108
D) 29980
E) 3.540 × 108
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15
Which of the following has the highest energy?
A) Radio waves
B) Infrared rays
C) Visible light
D) Ultraviolet rays
E) X-rays
A) Radio waves
B) Infrared rays
C) Visible light
D) Ultraviolet rays
E) X-rays
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16
A wave is a periodic oscillation that transmits _____ through space.
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17
A wave belonging to the electromagnetic spectrum has a frequency of 440.0 MHz. What is its wavelength?
A) 0.6818 m
B) 2.880 m
C) 1.004 m
D) 0.006000 m
E) 1.442 m
A) 0.6818 m
B) 2.880 m
C) 1.004 m
D) 0.006000 m
E) 1.442 m
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18
Electromagnetic waves can only be transmitted in the Earth's atmosphere.
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19
Write a note on the electromagnetic radiation and the electromagnetic spectrum.
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20
All forms of electromagnetic radiation have the same speed of transmission.
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21
The unit of the Planck's constant is _____.
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22
The ground state of an electron is associated with the lowest energy.
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23
What is the smallest possible unit of energy called?
A) Photon
B) Erg
C) Quark
D) Positron
E) Quantum
A) Photon
B) Erg
C) Quark
D) Positron
E) Quantum
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24
A photon is a quantum of radiant energy possessing a particular energy.
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25
When a pure sample of an individual element is heated (as in a discharge tube), a continuous spectrum of electromagnetic radiation is emitted by the sample.
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26
Which of the following is true of the photoelectric effect?
A) The number of electrons emitted by a metallic surface is independent of the frequency of incident light.
B) The number of electrons emitted by a metallic surface is independent of the intensity of light at any frequency.
C) The number of electrons emitted by a metallic surface is directly proportional to the intensity of incident light above the threshold frequency.
D) The number of electrons emitted by a metallic surface is proportional to the frequency of incident light only below a certain light intensity.
E) The number of electrons emitted by a metallic surface is inversely proportional to the intensity and frequency of incident light.
A) The number of electrons emitted by a metallic surface is independent of the frequency of incident light.
B) The number of electrons emitted by a metallic surface is independent of the intensity of light at any frequency.
C) The number of electrons emitted by a metallic surface is directly proportional to the intensity of incident light above the threshold frequency.
D) The number of electrons emitted by a metallic surface is proportional to the frequency of incident light only below a certain light intensity.
E) The number of electrons emitted by a metallic surface is inversely proportional to the intensity and frequency of incident light.
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27
Explain Einstein's hypothesis to explain the photo electric effect.
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28
A crystal emits a light of wavelength 720.0 nm. What is the light's energy in joules of a mole photons
A) 4.164 × 1010 J/mol
B) 6.625 × 10 -34 J/mol
C) 1.661 × 105 J/mol
D) 1.507 × 1015 J/mol
E) 41.120 × 1014 J/mol
A) 4.164 × 1010 J/mol
B) 6.625 × 10 -34 J/mol
C) 1.661 × 105 J/mol
D) 1.507 × 1015 J/mol
E) 41.120 × 1014 J/mol
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29
Above the threshold frequency of a metal, the amount of electrons emitted by the metal when light is incident on it is proportional to the _____ of the light.
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30
The Pfund series of lines are due to transitions from higher-energy orbits to orbits with n = 5.
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31
To explain the line emission spectra of hydrogen in the visible region, Balmer proposed the following formula
. According to this formula for what value of n would the energy of the emitted wavelength be the greatest?
A) 3
B) 4
C) 5
D) 6
E) 7

A) 3
B) 4
C) 5
D) 6
E) 7
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32
What is the energy of a single photon emitted by a laser emitting light at 540.0 nm?
A) 3.679 × 10 -19 J
B) 6.625 × 10 -34 J
C) 4.312 × 10 -34 J
D) 1.806 × 10 -19 J
E) 5.418× 10 -19 J
A) 3.679 × 10 -19 J
B) 6.625 × 10 -34 J
C) 4.312 × 10 -34 J
D) 1.806 × 10 -19 J
E) 5.418× 10 -19 J
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33
In the emission spectrum of hydrogen the Brackett series of lines corresponds to transition of electrons from the excited states to the n1=4 orbit. What is the wavelength of the energy line n2=9 in the Brackett series?
A) 1350 nm
B) 5.50 × 105 nm
C) 1.09 nm
D) 1820 nm
E) 0.0123 m
A) 1350 nm
B) 5.50 × 105 nm
C) 1.09 nm
D) 1820 nm
E) 0.0123 m
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34
_____ is the frequency of light below which no electrons are emitted regardless of the light's intensity.
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35
According to the Niels Bohr's model of atom, the orbits of electrons are determined purely by the electrostatic forces within the atom.
