Deck 11: Gases

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Question
The volume of a gas is proportional to number of moles of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
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Question
Using the graph below,determine the gas that has the lowest density at STP. <strong>Using the graph below,determine the gas that has the lowest density at STP.  </strong> A) A B) B C) C D) D E) All of the gases have the same density at STP. <div style=padding-top: 35px>

A) A
B) B
C) C
D) D
E) All of the gases have the same density at STP.
Question
A syringe contains 0.65 moles of He gas that occupy 750.0 mL.What volume (in L)of gas will the syringe hold if 0.35 moles of Ne is added?

A) 0.87 L
B) 4.9 L
C) 1.2 L
D) 2.1 L
E) 1.9 L
Question
A scuba diver experiences ________ as she descends into the ocean water.

A) decrease of 1 atm for each 20 m of depth
B) decrease of 1 atm for each 10 m of depth
C) increase of 1 atm for each 20 m of depth
D) increase of 1 atm for each 10 m of depth
E) no difference in pressure
Question
The volume of a gas is inversely proportional to the pressure of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
Question
Using the graph below,determine the gas that has the highest density at STP. <strong>Using the graph below,determine the gas that has the highest density at STP.  </strong> A) A B) B C) C D) D E) All of the gases have the same density at STP. <div style=padding-top: 35px>

A) A
B) B
C) C
D) D
E) All of the gases have the same density at STP.
Question
What pressure will 14.0 g of CO exert in a 3.5 L container at 75°C?

A) 4.1 atm
B) 5.0 atm
C) 6.4 atm
D) 1.1 atm
E) 2.3 atm
Question
A sample of gas initially has a volume of 859 mL at 565 K and 2.20 atm.What pressure will the sample have if the volume changes to 268 mL while the temperature is increased to 815 K?

A) 10.2 atm
B) 9.83 atm
C) 15.3 atm
D) 6.53 atm
E) 1.05 atm
Question
The volume of a gas is proportional to the temperature of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
Question
To what temperature must a balloon,initially at 25°C and 2.00 L,be heated in order to have a volume of 6.00 L?

A) 993 K
B) 403 K
C) 75 K
D) 655 K
E) 894 K
Question
An instrument used to measure blood pressure is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
Question
An instrument used to measure atmospheric pressure is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
Question
Which of the following will cause the volume of an ideal gas to triple in value?

A) raising the temperature from 25°C to 75°C at constant pressure
B) lowering the absolute temperature by a factor of 3 at constant pressure
C) raising the absolute temperature by a factor of 3 while increasing the pressure by a factor of 3
D) lowering the absolute temperature by a factor of 3 while increasing the pressure by a factor of 3
E) lowering the pressure by a factor of 3 while the temperature stays constant
Question
A large balloon is initially filled to a volume of 25.0 L at 353 K and a pressure of 2575 mm Hg.What volume of gas will the balloon contain at 1.35 atm and 253 K?

A) 22.2 L
B) 87.5 L
C) 11.4 L
D) 45.0 L
E) 58.6 L
Question
If a sample of 0.29 moles of Ar occupies 3.8 L under certain conditions,what volume will 0.66 moles occupy under the same conditions?

A) 12 L
B) 8.6 L
C) 17 L
D) 5.0 L
E) 15 L
Question
What is the volume of 5.60 g of O2 at 7.78 atm and 415K?

A) 1.53 L
B) 565 L
C) 24.5 L
D) 25.0 L
E) 0.766 L
Question
A syringe initially holds a sample of gas with a volume of 285 mL at 355 K and 1.88 atm.To what temperature must the gas in the syringe be heated/cooled in order to have a volume of 435 mL at 2.50 atm?

A) 139 K
B) 572 K
C) 175 K
D) 466 K
E) 721 K
Question
What mass of NO2 is contained in a 13.0 L tank at 4.58 atm and 385 K?

A) 18.8 g
B) 53.1 g
C) 24.4 g
D) 86.7 g
E) 69.2 g
Question
What volume (in mL)will a sample of F2 gas occupy in a syringe at 5.5 atm,if the F2 has a volume of 25.0 mL at 1.2 atm?

A) 11 mL
B) 17 mL
C) 3.8 mL
D) 5.5 mL
E) 7.6 mL
Question
An instrument used to measure the pressure of a gas in a laboratory is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
Question
A 0.465 g sample of an unknown compound occupies 245 mL at 298 K and 1.22 atm.What is the molar mass of the unknown compound?

A) 26.3 g/mol
B) 33.9 g/mol
C) 12.2 g/mol
D) 38.0 g/mol
E) 81.8 g/mol
Question
Give the definition for diffusion.

A) Gas molecules mix equally.
B) Gas molecules spread out in a concentration gradient.
C) Gas molecules escape from a container into a vacuum through a small hole.
D) average distance between collisions
E) Gas molecules mix unequally.
Question
A mixture of 10.0 g of Ne and 10.0 g Ar have a total pressure of 1.6 atm.What is the partial pressure of Ne?

A) 1.1 atm
B) 0.80 atm
C) 0.54 atm
D) 0.40 atm
E) 1.3 atm
Question
A 0.334 g sample of an unknown halogen occupies 109 mL at 398 K and 1.41 atm.What is the identity of the halogen?

