Deck 8: Molecules and Materials
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Deck 8: Molecules and Materials
1
Nonmetals have large band gaps and do not conduct electricity.
True
2
Sodium chloride is an excellent example of a( n)_____.
A)amorphous solid
B)crystalline solid
C)covalent network
D)metallic solid
A)amorphous solid
B)crystalline solid
C)covalent network
D)metallic solid
crystalline solid
3
A substance that solidifies into a random molecular arrangement is referred to as an amorphous solid.
True
4
A phase diagram provides detailed kinetics data on how fast a chemical reaction proceeds.
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5
Which of the following substances is an excellent conductor of electricity ?
A)Zinc
B)Silicon
C)Oxygen
D)Iodine
A)Zinc
B)Silicon
C)Oxygen
D)Iodine
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6
How many "equivalent" atoms belong to a single face-centered cubic unit cell?
A)1
B)2
C)3
D)4
A)1
B)2
C)3
D)4
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7
_____ is the unoccupied band above the valence band .
A)Pauling's band
B)The conduction band
C)The induction band
D)The passive motion band
A)Pauling's band
B)The conduction band
C)The induction band
D)The passive motion band
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8
Polymerization involves the linkage of several monomer units.
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9
If iridium has a density of 23.3 g\cm3and forms a face-centered cubic lattice, what is the atomic radius of the iridium atom?
A)135.7 pm
B)203.7 pm
C)271.4 pm
D)648.0 pm
A)135.7 pm
B)203.7 pm
C)271.4 pm
D)648.0 pm
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10
If the orbitals of two atoms overlap and interact with constructive interference, the resulting wave, which will have increased amplitude (or electron density)between the nuclei, is referred to as a( n)_____.
A)bonding molecular orbital
B)antibonding molecular orbital
C)free radical formation
D)cation formation
A)bonding molecular orbital
B)antibonding molecular orbital
C)free radical formation
D)cation formation
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11
To measure the vapor pressure of a liquid or a solid requires that the system reach equilibrium.
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12
Condensation polymers are made using a monomer with two functional groups that split off as the remainder of the two monomers are joined together. Often the small molecule eliminated in the process is water.
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13
The essential feature of the sea of electrons model is that the valence electrons of metal atoms do not move freely and are tied to specific atoms.
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14
If silver atoms follow a face-centered cubic unit cell pattern, what is the length of this unit cell if the atomic radius is 144.4 pm?
A)144 pm
B)179 pm
C)408 pm
D)635 pm
A)144 pm
B)179 pm
C)408 pm
D)635 pm
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15
In the context of dispersion forces, large molecules tend to be less polarizable than small ones.
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16
The ability to pull a metallic solid into a wire is called the metal's _____.
A)mobility
B)ductility
C)malleability
D)conductivity
A)mobility
B)ductility
C)malleability
D)conductivity
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17
The manufacturing of semiconductors involves doping pure semiconductors, such as silicon or germanium, with controlled trace amounts of another element.
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18
How many "equivalent" atoms belong to a single body-centered cubic unit cell?
A)1
B)2
C)3
D)4
A)1
B)2
C)3
D)4
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19
Metals are _____, meaning they can be formed into useful shapes or foils .
A)brittle
B)ductile
C)malleable
D)conductors
A)brittle
B)ductile
C)malleable
D)conductors
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20
Additives such as plasticizers are often employed to improve the flexibility of polymers.
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21
In which of the following molecules are you likely to observe hydrogen bonding?
A)NaF
B)C2H4F2
C)Na2O
D)HF
A)NaF
B)C2H4F2
C)Na2O
D)HF
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22
Which pair of atoms is most likely to be involved in hydrogen bonding ?
A)H and F
B)Al and H
C)H and K
D)Na and H
A)H and F
B)Al and H
C)H and K
D)Na and H
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23
Which substance has the lowest vapor pressure ?
A)CClF 3
B)propane (C3H8)
C)ethane (C2H6)
D)HCN
A)CClF 3
B)propane (C3H8)
C)ethane (C2H6)
D)HCN
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24
Many current micro-electrical-mechanical systems (MEMS)devices begin with _____ as their primary component .
A)hydrogen
B)silicon
C)carbon
D)sodium
A)hydrogen
B)silicon
C)carbon
D)sodium
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25
Band gaps tend to be smallest for _____.