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36
The _____ refers to the sharp decrease in the intensity of black body radiation emitted at shorter wavelengths.
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37
A(n) _____ is a quantum of radiant energy each with a particular energy E.
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38
Max Planck proposed that the energy of electromagnetic waves is continuous rather than quantized.
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39
Briefly explain the photoelectric effect. What is threshold frequency?
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40
To explain the line emission spectra of hydrogen in the visible region, Balmer proposed the following formula
. According to this formula, which of the following is the possible value for n?
A) 1
B) 2
C) 3
D) -1
E) -3

A) 1
B) 2
C) 3
D) -1
E) -3
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41
The minimum uncertainty in the position of a tennis ball weighting 125.0 g and traveling at a speed of 70.00 1.000 mi/h is _____.
A) 6.626
B) 9.436
C) 1.666
D) 0.5345
E) 1.310
A) 6.626
B) 9.436
C) 1.666
D) 0.5345
E) 1.310
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42
Explain the working of a laser with an example.
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43
The wavelength of a tennis ball weighing 70.0 g and travelling at a speed of 40.0 miles/hour is _____.
A) 6.63 × 1034 m
B) 1.252 × 1034 m
C) 5.29 × 10-34 m
D) 0.371 × 10-34 m
E) 9.46 × 10-34 m
A) 6.63 × 1034 m
B) 1.252 × 1034 m
C) 5.29 × 10-34 m
D) 0.371 × 10-34 m
E) 9.46 × 10-34 m
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44
Explain Bohr's model of the hydrogen atom.
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45
What is the energy of the radiation required to excite an atom from the n1=1 orbit to the n2=4 orbit?
A) 1230 kJ/mol of photon
B) 3120 kJ/mol of photon
C) 122 kJ/mol of photon
D) 656 kJ/mol of photon
E) 434 kJ/mol of photon
A) 1230 kJ/mol of photon
B) 3120 kJ/mol of photon
C) 122 kJ/mol of photon
D) 656 kJ/mol of photon
E) 434 kJ/mol of photon
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46
A(n)_____ is the point at which the amplitude of the wave is zero.
A) overtone
B) node
C) standing wave
D) fundamental point
E) still zone
A) overtone
B) node
C) standing wave
D) fundamental point
E) still zone
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47
The energy level in an atom corresponding to n=5 will have a total of 5 nodes.
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48
A(n) _____ spectrum is a spectrum produced by the emission of light by atoms in excited states.
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49
A node is the point where the amplitude of a wave is zero.
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50
What is the de Broglie wavelength of a 20,000.0 pound jet fighter traveling at 1200.0 km/hr?
A) 0.1430
B) 2.191
C) 2.191
D) 1.879
E) 1.879
A) 0.1430
B) 2.191
C) 2.191
D) 1.879
E) 1.879
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51
In the emission spectrum of hydrogen, the Balmer series of lines corresponds to transition of electrons from the excited states to the n1=1 orbit. What is the wavelength of the energy line n2=4 in the Balmer series?
A) 97.2 nm
B) 486 nm
C) 434 nm
D) 1870 nm
E) 65.6 nm
A) 97.2 nm
B) 486 nm
C) 434 nm
D) 1870 nm
E) 65.6 nm
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52
The Paschen series are due to transitions from higher-energy orbits to orbits with _____.
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53
What is the wavelength of a neutron (1.675 × 10-27 kg) that is moving at 1.400 × 10-7 m/s?
A) 3.96 × 107 m
B) 7.98 × 10-7 m
C) 2.83 m
D) 4.00 m
E) 4.50 × 10-7 m
A) 3.96 × 107 m
B) 7.98 × 10-7 m
C) 2.83 m
D) 4.00 m
E) 4.50 × 10-7 m
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54
A standing circular wave has a circumference of 2.734 units. Which of the following wavelengths would cause destructive interference of the wave?
A) 2.734 units
B) 5.468 units
C) 8.202 units
D) 12.303 units
E) 21.872 units
A) 2.734 units
B) 5.468 units
C) 8.202 units
D) 12.303 units
E) 21.872 units
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55
The _____ state is the most stable arrangement of electrons for an element or a compound.
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56
A(n) _____ is any arrangement of electrons that is higher in energy than the ground state.