A) Br2
B) F2
C) Cl2
D) I2
E) Ge
Question
The total pressure of a gas mixture is the sum of the partial pressure of its components is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
Question
A compound is found to be 30.45% N and 69.55 % O by mass.If 1.63 g of this compound occupy 389 mL at 0.00°C and 775 mm Hg,what is the molecular formula of the compound?

A) NO2
B) N2O
C) N4O2
D) N2O5
E) N2O4
Question
Define vapor pressure.

A) partial pressure of water in a liquid mixture
B) partial pressure of water in a gaseous mixture
C) condensation of water
D) water dissolved in a liquid
E) water molecules
Question
Determine the density of CO2 gas at STP.

A) 1.96 g/L
B) 1.80 g/L
C) 2.24 g/L
D) 4.46 g/L
E) 5.10 g/L
Question
Determine the volume of O2 (at STP)formed when 50.0 g of KClO3 decomposes according to the following reaction.The molar mass for KClO3 is 122.55 g/mol. 2 KClO3(s)→ 2 KCl(s)+ 3 O2(g)

A) 9.14 L
B) 8.22 L
C) 12.3 L
D) 13.7 L
E) 14.6 L
Question
What pressure would a gas mixture in a 10.0 L tank exert if it were composed of 48.5 g He and 94.6 g CO2 at 398 K?

A) 39.6 atm
B) 7.02 atm
C) 32.6 atm
D) 46.6 atm
E) 58.7 atm
Question
Which of the gases in the graph below has the largest molar mass? <strong>Which of the gases in the graph below has the largest molar mass?  </strong> A) A B) B C) C D) D E) There is not enough information to determine. <div style=padding-top: 35px>

A) A
B) B
C) C
D) D
E) There is not enough information to determine.
Question
Calculate the root mean square velocity of nitrogen molecules at 25°C.

A) 729 m/s
B) 515 m/s
C) 149 m/s
D) 297 m/s
Question
A mixture of 1.0 mol He and 1.0 mol Ne are at STP in a rigid container.Which of the following statements is TRUE?

A) Both gases have the same average kinetic energy.
B) Both gases contribute equally to the density of the mixture under these conditions.
C) Both gases have the same molecular speed.
D) The mixture has a volume of 22.4 L
E) All of the above are true.
Question
A gas mixture consists of N2,O2,and Ne,where the mole fraction of N2 is 0.55 and the mole fraction of Ne is 0.25.If the mixture is at STP in a 5.0 L container,how many molecules of O2 are present?

A) 4.5 × 1022 molecules O2
B) 2.7 × 1022 molecules O2
C) 3.7 × 1023 molecules O2
D) 1.1 × 1023 molecules O2
E) 9.3 × 1024 molecules O2
Question
The rate of effusion of two different gases is known as

A) Avogadro's Law.
B) Graham's Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
Question
Determine the density of NH3 gas at 435 K and 1.00 atm.

A) 2.10 g/L
B) 0.477 g/L
C) 0.321 g/L
D) 2.24 g/L
E) 0.851 g/L
Question
A syringe contains 589 mL of CO at 325 K and 1.2 atm pressure.A second syringe contains 473 mL of N2 at 298 K and 2.6 atm.What is the final pressure if the contents of these two syringes are injected into a 1.00 L container at 273 K?

A) 0.59 atm
B) 1.1 atm
C) 1.7 atm
D) 1.9 atm
E) 3.8 atm
Question
Define hypoxia.

A) oxygen starvation
B) increased oxygen concentration in body tissues
C) increased nitrogen concentration in body tissues and fluids
D) nitrogen starvation
Question
Which statement is TRUE about kinetic molecular theory?

A) A single particle does not move in a straight line.
B) The size of the particle is large compared to the volume of the particle.
C) The collisions of particles with one another is completely elastic.
D) The average kinetic energy of a particle is not proportional to the temperature.
Question
The following reaction is used to generate hydrogen gas in the laboratory.If 243 mL of gas is collected at 25°C and has a total pressure of 745 mm Hg,what mass of hydrogen is produced? A possibly useful table of water vapor pressures is provided below.
Mg(s)+ 2 HCl(aq)→ MgCl2(aq)+ H2(g)T (°C)P (mm Hg)
20 17.55
25 23.78
30 31.86

A) 0.0196 g H2
B) 0.0717 g H2
C) 0.0190 g H2
D) 0.0144 g H2
E) 0.0449 g H2
Question
The rate of effusion of argon to an unknown gas is 1.194.What is the other gas?

A) oxygen
B) nitrogen
C) neon
D) krypton
E) hydrogen
Question
Determine the total volume of all gases (at STP)formed when 50.0 mL of TNT (C3H5(NO3)3,d = 1.60 g/mL,molar mass = 227.10 g/mol)reacts according to the following reaction. 4 C3H5(NO3)3(l)→ 6 N2(g)+ O2(g)+ 12 CO2(g)+ 10 H2O(g)

A) 4.93 L
B) 57.2 L
C) 29.6 L
D) 448 L
E) 175 L
Question
Determine the theoretical yield and the percent yield if 21.8 g of K2CO3 is produced from reacting 27.9 g KO2 with 29.0 L of CO2 (at STP).The molar mass of KO2 = 71.10 g/mol and K2CO3 = 138.21 g/mol. 4 KO2(s)+ 2 CO2(g)→ 2 K2CO3(s)+ 3 O2(g)

