Deck 12: Introduction to Organic Chemistry: Hydrocarbons
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Deck 12: Introduction to Organic Chemistry: Hydrocarbons
1
Which of the following is a condensed structural formula for an alkane with four carbon atoms?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)


2
Organic chemistry is the study of the chemistry of compounds of
A)polymers.
B)oxygen.
C)hydrogen.
D)carbon.
E)living things.
A)polymers.
B)oxygen.
C)hydrogen.
D)carbon.
E)living things.
carbon.
3
How does a molecule of a vitamin synthesized in the laboratory behave when compared to the behavior of the same vitamin isolated from a natural source (e.g., vitamin C synthesized, compared to vitamin C from rose
Hips)?
A)Few effects are the same.
B)identical in every way
C)Some effects are the same.
D)usually identical
E)The natural vitamin is better.
Hips)?
A)Few effects are the same.
B)identical in every way
C)Some effects are the same.
D)usually identical
E)The natural vitamin is better.
identical in every way
4
In a molecule with a symmetrical arrangement of polar bonds, the overall molecule is
A)nonpolar.
B)reverse polar.
C)somewhat polar.
D)highly polar.
E)strongly reverse polar.
A)nonpolar.
B)reverse polar.
C)somewhat polar.
D)highly polar.
E)strongly reverse polar.
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5
Which of these formulas is an expanded structural formula for an alkane with three carbon atoms?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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6
The bond angles of tetravalent carbon are all approximately
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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7
Carbon tetrachloride has a polar C-Cl bond. What is the overall polarity of the carbon tetrachloride molecule?
A)inverse polarity
B)weakly polar
C)strongly polar
D)nonpolar
E)reversed polarity
A)inverse polarity
B)weakly polar
C)strongly polar
D)nonpolar
E)reversed polarity
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8
Generally, a solution of an organic compound in water will be electrically
A)highly conductive.
B)highly ionized.
C)insulated.
D)nonconductive.
E)charged.
A)highly conductive.
B)highly ionized.
C)insulated.
D)nonconductive.
E)charged.
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9
A molecule containing a carbon atom bonded to four chlorine atoms has the shape of a
A)square.
B)rhombus.
C)tetrahedron.
D)cube.
E)triangle.
A)square.
B)rhombus.
C)tetrahedron.
D)cube.
E)triangle.
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10
As carbon bonds with atoms of increasingly higher electronegativities, the polarity of the bond
A)decreases.
B)reverses.
C)becomes inverted.
D)increases.
E)stays the same.
A)decreases.
B)reverses.
C)becomes inverted.
D)increases.
E)stays the same.
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11
In a condensed structural formula, each carbon atom is
A)shown with all individual atoms and bonds drawn.
B)not explicitly shown.
C)shown with only the other carbon atoms.
D)written in lowercase letters.
E)grouped with its bonded hydrogen atoms.
A)shown with all individual atoms and bonds drawn.
B)not explicitly shown.
C)shown with only the other carbon atoms.
D)written in lowercase letters.
E)grouped with its bonded hydrogen atoms.
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12
How many valence electrons does carbon have?
A)one
B)two
C)three
D)four
E)five
A)one
B)two
C)three
D)four
E)five
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13
VSEPR theory predicts that simple carbon compounds will form bonds that are
A)pointed to the corners of a triangle.
B)as far apart as possible.
C)as close together as possible.
D)arranged in a straight line.
E)pointed to the corners of a cube.
A)pointed to the corners of a triangle.
B)as far apart as possible.
C)as close together as possible.
D)arranged in a straight line.
E)pointed to the corners of a cube.
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14
Which one of the following is NOT an organic substance?
A)nylon
B)silk
C)salt, sodium chloride
D)coal
E)an antibiotic
A)nylon
B)silk
C)salt, sodium chloride
D)coal
E)an antibiotic
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15
Which of the following is NOT typical of most organic compounds?
A)high melting point
B)covalent bonding
C)poor solubility in water
D)high flammability
E)low boiling point
A)high melting point
B)covalent bonding
C)poor solubility in water
D)high flammability
E)low boiling point
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16
A formula that shows the arrangement of all bonds in a molecule is called a(n)
A)isomeric formula.
B)condensed structural formula.
C)molecular formula.
D)condensed molecular formula.
E)expanded structural formula.
A)isomeric formula.
B)condensed structural formula.
C)molecular formula.
D)condensed molecular formula.
E)expanded structural formula.
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17
A hydrocarbon contains only the elements
A)carbon and oxygen.
B)carbon, hydrogen, and oxygen.
C)hydrogen and oxygen.
D)carbon and hydrogen.
E)carbon, hydrogen, and nitrogen.
A)carbon and oxygen.
B)carbon, hydrogen, and oxygen.
C)hydrogen and oxygen.
D)carbon and hydrogen.
E)carbon, hydrogen, and nitrogen.
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18
Carbon atoms always have how many covalent bonds?
A)one
B)two
C)three
D)four
E)five
A)one
B)two
C)three
D)four
E)five
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19
In the three-dimensional structure of methane,
the hydrogen atoms attached to a carbon atom are aligned
A) at the corners of a rectangle.
B) in a straight line.
C) at the corners of a cube.
D) at the corners of a square.
E) at the corners of a tetrahedron.

