Deck 23: Organic Compounds, Polymers, and Biochemicals
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Deck 23: Organic Compounds, Polymers, and Biochemicals
1
How many isomers are there of butane, C4H10?
A)1 (no isomers)
B)2
C)3
D)4
E)5
A)1 (no isomers)
B)2
C)3
D)4
E)5
2
2
How many isomers are there of propane, C3H8?
A)1 (no isomers)
B)2
C)3
D)4
E)5
A)1 (no isomers)
B)2
C)3
D)4
E)5
1 (no isomers)
3
How many isomers are there of pentane, C5H12?
A)1 (no isomers)
B)2
C)3
D)4
E)5
A)1 (no isomers)
B)2
C)3
D)4
E)5
3
4
CH3-CH2-O-H and CH3-O-CH3 are a pair of compounds that are
A)allotropes.
B)allomers.
C)isochrones.
D)isomers.
E)allotones.
A)allotropes.
B)allomers.
C)isochrones.
D)isomers.
E)allotones.
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5
CH3-CH2-NH2 and CH3-NH-CH3 are a pair of compounds that are
A)allotropes.
B)allomers.
C)isochrones.
D)isomers.
E)allotones.
A)allotropes.
B)allomers.
C)isochrones.
D)isomers.
E)allotones.
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6
The functional group, -O-H, is found in which one of these types of organic compounds?
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
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7
The functional group, -NH2, is found in which one of these types of organic compounds?
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
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8
The functional group, R-O-R, is found in which one of these types of organic compounds?
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
A)alkanes
B)alkenes
C)amines
D)alcohols
E)ethers
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9
Draw a structural formula for cyclohexane, a cyclic saturated hydrocarbon (C6H12). How many ?-bonds are in cyclohexane?
A)12
B)16
C)17
D)18
E)20
A)12
B)16
C)17
D)18
E)20
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10
Draw a structural formula for cyclohexane, a cyclic saturated hydrocarbon (C6H12). How many ?-bonds are in a cyclohexane molecule?
A)0
B)2
C)3
D)4
E)6
A)0
B)2
C)3
D)4
E)6
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11
How many isomers are there of propene,
?
A)1 (no isomers)
B)2
C)3
D)4
E)5

A)1 (no isomers)
B)2
C)3
D)4
E)5
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12
A saturated 8-carbon straight chain hydrocarbon would have how many hydrogens?
A)8
B)10
C)16
D)18
E)24
A)8
B)10
C)16
D)18
E)24
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13
Butene, C4H8, is a hydrocarbon with one double bond. How many isomers are there of butane?
A)1 (no isomers)
B)2
C)3
D)4
E)5
A)1 (no isomers)
B)2
C)3
D)4
E)5
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14
Which compound is butane?
A)CH3CH3
B)CH3CH2CH3
C)CH3CH2CH2CH3
D)CH3CH2CH2CH2CH3
E)CH3CH2CH2CH2CH2CH3
A)CH3CH3
B)CH3CH2CH3
C)CH3CH2CH2CH3
D)CH3CH2CH2CH2CH3
E)CH3CH2CH2CH2CH2CH3
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15
Which compound is pentane?
A)CH3CH3
B)CH3CH2CH3
C)CH3CH2CH2CH3
D)CH3CH2CH2CH2CH3
E)CH3CH2CH2CH2CH2CH3
A)CH3CH3
B)CH3CH2CH3
C)CH3CH2CH2CH3
D)CH3CH2CH2CH2CH3
E)CH3CH2CH2CH2CH2CH3
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16
Which compound is a butene?
A)
B)
C)CH3-CH2-CH2-CH3
D)CH3-CH2-CH3
E)
A)

B)

C)CH3-CH2-CH2-CH3
D)CH3-CH2-CH3
E)

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17
Which compound is pentane?
A)CH3-CH2-CH2-CH3
B)
C)
D)CH3-CH2-CH2-CH2-CH3
E)CH3-CH2-CH2-CH2-CH2-CH3
A)CH3-CH2-CH2-CH3
B)

C)