A) 27.1 g, 80.4 % yield
B) 179 g, 12.2 % yield
C) 91.7 g, 23.8 % yield
D) 206 g, 10.6 % yield
E) 61.0 g, 35.7 % yield
Question
Determine the mass of water formed when 12.5 L NH3 (at 298 K and 1.50 atm)is reacted with 18.9 L of O2 (at 323 K and 1.1 atm). 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(g)

A) 17.0 g H2O
B) 20.7 g H2O
C) 37.7 g H2O
D) 13.8 g H2O
E) 27.9 g H2O
Question
All of the following statements concerning real cases is correct EXCEPT

A) molecules of real gases are attracted to each other.
B) molecules of real gases occupy no volume.
C) the pressure of a real gas at low temperatures is lower than for ideal gases.
D) the pressure of a real gas is due to collisions with the container.
E) nonideal gas behavior is described by the Van der Waals Equation.
Question
Which one of these will diffuse the fastest at 25°C?

A) 2.0 M Ar
B) 1.0 M H2
C) 2.0 M N2
D) 0.5 M Ne
E) 2.0 M O2
Question
Which of the following compounds will behave LEAST like an ideal gas at low temperatures?

A) He
B) SO2
C) H2
D) N2
E) F2
Question
This equation is used to calculate the properties of a gas under nonideal conditions.

A) Charles's Law
B) Avogadro's Law
C) Boyle's Law
D) van der Waals equation
E) Dalton's Law
Question
Determine the volume of SO2 (at STP)formed from the reaction of 96.7 g of FeS2 and 55.0 L of O2 (at 398 K and 1.20 atm).The molar mass of FeS2 is 119.99 g/mol. 4 FeS2(s)+ 11 O2(g)→ 2 Fe2O3(s)+ 8 SO2(g)

A) 36.1 L
B) 45.3 L
C) 18.1 L
D) 27.6 L
E) 32.9 L
Question
What is the volume of 0.700 mol of neon gas at a pressure of 609.5 mm Hg and 117°C?

A) 0.0941 L
B) 13.5 L
C) 2.13 L
D) 27.9 L
E) 0.138 L
Question
Which of the following statements is TRUE?

A) At a given temperature, lighter gas particles travel more slowly than heavier gas particles.
B) The smaller a gas particle, the slower it will effuse.
C) The higher the temperature, the lower the average kinetic energy of the sample.
D) At low temperatures, intermolecular forces become important and the pressure of a gas will be lower than predicted by the ideal gas law.
E) None of the above statements are true.
Question
Determine the volume of H2S (at 375 K and 1.20 atm)needed to produce 55.0 g of S.Assume that there is excess SO2 present. 2 H2S(g)+ SO2(g)→ 3 S(s)+ 2 H2O(g)

A) 44.0 L
B) 29.3 L
C) 22.7 L
D) 34.1 L
E) 66.0 L
Question
Which of the following gases has the largest density at STP?

A) He
B) C2H2
C) F2
D) N2
E) H2
Question
The rate of effusion of oxygen to an unknown gas is 0.935.What is the other gas?

A) Ne
B) Ar
C) F2
D) N2
Question
How many molecules of XeF6 are formed from 12.9 L of F2 (at 298 K and 2.60 atm)according to the following reaction? Assume that there is excess Xe.
Xe(g)+ 3 F2(g)→ XeF6(g)

A) 1.21 × 1023 molecules XeF6
B) 8.25 × 1023 molecules XeF6
C) 2.75 × 1023 molecules XeF6
D) 7.29 × 1023 molecules XeF6
E) 1.37 × 1023 molecules XeF6
Question
Arrange the gases according to increasing rate of diffusion at 50°C.

A) NO2 < O2 < SO2
B) O2 < NO2 < SO2
C) O2 < SO2 < NO2
D) SO2 < O2 < NO2
E) SO2 < NO2 < O2
Question
Which of the following statements is TRUE?

A) Particles of different masses have the same average speed at a given temperature.
B) The larger a molecule, the faster it will effuse.
C) At very high pressures, a gas will occupy a larger volume than predicted by the ideal gas law.
D) For a given gas, the lower the temperature, the faster it will effuse.
E) None of the above statements are true.
Question
A sample of nitrogen gas is placed in a sealed chamber,and the temperature is increased from 25°C to 125°C under constant pressure.The volume of the sample must

A) increase.
B) decrease.
C) remain constant.
D) None of these are possible.
Question
What volume of water is produced when 38.5 g of ethanol reacts with oxygen at 500°C at 1.75 atm?
CH3CH2OH(g)+ 3 O2(g)→ 2 CO2(g)+ 3 H2O(g)

A) 91.0 L
B) 58.7 L
C) 103 L
D) 30.3 L
E) 12.5 L
Question
If 2.0 mol of gas A is mixed with 1.0 mol of gas B to give a total pressure of 1.6 atm,what is the partial pressure of gas A and B?

A) PA = 0.33 atm and PB = 0.67 atm
B) PA = 0.67 atm and PB = 0.33 atm
C) PA = 1.0 atm and PB = 2.0 atm
D) PA = 2.0 atm and PB = 1.0 atm
E) PA = 1.06 atm and PB = 0.53 atm
Question
The atmospheric pressure is 715 mm Hg.What is the pressure in torr?