A)conductors
B)semiconductors
C)insulators
D)modulators
A)conductors
B)semiconductors
C)insulators
D)modulators
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26
The sea of electrons model provides a quantitative understanding of metallic bonds .
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27
When a liquid reaches a temperature at which its vapor pressure is equal to one atmosphere, the liquid has reached its _____.
A)melting point
B)normal boiling point
C)sublimation point
D)evaporation point
A)melting point
B)normal boiling point
C)sublimation point
D)evaporation point
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28
The packing efficiency of a body-centered cubic structure is more than a face-centered cubic structure .
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29
Which of the following substances has the highest boiling point?
A)C8H18
B)Kr
C)CH2Cl2
D)H2O
A)C8H18
B)Kr
C)CH2Cl2
D)H2O
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30
Doping pure silicon with gallium results in a(n)_____ material .
A)p-type
B)n-type
C)s-type
D)d-type
A)p-type
B)n-type
C)s-type
D)d-type
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31
In the molecular structure of propylene, if the methyl groups all point forward or backward, a(n)_____ is produced .
A)copolymer
B)atactic polymer
C)syndiotactic polymer
D)isostatic polymer
A)copolymer
B)atactic polymer
C)syndiotactic polymer
D)isostatic polymer
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32
In the context of band theory and conductivity, semiconductors have a larger band gap than insulators .
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33
The material etched during the creation of a micro-electrical-mechanical system device is referred to as the _____.
A)substrate
B)counter layer
C)mask
D)retardant
A)substrate
B)counter layer
C)mask
D)retardant
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34
A p-type material can be made if pure germanium is doped with _____.
A)gallium
B)carbon
C)arsenic
D)silicon
A)gallium
B)carbon
C)arsenic
D)silicon
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35
_____ involve side chains of one polymer attached to a backbone of a different polymer .
A)Alternating copolymers
B)Block copolymers
C)Graft copolymers
D)Random copolymers
A)Alternating copolymers
B)Block copolymers
C)Graft copolymers
D)Random copolymers
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36
_____ is a polymer that can maintain its shape and strength when heated .
A)Polylactide
B)A thermosetting polymer
C)A thermoplastic polymer
D)Acrylonitrile butadiene styrene
A)Polylactide
B)A thermosetting polymer
C)A thermoplastic polymer
D)Acrylonitrile butadiene styrene
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37
Which of the followings statements is true of dipole-dipole interactions ?
A)They are based on transient dipoles.
B)They are stronger than dispersion forces.
C)They are also referred to as instantaneous dipole-induced dipole forces.
D)They are also referred to as London forces.
A)They are based on transient dipoles.
B)They are stronger than dispersion forces.
C)They are also referred to as instantaneous dipole-induced dipole forces.
D)They are also referred to as London forces.
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38
A p-type semiconductor can be formed if silicon is doped with an element that:
A) has more valence electrons than silicon.
B) has fewer valence electrons than silicon.
C) belongs to group 14 of the modern periodic table.
D) belongs to group 15 of the modern periodic table.
A) has more valence electrons than silicon.
B) has fewer valence electrons than silicon.
C) belongs to group 14 of the modern periodic table.
D) belongs to group 15 of the modern periodic table.
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39
Which of these materials provides an example of an ionic crystalline solid?
A)SrCl2
B)C
C)SiC
D)C60
A)SrCl2
B)C
C)SiC
D)C60
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40
An addition polymerization must begin with the formation of a(n)_____.
A)free radical
B)electron pair
C)plasticizer
D)anion resin
A)free radical
B)electron pair
C)plasticizer
D)anion resin
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41
An n-type semiconductor can be formed if silicon is doped with an element that :
A)has more valence electrons than silicon.
B)has fewer valence electrons than silicon.
C)belongs to group 14 of the modern periodic table.
D)belongs to group 13 of the modern periodic table.
A)has more valence electrons than silicon.
B)has fewer valence electrons than silicon.
C)belongs to group 14 of the modern periodic table.
D)belongs to group 13 of the modern periodic table.
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42
Which of the following is the strongest of all intermolecular reactions ?
A)Dispersion forces
B)London forces
C)Dipole-Dipole interactions
D)Hydrogen bonding
A)Dispersion forces
B)London forces
C)Dipole-Dipole interactions
D)Hydrogen bonding
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