D)CH3-CH2-CH2-CH2-CH3
E)CH3-CH2-CH2-CH2-CH2-CH3
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18
Which one of the groups below goes by the name propyl?
A)CH3-CH2-
B)CH2-CH-
C)CH3-CH2-CH2-
D)CH2-CH-CH2-
E)CH3-CH-CH-
A)CH3-CH2-
B)CH2-CH-
C)CH3-CH2-CH2-
D)CH2-CH-CH2-
E)CH3-CH-CH-
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19
The alkyl group, -CH3, where the open bond shows where it attaches to a larger carbon chain, is named
A)methide
B)methonium
C)methal
D)methyl
E)trihydrogencarbide
A)methide
B)methonium
C)methal
D)methyl
E)trihydrogencarbide
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20
The alkyl group shown below, where the open bond shows where it attaches to a larger carbon chain, is named 
A)propyl
B)propide
C)propanium
D)isopropyl
E)propanyl

A)propyl
B)propide
C)propanium
D)isopropyl
E)propanyl
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21
Which compound is not an unsaturated compound?
A)
B)
C)
D)CH3-CH2-O-H
E)
A)

B)

C)

D)CH3-CH2-O-H
E)

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22
Which compound is not an unsaturated compound?
A)
B)
C)
D)
E)CH3-CH2-NH2
A)

B)

C)

D)

E)CH3-CH2-NH2
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23
Which of the following is true about the benzene molecule?
A)It is a straight chain hydrocarbon.
B)It contains a heterocyclic oxygen.
C)It is a saturated hydrocarbon.
D)The double bonds in its ring have resonance and their electrons are delocalized.
E)Attachments to the ring can exhibit cis/trans isomerism.
A)It is a straight chain hydrocarbon.
B)It contains a heterocyclic oxygen.
C)It is a saturated hydrocarbon.
D)The double bonds in its ring have resonance and their electrons are delocalized.
E)Attachments to the ring can exhibit cis/trans isomerism.
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24
In the IUPAC system of nomenclature, the alkane hydrocarbon whose skeleton is shown below, is regarded as a derivative of 
A)butane.
B)hexane.
C)heptane.
D)octane.
E)pentane.

A)butane.
B)hexane.
C)heptane.
D)octane.
E)pentane.
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25
In the IUPAC system of nomenclature, the alkane hydrocarbon whose skeleton is shown below, is regarded as a derivative of 
A)dodecane.
B)decane.
C)heptane.
D)pentane.
E)octane.

A)dodecane.
B)decane.
C)heptane.
D)pentane.
E)octane.
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26
The IUPAC name (don't worry about geometric isomers)for the compound,
, is
A)butene-2.
B)butene-3.
C)2-butene.
D)2-butyne.
E)3-butene.

A)butene-2.
B)butene-3.
C)2-butene.
D)2-butyne.
E)3-butene.
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27
The IUPAC name for the compound,
, is
A)butene-2.
B)1.3-dibutene.
C)1,3-butadiene.
D)butane-1,3.
E)2-butynel.

A)butene-2.
B)1.3-dibutene.
C)1,3-butadiene.
D)butane-1,3.
E)2-butynel.
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28
If two of the hydrogen atoms in butane are replaced by two chlorine atoms, how many different dichlorobutane isomers can there be?
A)1
B)2
C)3
D)4
E)6
A)1
B)2
C)3
D)4
E)6
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29
If two of the hydrogen atoms on a single carbon in pentane are replaced by two chlorine atoms, how many different dichloropentane isomers can there be?
A)2
B)3
C)4
D)5
E)6
A)2
B)3
C)4
D)5
E)6
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30
Draw a structural formula for benzene. How many ?bonds are in the molecule?
A)6
B)12
C)14
D)18
E)20
A)6
B)12
C)14
D)18
E)20
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31
Draw a structural formula for benzene. How many single and double bonds are in the benzene molecule?
A)3 single, 0 double
B)6 single, 2 double
C)3 single, 2 double
D)9 single, 23 double
E)12 single, 3 double
A)3 single, 0 double
B)6 single, 2 double
C)3 single, 2 double
D)9 single, 23 double
E)12 single, 3 double
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32
If two of the hydrogen atoms in ethylene,
, are replaced by two chlorine atoms to form dichloroethylene, how many different dichloroethylene isomers can there be?
A)1
B)2
C)3
D)4
E)6

A)1
B)2
C)3
D)4
E)6
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33
If two of the hydrogen atoms in ethylene,
are replaced by one chlorine atom and one fluorine atom to form chlorofluoroethene, C2H2ClF, how many different chlorofluoro-ethene isomers can there be?
A)1
B)2
C)3
D)4
E)6