A) 715 torr
B) 28.1 torr
C) 13.8 torr
D) 31.8 torr
E) 760 torr
Question
A sample of 0.200 moles of nitrogen occupies 0.400 L.Under the same conditions,what number of moles occupies 1.200 L?

A) 0.600 moles
B) 0.0667 moles
C) 2.40 moles
D) 0.0960 moles
Question
The atmospheric pressure is 700 mm Hg.What is the pressure in inches of Hg?

A) 16.0 in Hg
B) 0.921 in Hg
C) 13.5 in Hg
D) 27.6 in Hg
E) 32.5 in Hg
Question
Convert 1.75 atm to psi.

A) 52.4 psi
B) 875 psi
C) 25.7 psi
D) 1000 psi
E) 1330 psi
Question
A container filled with gas is connected to an open-end manometer that is filled with mineral oil.The pressure in the gas container is 753 mm Hg and atmospheric pressure is 724 mm.How high will the level rise in the manometer if the densities of Hg and mineral oil are 13.6 g/mL and 0.822 g/mL respectively?

A) 1.75 mm
B) 23.8 mm
C) 29.0 mm
D) 480 mm
Question
Convert 1.50 atm to mm Hg.

A) 760 mm Hg
B) 875 mm Hg
C) 1140 mm Hg
D) 1000 mm Hg
E) 1520 mm Hg
Question
A gas occupies 4.23 L at 2.25 atm.What is the volume at 3.46 atm?

A) 6.50 L
B) 1.84 L
C) 2.75 L
D) 32.9 L
E) 0.364 L
Question
To what volume will a sample of gas expand if it is heated from 50.0C and 2.33 L to 500.0°C?

A) 5.58 L
B) 23.3 L
C) 0.233 L
D) 0.97 L
E) 0.184 L
Question
If the pressure in a gas container that is connected to an open-end U-tube manometer is 116 kPa and the pressure of the atmosphere at the open end of the tube is 752 mm Hg,the level of mercury in the tube will

A) be 118 mm higher in the arm open to the atmosphere.
B) be 118 mm higher in the arm connected to the gas cylinder.
C) be 870 mm higher in the arm open to the atmosphere.
D) be 870 mm higher in the arm connected to the gas cylinder.
Question
For a given set of conditions,a sample of 0.95 moles of Kr occupies 5.20 L.How many moles of Kr will occupy 24.8 L under the same conditions?

A) 7.42 mol
B) 0.0221 mol
C) 10.5 mol
D) 4.53 mol
E) 3.58 mol
Question
How many moles of nitrogen will react with 380 mL of hydrogen at -30°C and 200 mm Hg?
N2(g)+ 3 H2(g)→ 2 NH3(g)

A) 0.0150 mol
B) 0.00782 mol
C) 0.00501 mol
D) 0.00167 mol
E) 0.0382 mol
Question
A 7.82 L gas cylinder contains 28.6 g of O2 and 79.5 g of Xe at 70°C.What is the pressure exerted by the gas?

A) 1.10 atm
B) 8.63 atm
C) 6.92 atm
D) 3.28 atm
E) 5.41 atm
Question
A sample of neon at 30.5°C exerts a pressure of 701 mm Hg? What is its density?

A) 0.747 g/mL
B) 563 g/mL
C) 7.42 g/mL
D) 1.38 g/mL
E) 0.482 g/mL
Question
What is the temperature of 100.8 g of N2 that exerts a pressure of 23.8 atm in a 6.51 L container?

A) 524K
B) 489K
C) 778K
D) 261K
E) 340K
Question
Convert 1.50 atm to torr.

A) 760 torr
B) 875 torr
C) 1140 torr
D) 1000 torr
E) 1520 torr
Question
What is the temperature of 144.32 g of O2 found in a 5.00L container kept at a pressure of 3.28 atm assuming it behaves as a real gas?

A) 44.3 K
B) 57.5 K
C) 102 K
D) 219 K
E) 328 K
Question
A sample of CO2 gas fills a container with a volume of 44.5 L.When the volume is decreased to 13.8 L at a constant temperature,the pressure inside the container is 6.25 atm.What was the pressure inside the container originally?

A) 0.035 atm
B) 0.51 atm
C) 1.94 atm
D) 3.84 atm
E) 6.25 atm
Question
A sample of 1.58 g of an unknown gas has a volume of 0.682 L.The sample is kept at 60°C,and exerts a pressure of 1.38 atm.What is the gas?

A) Cl2
B) NO
C) NO2
D) SO2
E) C2H6
Question
What is the pressure in a gas container that is connected to an open-end U-tube manometer if the pressure of the atmosphere is 742 torr and the level of mercury in the arm connected to the container is 8.60 cm higher than the level of mercury open to the atmosphere?

A) 656 mm Hg
B) 733 mm Hg
C) 751 mm Hg
D) 828 mm Hg
Question
What volume will a balloon occupy at 1.0 atm,if the balloon has a volume of 8.8 L at 4.4 atm?