A) at the corners of a rectangle.
B) in a straight line.
C) at the corners of a cube.
D) at the corners of a square.
E) at the corners of a tetrahedron.
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20
An organic compound composed of carbon and hydrogen connected only by single bonds is an
A)alkene.
B)alkyne.
C)alcohol.
D)alkane.
E)aromatic compound.
A)alkene.
B)alkyne.
C)alcohol.
D)alkane.
E)aromatic compound.
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21
What is the IUPAC name of this compound?

A) ethane
B) propane
C) pentane
D) hexane
E) butane

A) ethane
B) propane
C) pentane
D) hexane
E) butane
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22
What is the IUPAC name of this compound? 
A)cyclopentane
B)hexane
C)cyclohexane
D)cycloheptane
E)cyclooctane

A)cyclopentane
B)hexane
C)cyclohexane
D)cycloheptane
E)cyclooctane
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23
What is the IUPAC name for a nine-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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24

A)4-methylhexane
B)3-methylhexane
C)2-methylhexane
D)methylhexane
E)heptane
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25

A)methanechlorine.
B)chloromethane.
C)methane chloride.
D)methyl chloride.
E)chloroethane.
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26
What is the IUPAC name for a four-carbon continuous-chain alkane?
A)ethane
B)propane
C)pentane
D)butane
E)methane
A)ethane
B)propane
C)pentane
D)butane
E)methane
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27
What is the IUPAC name for a six-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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28
What is the IUPAC name for the following? 
A)2-chlorobutane
B)3-chlorobutane
C)chlorobutane
D)2-chloropropane
E)1-chlorobutane

A)2-chlorobutane
B)3-chlorobutane
C)chlorobutane
D)2-chloropropane
E)1-chlorobutane
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29
What is the IUPAC name for a five-carbon continuous-chain alkane?
A)ethane
B)propane
C)pentane
D)methane
E)butane
A)ethane
B)propane
C)pentane
D)methane
E)butane
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30
What is the IUPAC name of this compound? 
A)octane
B)heptane
C)hexane
D)methylbutane
E)pentane

A)octane
B)heptane
C)hexane
D)methylbutane
E)pentane
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31
Which of the following pairs of compounds are structural isomers?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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32
What is 
A)pentane
B)propane
C)ethane
D)butane
E)hexane

A)pentane
B)propane
C)ethane
D)butane
E)hexane
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33
What is the IUPAC name for 
A) propane dichloride
B) 1,3-dichlorobutane
C) 1,1-dichloropropane
D) dichloropropane
E) 1,3 -dichloropropane