A)1
B)2
C)3
D)4
E)6
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34
Various hydrocarbons can be separated from a crude oil mixture by
A)filtration.
B)chromatography.
C)precipitation.
D)fractional distillation.
E)centrifugation.
A)filtration.
B)chromatography.
C)precipitation.
D)fractional distillation.
E)centrifugation.
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35
When
is reacted with water in the presence of a catalytic amount of acid, a new compound is formed. What might be the product of this reaction?
A)CH3-CH-CH2
B)

C)

D)

E)


A)CH3-CH-CH2
B)

C)

D)

E)

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36
The general structural formula for an ether is
A)

B)

C)

D)

E)R-O-R'
A)

B)

C)

D)

E)R-O-R'
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37
Which formula is an alcohol?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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38
Which is a product of the oxidation of CH3-CH2-CH2-O-H?
A)

B)

C)CH3-CH2-CH3
D)

E)CH3-CH2-O-CH3
A)

B)

C)CH3-CH2-CH3
D)

E)CH3-CH2-O-CH3
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39
The functional group
is found in
A)alkenes.
B)ketones.
C)amines.
D)alcohols.
E)ethers.

A)alkenes.
B)ketones.
C)amines.
D)alcohols.
E)ethers.
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40
The functional group
is found in all the species below except
A)aldehydes.
B)ketones.
C)amides.
D)ethers.
E)esters.

A)aldehydes.
B)ketones.
C)amides.
D)ethers.
E)esters.
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41
The functional group
is found in all the species below except
A)aldehydes.
B)carboxylic acids.
C)amides.
D)amines.
E)esters.

A)aldehydes.
B)carboxylic acids.
C)amides.
D)amines.
E)esters.
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42
The compound below is classified as which type of compound? 
A)aldehyde
B)ketone
C)acid
D)ester
E)amine

A)aldehyde
B)ketone
C)acid
D)ester
E)amine
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43
The compound below is classified as which type of compound? 
A)amine
B)amide
C)aromatic
D)ester
E)ether

A)amine
B)amide
C)aromatic
D)ester
E)ether
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44
The compound below is classified as which type of compound? 
A)amine
B)amide
C)aromatic
D)ester
E)ether

A)amine
B)amide
C)aromatic
D)ester
E)ether
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45
The compound below is classified as which type of compound? 
A)amine
B)amide
C)aromatic
D)ester
E)ether

A)amine
B)amide
C)aromatic
D)ester
E)ether
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46
The compound below is classified as which type of compound? 
A)amine
B)amide
C)aromatic
D)ester
E)ether

A)amine
B)amide
C)aromatic
D)ester
E)ether
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47
The compound below has which functional groups? 
A)ketone and ester
B)ketone, alcohol, and carboxylic acid
C)ether, ketone, and aldehyde
D)ether and aldehyde
E)ketone and aldehyde

A)ketone and ester
B)ketone, alcohol, and carboxylic acid
C)ether, ketone, and aldehyde
D)ether and aldehyde
E)ketone and aldehyde
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48
The compound below is classified as which type of compound? 
A)aldehyde
B)ketone
C)acid
D)ester
E)amine

A)aldehyde
B)ketone
C)acid
D)ester
E)amine
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49
The compound below is classified as which type of compound? 
A)ketone
B)aldehyde
C)ester
D)carboxylic acid
E)amide

A)ketone
B)aldehyde
C)ester
D)carboxylic acid
E)amide
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50
The compound below is named 
A)butanamine.
B)butanamide.
C)butanketone.
D)2-butanone.
E)2-butanal.

A)butanamine.
B)butanamide.
C)butanketone.
D)2-butanone.
E)2-butanal.
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51
The compound below has which functional groups? 
A)aromatic, alcohol, and ether
B)aromatic, alcohol, and ester
C)ether, alkene, and alcohol
D)ester, alkene and alcohol
E)ether and ester

A)aromatic, alcohol, and ether
B)aromatic, alcohol, and ester
C)ether, alkene, and alcohol
D)ester, alkene and alcohol
E)ether and ester
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52
The compound below has which functional groups? 
A)alcohol and ester
B)amide, ether, and aldehyde
C)ether and amine
D)ester and amine
E)amine, alcohol, and ether

A)alcohol and ester
B)amide, ether, and aldehyde
C)ether and amine
D)ester and amine
E)amine, alcohol, and ether
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53
The compound below is named 
A)pentaketone.
B)pentaldehyde.
C)pentanal.
D)pentanone.
E)pentanoic acid.