A) 2.0 L
B) 0.50 L
C) 39 L
D) 13 L
E) 4.4 L
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Deck 11: Gases
1
The volume of a gas is proportional to number of moles of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
Avogadro's Law.
2
Using the graph below,determine the gas that has the lowest density at STP. <strong>Using the graph below,determine the gas that has the lowest density at STP.  </strong> A) A B) B C) C D) D E) All of the gases have the same density at STP.

A) A
B) B
C) C
D) D
E) All of the gases have the same density at STP.
A
3
A syringe contains 0.65 moles of He gas that occupy 750.0 mL.What volume (in L)of gas will the syringe hold if 0.35 moles of Ne is added?

A) 0.87 L
B) 4.9 L
C) 1.2 L
D) 2.1 L
E) 1.9 L
1.2 L
4
A scuba diver experiences ________ as she descends into the ocean water.

A) decrease of 1 atm for each 20 m of depth
B) decrease of 1 atm for each 10 m of depth
C) increase of 1 atm for each 20 m of depth
D) increase of 1 atm for each 10 m of depth
E) no difference in pressure
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5
The volume of a gas is inversely proportional to the pressure of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
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6
Using the graph below,determine the gas that has the highest density at STP. <strong>Using the graph below,determine the gas that has the highest density at STP.  </strong> A) A B) B C) C D) D E) All of the gases have the same density at STP.

A) A
B) B
C) C
D) D
E) All of the gases have the same density at STP.
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7
What pressure will 14.0 g of CO exert in a 3.5 L container at 75°C?

A) 4.1 atm
B) 5.0 atm
C) 6.4 atm
D) 1.1 atm
E) 2.3 atm
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8
A sample of gas initially has a volume of 859 mL at 565 K and 2.20 atm.What pressure will the sample have if the volume changes to 268 mL while the temperature is increased to 815 K?

A) 10.2 atm
B) 9.83 atm
C) 15.3 atm
D) 6.53 atm
E) 1.05 atm
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9
The volume of a gas is proportional to the temperature of a gas is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
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10
To what temperature must a balloon,initially at 25°C and 2.00 L,be heated in order to have a volume of 6.00 L?

A) 993 K
B) 403 K
C) 75 K
D) 655 K
E) 894 K
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11
An instrument used to measure blood pressure is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
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12
An instrument used to measure atmospheric pressure is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
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13
Which of the following will cause the volume of an ideal gas to triple in value?

A) raising the temperature from 25°C to 75°C at constant pressure
B) lowering the absolute temperature by a factor of 3 at constant pressure
C) raising the absolute temperature by a factor of 3 while increasing the pressure by a factor of 3
D) lowering the absolute temperature by a factor of 3 while increasing the pressure by a factor of 3
E) lowering the pressure by a factor of 3 while the temperature stays constant
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14
A large balloon is initially filled to a volume of 25.0 L at 353 K and a pressure of 2575 mm Hg.What volume of gas will the balloon contain at 1.35 atm and 253 K?

A) 22.2 L
B) 87.5 L
C) 11.4 L
D) 45.0 L
E) 58.6 L
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15
If a sample of 0.29 moles of Ar occupies 3.8 L under certain conditions,what volume will 0.66 moles occupy under the same conditions?

A) 12 L
B) 8.6 L
C) 17 L
D) 5.0 L
E) 15 L
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16
What is the volume of 5.60 g of O2 at 7.78 atm and 415K?

A) 1.53 L
B) 565 L
C) 24.5 L
D) 25.0 L
E) 0.766 L
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17
A syringe initially holds a sample of gas with a volume of 285 mL at 355 K and 1.88 atm.To what temperature must the gas in the syringe be heated/cooled in order to have a volume of 435 mL at 2.50 atm?

A) 139 K
B) 572 K
C) 175 K
D) 466 K
E) 721 K
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18
What mass of NO2 is contained in a 13.0 L tank at 4.58 atm and 385 K?

A) 18.8 g
B) 53.1 g
C) 24.4 g
D) 86.7 g
E) 69.2 g
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19
What volume (in mL)will a sample of F2 gas occupy in a syringe at 5.5 atm,if the F2 has a volume of 25.0 mL at 1.2 atm?

A) 11 mL
B) 17 mL
C) 3.8 mL
D) 5.5 mL
E) 7.6 mL
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20
An instrument used to measure the pressure of a gas in a laboratory is called a

A) barometer.
B) manometer.
C) sphygmomanometer.
D) spectrophotometer.
E) spectrometer.
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21
A 0.465 g sample of an unknown compound occupies 245 mL at 298 K and 1.22 atm.What is the molar mass of the unknown compound?

A) 26.3 g/mol
B) 33.9 g/mol
C) 12.2 g/mol
D) 38.0 g/mol
E) 81.8 g/mol
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22
Give the definition for diffusion.

A) Gas molecules mix equally.
B) Gas molecules spread out in a concentration gradient.
C) Gas molecules escape from a container into a vacuum through a small hole.
D) average distance between collisions
E) Gas molecules mix unequally.
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23
A mixture of 10.0 g of Ne and 10.0 g Ar have a total pressure of 1.6 atm.What is the partial pressure of Ne?

A) 1.1 atm
B) 0.80 atm
C) 0.54 atm
D) 0.40 atm
E) 1.3 atm
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24
A 0.334 g sample of an unknown halogen occupies 109 mL at 398 K and 1.41 atm.What is the identity of the halogen?