A) propane dichloride
B) 1,3-dichlorobutane
C) 1,1-dichloropropane
D) dichloropropane
E) 1,3 -dichloropropane
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34
What is the IUPAC name of this compound? 
A)octane
B)heptane
C)butane
D)hexane
E)pentane

A)octane
B)heptane
C)butane
D)hexane
E)pentane
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35
What is the IUPAC name for a ten-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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36

A)butane
B)1-methylbutane
C)4-methylbutane
D)hexane
E)pentane
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37
What is the IUPAC name for a seven-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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38
What is the IUPAC name of the continuous chain alkane with six carbon atoms?
A)hexane
B)octane
C)heptane
D)butane
E)pentane
A)hexane
B)octane
C)heptane
D)butane
E)pentane
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39
What is the IUPAC name for an eight-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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40
What is the IUPAC name of this compound? 
A)cyclohexane
B)cyclopentane
C)pentane
D)cycloheptane
E)cyclooctane

A)cyclohexane
B)cyclopentane
C)pentane
D)cycloheptane
E)cyclooctane
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41
In the equation for the combustion of pentane, the coefficient of carbon dioxide is
A)one
B)two.
C)three.
D)four.
E)five.
A)one
B)two.
C)three.
D)four.
E)five.
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42
Which of the following is true of nonane,
which has a density of 0.79 g/mL , melts at
and boils at 
A)Nonane is soluble in water.
B)Nonane does not undergo combustion.
C)Nonane is a solid at room temperature.
D)Nonane is a gas at room temperature.
E)Nonane floats on the surface of water.



A)Nonane is soluble in water.
B)Nonane does not undergo combustion.
C)Nonane is a solid at room temperature.
D)Nonane is a gas at room temperature.
E)Nonane floats on the surface of water.
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43
What is the IUPAC name for this alkane? 
A)2, 3-diethylbutane
B)2-ethyl-3-methylpentane
C)4-ethyl-3-methylpentane
D)octane
E)3, 4-dimethylhexane

A)2, 3-diethylbutane
B)2-ethyl-3-methylpentane
C)4-ethyl-3-methylpentane
D)octane
E)3, 4-dimethylhexane
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44
What is the name of this compound? 
A)1,3-dichlorobutane
B)1,1-dichlorobutane
C)1,4-dichlorobutane
D)1,2,-dichlorobutane
E)dichlorobutane

A)1,3-dichlorobutane
B)1,1-dichlorobutane
C)1,4-dichlorobutane
D)1,2,-dichlorobutane
E)dichlorobutane
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45
The reaction for the combustion of heptane is
How many liters of
at STP are produced from the complete combustion of 2.00 moles of heptane?
A) 44.8 L
B) 246 L
C) 22.4 L
D) 314 L
E) 157 L


A) 44.8 L
B) 246 L
C) 22.4 L
D) 314 L
E) 157 L
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46
When drawing a structural formula, the first step is to draw
A)the substituents.
B)the main carbon chain.
C)the functional group.
D)the saturated carbons.
E)the most highly substituted carbons.
A)the substituents.
B)the main carbon chain.
C)the functional group.
D)the saturated carbons.
E)the most highly substituted carbons.
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47
Which of the following compounds could have the molecular formula C7H16?
A)pentane
B)hexane
C)2-methylheptane
D)3-ethylhexane
E)2,3-dimethylpentane
A)pentane
B)hexane
C)2-methylheptane
D)3-ethylhexane
E)2,3-dimethylpentane
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48
According to the IUPAC convention, alkyl group names should be located ________ of the name of the main chain.
A)at the end
B)in front
C)in the middle
A)at the end
B)in front
C)in the middle
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49
What is the IUPAC name for the following? 
A)2,3-dichloro-1-methylcyclopentane
B)2,3-dichloro-1-methylpentane
C)1,2-dichloro-3-methylcyclobutane
D)3-methyl-1,2-dichlorocyclopentane
E)1-methyl-2,3-dichlorocyclopentane