A)pentaketone.
B)pentaldehyde.
C)pentanal.
D)pentanone.
E)pentanoic acid.
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54
The ester that is prepared by heating 1-pentanol with acetic acid in the presence of an acidic catalyst is named
A)acetic pentanoate.
B)pentanoic acetate.
C)1-pentyl acetate.
D)acetyl 1-pentanoate.
E)acetyl pentanol.
A)acetic pentanoate.
B)pentanoic acetate.
C)1-pentyl acetate.
D)acetyl 1-pentanoate.
E)acetyl pentanol.
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55
Ethyl propanoate is a(n)
A)carboxyl alcohol.
B)aldehyde.
C)alcohol.
D)ester.
E)amide.
A)carboxyl alcohol.
B)aldehyde.
C)alcohol.
D)ester.
E)amide.
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56
The compound below has which functional groups? 
A)ester, amide, carboxylic acid
B)aromatic, ketone, amine
C)aromatic, ketone, amide
D)aromatic, aldehyde, amide
E)aromatic, aldehyde, amine

A)ester, amide, carboxylic acid
B)aromatic, ketone, amine
C)aromatic, ketone, amide
D)aromatic, aldehyde, amide
E)aromatic, aldehyde, amine
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57
Which is a product of the oxidation of the following: 
A)

B)

C)CH3-CH2-CH3
D)

E)CH3-CH2-O-CH3

A)

B)

C)CH3-CH2-CH3
D)

E)CH3-CH2-O-CH3
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58
The reaction of
with concentrated HBr using controlled heating yields
A)CH3-CH2-CH2-Br
B)(CH3)2CH-CH2-Br
C)(CH3)2CH-CH2-O-Br
D)(CH3)2CH-CH4+ Br-
E)(CH3)2CH-CH3

A)CH3-CH2-CH2-Br
B)(CH3)2CH-CH2-Br
C)(CH3)2CH-CH2-O-Br
D)(CH3)2CH-CH4+ Br-
E)(CH3)2CH-CH3
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59
Based on the properties of the attached functional group, which compound would you expect to interact most strongly with water, thus making it the substance most soluble in water?Hint: Consider hydrogen bonds.
A)CH3-CH2-Cl
B)CH3-CH2-F
C)CH3-CH2-I
D)CH3-CH2-S-H
E)CH3-CH2-O-H
A)CH3-CH2-Cl
B)CH3-CH2-F
C)CH3-CH2-I
D)CH3-CH2-S-H
E)CH3-CH2-O-H
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60
Cyclohexyl propanoate is a(n)
A)aldehyde.
B)ketone.
C)carboxylic acid.
D)ester.
E)amide.
A)aldehyde.
B)ketone.
C)carboxylic acid.
D)ester.
E)amide.
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61
Based on the properties of the attached functional group, which compound below would you expect to interact most strongly with water, thus making it the most soluble compound? Hint: Consider hydrogen bonds.
A)CH3-CH2-H
B)CH3-CH2-NH2
C)CH3-O-CH3
D)CH3-CH2-I
E)CH3-CH2-S-H
A)CH3-CH2-H
B)CH3-CH2-NH2
C)CH3-O-CH3
D)CH3-CH2-I
E)CH3-CH2-S-H
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62
Which compound is least soluble in water?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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63
Which compound is least soluble in water?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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64
Which compound is a Brønsted base?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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65
Which one of the species below is soluble in dilute HCl(aq)?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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66
Which compound is insoluble in water?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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67
A functional group containing nitrogen is found in
A)alkenes.
B)alcohols.
C)amines.
D)carboxylic acids.
E)ethers.
A)alkenes.
B)alcohols.
C)amines.
D)carboxylic acids.
E)ethers.
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68
One of the compounds listed is an organic base that functions as a proton acceptor. Identify this organic base.
A)CH3-CH2-CH2-O-H
B)
C)

D)

E)CH3-CH2-NH2
A)CH3-CH2-CH2-O-H
B)

C)

D)