A) Br2
B) F2
C) Cl2
D) I2
E) Ge
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25
The total pressure of a gas mixture is the sum of the partial pressure of its components is known as

A) Avogadro's Law.
B) Ideal Gas Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
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26
A compound is found to be 30.45% N and 69.55 % O by mass.If 1.63 g of this compound occupy 389 mL at 0.00°C and 775 mm Hg,what is the molecular formula of the compound?

A) NO2
B) N2O
C) N4O2
D) N2O5
E) N2O4
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27
Define vapor pressure.

A) partial pressure of water in a liquid mixture
B) partial pressure of water in a gaseous mixture
C) condensation of water
D) water dissolved in a liquid
E) water molecules
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28
Determine the density of CO2 gas at STP.

A) 1.96 g/L
B) 1.80 g/L
C) 2.24 g/L
D) 4.46 g/L
E) 5.10 g/L
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29
Determine the volume of O2 (at STP)formed when 50.0 g of KClO3 decomposes according to the following reaction.The molar mass for KClO3 is 122.55 g/mol. 2 KClO3(s)→ 2 KCl(s)+ 3 O2(g)

A) 9.14 L
B) 8.22 L
C) 12.3 L
D) 13.7 L
E) 14.6 L
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30
What pressure would a gas mixture in a 10.0 L tank exert if it were composed of 48.5 g He and 94.6 g CO2 at 398 K?

A) 39.6 atm
B) 7.02 atm
C) 32.6 atm
D) 46.6 atm
E) 58.7 atm
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31
Which of the gases in the graph below has the largest molar mass? <strong>Which of the gases in the graph below has the largest molar mass?  </strong> A) A B) B C) C D) D E) There is not enough information to determine.

A) A
B) B
C) C
D) D
E) There is not enough information to determine.
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32
Calculate the root mean square velocity of nitrogen molecules at 25°C.

A) 729 m/s
B) 515 m/s
C) 149 m/s
D) 297 m/s
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33
A mixture of 1.0 mol He and 1.0 mol Ne are at STP in a rigid container.Which of the following statements is TRUE?

A) Both gases have the same average kinetic energy.
B) Both gases contribute equally to the density of the mixture under these conditions.
C) Both gases have the same molecular speed.
D) The mixture has a volume of 22.4 L
E) All of the above are true.
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34
A gas mixture consists of N2,O2,and Ne,where the mole fraction of N2 is 0.55 and the mole fraction of Ne is 0.25.If the mixture is at STP in a 5.0 L container,how many molecules of O2 are present?

A) 4.5 × 1022 molecules O2
B) 2.7 × 1022 molecules O2
C) 3.7 × 1023 molecules O2
D) 1.1 × 1023 molecules O2
E) 9.3 × 1024 molecules O2
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35
The rate of effusion of two different gases is known as

A) Avogadro's Law.
B) Graham's Law.
C) Charles's Law.
D) Boyle's Law.
E) Dalton's Law.
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36
Determine the density of NH3 gas at 435 K and 1.00 atm.

A) 2.10 g/L
B) 0.477 g/L
C) 0.321 g/L
D) 2.24 g/L
E) 0.851 g/L
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37
A syringe contains 589 mL of CO at 325 K and 1.2 atm pressure.A second syringe contains 473 mL of N2 at 298 K and 2.6 atm.What is the final pressure if the contents of these two syringes are injected into a 1.00 L container at 273 K?

A) 0.59 atm
B) 1.1 atm
C) 1.7 atm
D) 1.9 atm
E) 3.8 atm
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38
Define hypoxia.

A) oxygen starvation
B) increased oxygen concentration in body tissues
C) increased nitrogen concentration in body tissues and fluids
D) nitrogen starvation
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39
Which statement is TRUE about kinetic molecular theory?

A) A single particle does not move in a straight line.
B) The size of the particle is large compared to the volume of the particle.
C) The collisions of particles with one another is completely elastic.
D) The average kinetic energy of a particle is not proportional to the temperature.
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40
The following reaction is used to generate hydrogen gas in the laboratory.If 243 mL of gas is collected at 25°C and has a total pressure of 745 mm Hg,what mass of hydrogen is produced? A possibly useful table of water vapor pressures is provided below.
Mg(s)+ 2 HCl(aq)→ MgCl2(aq)+ H2(g)T (°C)P (mm Hg)
20 17.55
25 23.78
30 31.86

A) 0.0196 g H2
B) 0.0717 g H2
C) 0.0190 g H2
D) 0.0144 g H2
E) 0.0449 g H2
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41
The rate of effusion of argon to an unknown gas is 1.194.What is the other gas?