A)2,3-dichloro-1-methylcyclopentane
B)2,3-dichloro-1-methylpentane
C)1,2-dichloro-3-methylcyclobutane
D)3-methyl-1,2-dichlorocyclopentane
E)1-methyl-2,3-dichlorocyclopentane
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50
What is the IUPAC name for this three-carbon alkyl group? 
A)iso-propyl
B)ethyl
C)butyl
D)iso-butyl
E)n-propyl

A)iso-propyl
B)ethyl
C)butyl
D)iso-butyl
E)n-propyl
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51
What is the name for the following? 
A)pentane
B)4-methylpentane
C)2-methylpentane
D)methylpentane
E)hexane

A)pentane
B)4-methylpentane
C)2-methylpentane
D)methylpentane
E)hexane
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52
What is the IUPAC name of this alkane? 
A)2-ethyl-4,4-dimethylpentane
B)4-ethyl-2,2-dimethylpentane
C)3,5,5-trimethylhexane
D)2-ethyl-2,2-dimethylpentane
E)2,2,4-trimethylhexane

A)2-ethyl-4,4-dimethylpentane
B)4-ethyl-2,2-dimethylpentane
C)3,5,5-trimethylhexane
D)2-ethyl-2,2-dimethylpentane
E)2,2,4-trimethylhexane
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53
According to the IUPAC convention for chemical naming, which part of a hydrocarbon is selected as the main chain for a hydrocarbon chain?
A)the chain with the most substituted carbons in it
B)the most highly branched chain
C)the longest chain drawn in a straight line
D)the shortest chain
E)the longest continuous chain, regardless of bends
A)the chain with the most substituted carbons in it
B)the most highly branched chain
C)the longest chain drawn in a straight line
D)the shortest chain
E)the longest continuous chain, regardless of bends
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54
What is the IUPAC name for a three-carbon alkyl group?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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55
Organic compounds that are poorly soluble in water behave that way because they are
A)covalently bonded.
B)generally nonpolar.
C)moderately polar.
D)highly polar.
E)ionically bonded.
A)covalently bonded.
B)generally nonpolar.
C)moderately polar.
D)highly polar.
E)ionically bonded.
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56
What is the IUPAC name for a two-carbon alkyl group?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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57
What is the name of the alkyl group 
A) ethane
B) ethyl
C) propane
D) methyl
E) propyl

A) ethane
B) ethyl
C) propane
D) methyl
E) propyl
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58
According to the IUPAC convention, alkyl substituents on a hydrocarbon chain should be listed in which order?
A)in order with the substituent having the lowest number of carbons first
B)alphabetical without considering prefixes
C)in order with the substituent having the highest total number of carbons first
D)alphabetical including prefixes
E)in order with the substituent having the highest number of carbons first
A)in order with the substituent having the lowest number of carbons first
B)alphabetical without considering prefixes
C)in order with the substituent having the highest total number of carbons first
D)alphabetical including prefixes
E)in order with the substituent having the highest number of carbons first
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59
What is the IUPAC name for a one-carbon alkyl substituent?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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60
What is the name for the following? 
A)dimethylbutane
B)hexane
C)2-dimethylbutane
D)2,2-dimethylbutane
E)3,3-dimethylbutane

A)dimethylbutane
B)hexane
C)2-dimethylbutane
D)2,2-dimethylbutane
E)3,3-dimethylbutane
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61
A hydrocarbon with at least one double bond is a(n)
A)alcohol.
B)alkyne.
C)saturated compound.
D)alkene.
E)alkane.
A)alcohol.
B)alkyne.
C)saturated compound.
D)alkene.
E)alkane.
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62
The IUPAC name for ethylene is
A)ethanene.
B)ethane.
C)cycloethane.
D)ethene.
E)ethyne.
A)ethanene.
B)ethane.
C)cycloethane.
D)ethene.
E)ethyne.
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63
The IUPAC name for
is
A) pentyne.
B) 3 -pentyne.
C) 1-methylbutyne.
D) 2-pentyne.
E) 2-propene.