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57
The minimum uncertainty in the position of a neutron travelling at a speed of 2.2 km/s ± 0.1% is _____. Given: The weight of a neutron is 1.675 * 10-27 kg.
A) 0.1430
B) 0.1430
C) 0.3106
D) 0.3106
E) 0.1430
A) 0.1430
B) 0.1430
C) 0.3106
D) 0.3106
E) 0.1430
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58
What is the energy of the radiation used to excite the hydrogen atom from an n1=2 state to an n2=5 state?
A) 656 * 10-19 J/photon
B) 9.73 * 10-19 J/photon
C) 3.97 * 10-19 J/photon
D) 8.54 * 10-19 J/photon
E) 4.58 * 10-19 J/photon
A) 656 * 10-19 J/photon
B) 9.73 * 10-19 J/photon
C) 3.97 * 10-19 J/photon
D) 8.54 * 10-19 J/photon
E) 4.58 * 10-19 J/photon
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59
A(n) _____ is a spectrum produced by the absorption of light by ground-state atoms.
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60
An overtone is the lowest-energy standing wave.
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61
If the maximum value for the Azimuthal quantum number in an atom is 5, then the principal quantum number is _____.
A) 4
B) -5
C) 0
D) -1
E) 6
A) 4
B) -5
C) 0
D) -1
E) 6
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62
What is the de Broglie wavelength of an electron traveling at a velocity of 4.53 × 106 m/s in a hydrogen atom? Given: Mass of an electron: 9.11 × 10-31 kilograms
A) 2.26 × 10-34 m
B) 9.10 × 10-31 m
C) 4.78 × 10-11 m
D) 6.74 × 10-14 m
E) 1.61 × 10-10 m
A) 2.26 × 10-34 m
B) 9.10 × 10-31 m
C) 4.78 × 10-11 m
D) 6.74 × 10-14 m
E) 1.61 × 10-10 m
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63
Quantum mechanics predicts that in the hydrogen atom, all orbitals with the same value of n (e.g., the three 2p orbitals) are degenerate, meaning:
A) that they have similar looking shapes.
B) that they are similarly oriented in space.
C) that they have the same frequency.
D) that they have the same wavelength.
E) that they have the same energy.
A) that they have similar looking shapes.
B) that they are similarly oriented in space.
C) that they have the same frequency.
D) that they have the same wavelength.
E) that they have the same energy.
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64
A wave function (Ψ) relates the location of an electron at a given point in space to the amplitude of its wave.
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65
Which of the following quantum numbers describes the orientation of the electron distribution in an atom?
A) n
B) s
C) l
D) k
E) ml
A) n
B) s
C) l
D) k
E) ml
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66
In Bohr's model of the hydrogen atom, an electron behaves like a(n) _____, a wave which does not travel through space.
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67
An electron in the outermost shell of a(n) _____ atom would experience the most amount of shielding.
A) chlorine
B) fluorine
C) iodine
D) hydrogen
E) astatine
A) chlorine
B) fluorine
C) iodine
D) hydrogen
E) astatine
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68
If the position of a particle is known absolutely, then the uncertainty in the momentum of the particle must be _____.
A) equal to its mass
B) equal to the Planck's constant
C) infinite
D) equal to the velocity of the particle
E) zero
A) equal to its mass
B) equal to the Planck's constant
C) infinite
D) equal to the velocity of the particle
E) zero
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69
Write a note on de Broglie's explanation of constructive and destructive interference.
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70
Which of the following 3d orbitals has a distinct shape?
A)
B)
C)
D)
E)
A)
B)
C)
D)
E)
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71
The azimuthal quantum number (l) gives the average relative distance of an electron from the nucleus.
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72
If the azimuthal quantum number is 0, the magnetic quantum number can be only 0.
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73
s orbitals become larger as they extend farther from the nucleus.
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74
How many orbitals are in the principal shell with n = 2?
A) 1
B) 2
C) 3
D) 4
E) 5
A) 1
B) 2
C) 3
D) 4
E) 5
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75
A(n) _____ is the point where the amplitude of a wave is zero.
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76
According to de Broglie, an electron can be described by a wave whose wavelength is given by _____.


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77
A(n) _____ is the vibration of a standing wave that is higher in energy than the fundamental vibration.
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78
The _____ is a principle that matter and energy have properties typical of both waves and particles.
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79
A 3px orbital will have the same shape, size, and energy level as the _____ orbital.
A) 2s
B) 3s
C) 3py
D) 4px
E) 4py
A) 2s
B) 3s
C) 3py
D) 4px
E) 4py
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80
Write a note on Heisenberg's uncertainty principle.
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