A) oxygen
B) nitrogen
C) neon
D) krypton
E) hydrogen
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42
Determine the total volume of all gases (at STP)formed when 50.0 mL of TNT (C3H5(NO3)3,d = 1.60 g/mL,molar mass = 227.10 g/mol)reacts according to the following reaction. 4 C3H5(NO3)3(l)→ 6 N2(g)+ O2(g)+ 12 CO2(g)+ 10 H2O(g)

A) 4.93 L
B) 57.2 L
C) 29.6 L
D) 448 L
E) 175 L
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43
Determine the theoretical yield and the percent yield if 21.8 g of K2CO3 is produced from reacting 27.9 g KO2 with 29.0 L of CO2 (at STP).The molar mass of KO2 = 71.10 g/mol and K2CO3 = 138.21 g/mol. 4 KO2(s)+ 2 CO2(g)→ 2 K2CO3(s)+ 3 O2(g)

A) 27.1 g, 80.4 % yield
B) 179 g, 12.2 % yield
C) 91.7 g, 23.8 % yield
D) 206 g, 10.6 % yield
E) 61.0 g, 35.7 % yield
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44
Determine the mass of water formed when 12.5 L NH3 (at 298 K and 1.50 atm)is reacted with 18.9 L of O2 (at 323 K and 1.1 atm). 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(g)

A) 17.0 g H2O
B) 20.7 g H2O
C) 37.7 g H2O
D) 13.8 g H2O
E) 27.9 g H2O
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45
All of the following statements concerning real cases is correct EXCEPT

A) molecules of real gases are attracted to each other.
B) molecules of real gases occupy no volume.
C) the pressure of a real gas at low temperatures is lower than for ideal gases.
D) the pressure of a real gas is due to collisions with the container.
E) nonideal gas behavior is described by the Van der Waals Equation.
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46
Which one of these will diffuse the fastest at 25°C?

A) 2.0 M Ar
B) 1.0 M H2
C) 2.0 M N2
D) 0.5 M Ne
E) 2.0 M O2
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47
Which of the following compounds will behave LEAST like an ideal gas at low temperatures?

A) He
B) SO2
C) H2
D) N2
E) F2
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48
This equation is used to calculate the properties of a gas under nonideal conditions.

A) Charles's Law
B) Avogadro's Law
C) Boyle's Law
D) van der Waals equation
E) Dalton's Law
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49
Determine the volume of SO2 (at STP)formed from the reaction of 96.7 g of FeS2 and 55.0 L of O2 (at 398 K and 1.20 atm).The molar mass of FeS2 is 119.99 g/mol. 4 FeS2(s)+ 11 O2(g)→ 2 Fe2O3(s)+ 8 SO2(g)

A) 36.1 L
B) 45.3 L
C) 18.1 L
D) 27.6 L
E) 32.9 L
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50
What is the volume of 0.700 mol of neon gas at a pressure of 609.5 mm Hg and 117°C?

A) 0.0941 L
B) 13.5 L
C) 2.13 L
D) 27.9 L
E) 0.138 L
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51
Which of the following statements is TRUE?

A) At a given temperature, lighter gas particles travel more slowly than heavier gas particles.
B) The smaller a gas particle, the slower it will effuse.
C) The higher the temperature, the lower the average kinetic energy of the sample.
D) At low temperatures, intermolecular forces become important and the pressure of a gas will be lower than predicted by the ideal gas law.
E) None of the above statements are true.
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52
Determine the volume of H2S (at 375 K and 1.20 atm)needed to produce 55.0 g of S.Assume that there is excess SO2 present. 2 H2S(g)+ SO2(g)→ 3 S(s)+ 2 H2O(g)

A) 44.0 L
B) 29.3 L
C) 22.7 L
D) 34.1 L
E) 66.0 L
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53
Which of the following gases has the largest density at STP?

A) He
B) C2H2
C) F2
D) N2
E) H2
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54
The rate of effusion of oxygen to an unknown gas is 0.935.What is the other gas?

A) Ne
B) Ar
C) F2
D) N2
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55
How many molecules of XeF6 are formed from 12.9 L of F2 (at 298 K and 2.60 atm)according to the following reaction? Assume that there is excess Xe.
Xe(g)+ 3 F2(g)→ XeF6(g)

A) 1.21 × 1023 molecules XeF6
B) 8.25 × 1023 molecules XeF6
C) 2.75 × 1023 molecules XeF6
D) 7.29 × 1023 molecules XeF6
E) 1.37 × 1023 molecules XeF6
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56
Arrange the gases according to increasing rate of diffusion at 50°C.

A) NO2 < O2 < SO2
B) O2 < NO2 < SO2
C) O2 < SO2 < NO2
D) SO2 < O2 < NO2
E) SO2 < NO2 < O2
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57
Which of the following statements is TRUE?

A) Particles of different masses have the same average speed at a given temperature.
B) The larger a molecule, the faster it will effuse.
C) At very high pressures, a gas will occupy a larger volume than predicted by the ideal gas law.
D) For a given gas, the lower the temperature, the faster it will effuse.
E) None of the above statements are true.
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58
A sample of nitrogen gas is placed in a sealed chamber,and the temperature is increased from 25°C to 125°C under constant pressure.The volume of the sample must

A) increase.
B) decrease.
C) remain constant.
D) None of these are possible.
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59
What volume of water is produced when 38.5 g of ethanol reacts with oxygen at 500°C at 1.75 atm?
CH3CH2OH(g)+ 3 O2(g)→ 2 CO2(g)+ 3 H2O(g)

A) 91.0 L
B) 58.7 L
C) 103 L
D) 30.3 L
E) 12.5 L
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60
If 2.0 mol of gas A is mixed with 1.0 mol of gas B to give a total pressure of 1.6 atm,what is the partial pressure of gas A and B?