A) pentyne.
B) 3 -pentyne.
C) 1-methylbutyne.
D) 2-pentyne.
E) 2-propene.
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64
What type of compound is 
A) branched alkane
B) haloalkane
C) isomer
D) alkane
E) cycloalkane

A) branched alkane
B) haloalkane
C) isomer
D) alkane
E) cycloalkane
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65
What is the condensed structural formula for the compound 3-hexene?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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66
Which of the following is a property of nonane,
which has a density of 0.79 g/mL, melts at
and boils at 
A) Nonane does not undergo combustion.
B) Nonane solutions conduct electricity.
C) Nonane is not soluble in water.
D) Nonane is a gas at room temperature.
E) Nonane sinks in water.



A) Nonane does not undergo combustion.
B) Nonane solutions conduct electricity.
C) Nonane is not soluble in water.
D) Nonane is a gas at room temperature.
E) Nonane sinks in water.
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67
Which of the following compounds is an alkyne?
A)
B)
C) 2 -pentene
D)
E)
A)

B)

C) 2 -pentene
D)

E)

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68
The reaction of butane with oxygen is called
A)substitution.
B)combustion.
C)addition.
D)neutralization.
E)titration.
A)substitution.
B)combustion.
C)addition.
D)neutralization.
E)titration.
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69
The carbon atoms in saturated hydrocarbons
A)contain a benzene ring.
B)contain both a double and a triple bond.
C)contain at least one triple bond.
D)have only single bonds.
E)contain at least one double bond.
A)contain a benzene ring.
B)contain both a double and a triple bond.
C)contain at least one triple bond.
D)have only single bonds.
E)contain at least one double bond.
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70
An alkene is a hydrocarbon that contains at least one ________ bond.
A)triple
B)aromatic
C)single
D)double
E)hydrogen
A)triple
B)aromatic
C)single
D)double
E)hydrogen
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71
The compound 1-butyne contains
A)a ring structure.
B)all single bonds.
C)a triple bond.
D)a double bond.
E)a bromine atom.
A)a ring structure.
B)all single bonds.
C)a triple bond.
D)a double bond.
E)a bromine atom.
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72
Hydrocarbons are the primary constituents of
A)drugs.
B)food flavors.
C)gasoline.
D)disinfectants.
E)fruit juices.
A)drugs.
B)food flavors.
C)gasoline.
D)disinfectants.
E)fruit juices.
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73
The IUPAC name of
is
A) 1-butene.
B) 2-butyne.
C) 2-butene.
D) butene.
E) 2-butane.

A) 1-butene.
B) 2-butyne.
C) 2-butene.
D) butene.
E) 2-butane.
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74
Which of the compounds is a cycloalkene?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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75
What is the condensed structural formula of the compound propene?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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76
When naming an alkene, the parent chain is the longest carbon chain
A)that contains at least one of the carbon atoms of the double bond.
B)that does not contain the double bond.
C)regardless of whether or not it contains the double bond.
D)that contains the double bond.
E)that contains a branch.
A)that contains at least one of the carbon atoms of the double bond.
B)that does not contain the double bond.
C)regardless of whether or not it contains the double bond.
D)that contains the double bond.
E)that contains a branch.
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77
The balanced equation for the complete combustion of
will give which of these product(s)?
A)
B)
C)
D)
E) 10CO + 12H2O

A)

B)

C)

D)

E) 10CO + 12H2O
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78
An unsaturated compound always
A)is a cycloalkane.
B)contains a double bond.
C)contains at least one double or triple bond.
D)contains a triple bond.
E)is aromatic.
A)is a cycloalkane.
B)contains a double bond.
C)contains at least one double or triple bond.
D)contains a triple bond.
E)is aromatic.
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79
What is(are) the product(s) of the complete combustion of any hydrocarbon?
A) CO only
B)
C)
D)
E)
A) CO only
B)

C)

D)

E)

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80
An alkyne is a hydrocarbon that contains at least one________ bond.
A)triple
B)aromatic
C)hydrogen
D)single
E)double
A)triple
B)aromatic
C)hydrogen
D)single
E)double
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