E)CH3-CH2-NH2
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69
The compound, trimethylamine is a(n)________ and has the formula ________.
A)base, (CH3NH2)3
B)base, (CH3)3NH2
C)acid, (CH3)3NH2
D)base, (CH3)3N
E)acid, (CH3)3(NH2)2
A)base, (CH3NH2)3
B)base, (CH3)3NH2
C)acid, (CH3)3NH2
D)base, (CH3)3N
E)acid, (CH3)3(NH2)2
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70
Dodecylamine, CH3(CH2)10CH2NH2, is insoluble in water. Yet, it can be converted to a water soluble form. Which of the species below represents a water soluble form of this compound?
A)CH3(CH2)10CH2NH2-O-H
B)CH3(CH2)10CH2NH2-Cl
C)CH3(CH2)10CH2NH-CH3
D)CH3(CH2)10CH2NH3+ Cl-
E)CH3(CH2)10CH2NH2-O-CH3
A)CH3(CH2)10CH2NH2-O-H
B)CH3(CH2)10CH2NH2-Cl
C)CH3(CH2)10CH2NH-CH3
D)CH3(CH2)10CH2NH3+ Cl-
E)CH3(CH2)10CH2NH2-O-CH3
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71
Octylamine, CH3(CH2)7NH2, is insoluble in water. Yet, it can be converted to a water soluble form. Which of the species below represents a water-soluble form of this compound?
A)CH3(CH2)7NH2-O-H
B)CH3(CH2)7NH2-Cl
C)CH3(CH2)7NH-CH3
D)CH3(CH2)7NH3+ Cl-
E)CH3(CH2)7NH2-O-CH3
A)CH3(CH2)7NH2-O-H
B)CH3(CH2)7NH2-Cl
C)CH3(CH2)7NH-CH3
D)CH3(CH2)7NH3+ Cl-
E)CH3(CH2)7NH2-O-CH3
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72
The compound below has which functional groups? 
A)aromatic and carboxylic acid
B)aromatic and amide
C)aromatic and amine
D)aromatic and alcohol
E)aromatic and aldehyde

A)aromatic and carboxylic acid
B)aromatic and amide
C)aromatic and amine
D)aromatic and alcohol
E)aromatic and aldehyde
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73
The compound below has which functional groups? 
A)ester and amide
B)amide and amine
C)aldehyde and amine
D)carboxylic acid and amine
E)ester and amine

A)ester and amide
B)amide and amine
C)aldehyde and amine
D)carboxylic acid and amine
E)ester and amine
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74
The compound below is which type of compound? 
A)aldehyde
B)amine
C)ester
D)amide
E)amino acid

A)aldehyde
B)amine
C)ester
D)amide
E)amino acid
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75
The compound below is named 
A)pentanamine.
B)pentamine.
C)1-pentanamide.
D)pentanamide.
E)pentaketoneamine.

A)pentanamine.
B)pentamine.
C)1-pentanamide.
D)pentanamide.
E)pentaketoneamine.
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76
For the following segment of a polymer, what would be the expected monomer used to make it? 
A)
B)HC=CH
C)

D)

E)

A)

B)HC=CH
C)

D)

E)

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77
Polymers formed by the addition of monomer units by an initiator are often called
A)unit polymers.
B)chain-growth polymers.
C)branching polymers.
D)condensation polymers.
E)background polymers.
A)unit polymers.
B)chain-growth polymers.
C)branching polymers.
D)condensation polymers.
E)background polymers.
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78
A polymer is formed by the removal of water from the monomer mixture are often called
A)unit polymers.
B)chain-growth polymers.
C)branching polymers.
D)condensation polymers.
E)background polymers.
A)unit polymers.
B)chain-growth polymers.
C)branching polymers.
D)condensation polymers.
E)background polymers.
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79
Which of the following is a true statement with respect to molecular mass and strength?
A)High molecular mass polymers tend to be gases.
B)High molecular mass polymers tend to have low strength.
C)Low molecular mass polymers tend to have low strength.
D)All polymers have high strength and molecular mass.
E)Molecular mass tends to have no effect on polymer strength.
A)High molecular mass polymers tend to be gases.
B)High molecular mass polymers tend to have low strength.
C)Low molecular mass polymers tend to have low strength.
D)All polymers have high strength and molecular mass.
E)Molecular mass tends to have no effect on polymer strength.
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80
Which functional group is not usually found in carbohydrates?
A)aldehyde
B)amide
C)ether
D)hydroxy
E)ketone
A)aldehyde
B)amide
C)ether
D)hydroxy
E)ketone
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