A) PA = 0.33 atm and PB = 0.67 atm
B) PA = 0.67 atm and PB = 0.33 atm
C) PA = 1.0 atm and PB = 2.0 atm
D) PA = 2.0 atm and PB = 1.0 atm
E) PA = 1.06 atm and PB = 0.53 atm
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61
The atmospheric pressure is 715 mm Hg.What is the pressure in torr?

A) 715 torr
B) 28.1 torr
C) 13.8 torr
D) 31.8 torr
E) 760 torr
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62
A sample of 0.200 moles of nitrogen occupies 0.400 L.Under the same conditions,what number of moles occupies 1.200 L?

A) 0.600 moles
B) 0.0667 moles
C) 2.40 moles
D) 0.0960 moles
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63
The atmospheric pressure is 700 mm Hg.What is the pressure in inches of Hg?

A) 16.0 in Hg
B) 0.921 in Hg
C) 13.5 in Hg
D) 27.6 in Hg
E) 32.5 in Hg
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64
Convert 1.75 atm to psi.

A) 52.4 psi
B) 875 psi
C) 25.7 psi
D) 1000 psi
E) 1330 psi
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65
A container filled with gas is connected to an open-end manometer that is filled with mineral oil.The pressure in the gas container is 753 mm Hg and atmospheric pressure is 724 mm.How high will the level rise in the manometer if the densities of Hg and mineral oil are 13.6 g/mL and 0.822 g/mL respectively?

A) 1.75 mm
B) 23.8 mm
C) 29.0 mm
D) 480 mm
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66
Convert 1.50 atm to mm Hg.

A) 760 mm Hg
B) 875 mm Hg
C) 1140 mm Hg
D) 1000 mm Hg
E) 1520 mm Hg
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67
A gas occupies 4.23 L at 2.25 atm.What is the volume at 3.46 atm?

A) 6.50 L
B) 1.84 L
C) 2.75 L
D) 32.9 L
E) 0.364 L
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68
To what volume will a sample of gas expand if it is heated from 50.0C and 2.33 L to 500.0°C?

A) 5.58 L
B) 23.3 L
C) 0.233 L
D) 0.97 L
E) 0.184 L
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69
If the pressure in a gas container that is connected to an open-end U-tube manometer is 116 kPa and the pressure of the atmosphere at the open end of the tube is 752 mm Hg,the level of mercury in the tube will

A) be 118 mm higher in the arm open to the atmosphere.
B) be 118 mm higher in the arm connected to the gas cylinder.
C) be 870 mm higher in the arm open to the atmosphere.
D) be 870 mm higher in the arm connected to the gas cylinder.
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70
For a given set of conditions,a sample of 0.95 moles of Kr occupies 5.20 L.How many moles of Kr will occupy 24.8 L under the same conditions?

A) 7.42 mol
B) 0.0221 mol
C) 10.5 mol
D) 4.53 mol
E) 3.58 mol
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71
How many moles of nitrogen will react with 380 mL of hydrogen at -30°C and 200 mm Hg?
N2(g)+ 3 H2(g)→ 2 NH3(g)

A) 0.0150 mol
B) 0.00782 mol
C) 0.00501 mol
D) 0.00167 mol
E) 0.0382 mol
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72
A 7.82 L gas cylinder contains 28.6 g of O2 and 79.5 g of Xe at 70°C.What is the pressure exerted by the gas?

A) 1.10 atm
B) 8.63 atm
C) 6.92 atm
D) 3.28 atm
E) 5.41 atm
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73
A sample of neon at 30.5°C exerts a pressure of 701 mm Hg? What is its density?

A) 0.747 g/mL
B) 563 g/mL
C) 7.42 g/mL
D) 1.38 g/mL
E) 0.482 g/mL
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74
What is the temperature of 100.8 g of N2 that exerts a pressure of 23.8 atm in a 6.51 L container?

A) 524K
B) 489K
C) 778K
D) 261K
E) 340K
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75
Convert 1.50 atm to torr.

A) 760 torr
B) 875 torr
C) 1140 torr
D) 1000 torr
E) 1520 torr
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76
What is the temperature of 144.32 g of O2 found in a 5.00L container kept at a pressure of 3.28 atm assuming it behaves as a real gas?

A) 44.3 K
B) 57.5 K
C) 102 K
D) 219 K
E) 328 K
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77
A sample of CO2 gas fills a container with a volume of 44.5 L.When the volume is decreased to 13.8 L at a constant temperature,the pressure inside the container is 6.25 atm.What was the pressure inside the container originally?

A) 0.035 atm
B) 0.51 atm
C) 1.94 atm
D) 3.84 atm
E) 6.25 atm
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78
A sample of 1.58 g of an unknown gas has a volume of 0.682 L.The sample is kept at 60°C,and exerts a pressure of 1.38 atm.What is the gas?

A) Cl2
B) NO
C) NO2
D) SO2
E) C2H6
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79
What is the pressure in a gas container that is connected to an open-end U-tube manometer if the pressure of the atmosphere is 742 torr and the level of mercury in the arm connected to the container is 8.60 cm higher than the level of mercury open to the atmosphere?

A) 656 mm Hg
B) 733 mm Hg
C) 751 mm Hg
D) 828 mm Hg
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80
What volume will a balloon occupy at 1.0 atm,if the balloon has a volume of 8.8 L at 4.4 atm?

A) 2.0 L
B) 0.50 L
C) 39 L
D) 13 L
E) 4.4 L
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