Deck 11: Introduction to Organic Chemistry: Hydrocarbons
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Deck 11: Introduction to Organic Chemistry: Hydrocarbons
1
In the three-dimensional structure of methane,
,the hydrogen atoms attached to a carbon atom are aligned ________.
A)in a straight line
B)at the corners of a square
C)at the corners of a tetrahedron
D)at the corners of a rectangle
E)at the corners of a cube

A)in a straight line
B)at the corners of a square
C)at the corners of a tetrahedron
D)at the corners of a rectangle
E)at the corners of a cube
at the corners of a tetrahedron
2
What is the IUPAC name of the continuous chain alkane with six carbon atoms?
A)butane
B)pentane
C)hexane
D)heptane
E)octane
A)butane
B)pentane
C)hexane
D)heptane
E)octane
hexane
3
Which of the following is true of nonane,
,which has a density of 0.79 g/mL,melts at -51 °C,and boils at 151 °C?
A)Nonane is soluble in water.
B)Nonane is a gas at room temperature.
C)Nonane is a solid at room temperature.
D)Nonane does not undergo combustion.
E)Nonane floats on the surface of water.


A)Nonane is soluble in water.
B)Nonane is a gas at room temperature.
C)Nonane is a solid at room temperature.
D)Nonane does not undergo combustion.
E)Nonane floats on the surface of water.
Nonane floats on the surface of water.
4
A formula that shows the arrangement of all bonds in a molecule is called a(n)________.
A)molecular formula
B)expanded structural formula
C)condensed structural formula
D)condensed molecular formula
E)isomeric formula
A)molecular formula
B)expanded structural formula
C)condensed structural formula
D)condensed molecular formula
E)isomeric formula
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5
An organic compound composed of carbon and hydrogen connected only by single bonds is an ________.
A)alkane
B)alkene
C)alkyne
D)aromatic compound
E)alcohol
A)alkane
B)alkene
C)alkyne
D)aromatic compound
E)alcohol
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6
Which of these formulas is the expanded structural formula for an alkane with three carbon atoms?
A)

B)

C)
-
- 
D)C- C- C
E)
A)


B)


C)



D)C- C- C
E)

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7
Organic chemistry is the study of the chemistry of compounds of ________.
A)oxygen
B)hydrogen
C)living things
D)polymers
E)carbon
A)oxygen
B)hydrogen
C)living things
D)polymers
E)carbon
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8
A cycloalkane ________.
A)has two fewer carbon atoms than the corresponding alkane
B)has two fewer hydrogen atoms than the corresponding alkane
C)contains -
groups joined by single bonds
D)always contains a three carbon ring
E)has no hydrogen atoms
A)has two fewer carbon atoms than the corresponding alkane
B)has two fewer hydrogen atoms than the corresponding alkane
C)contains -

D)always contains a three carbon ring
E)has no hydrogen atoms
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9
Which of the following is not typical of most hydrocarbons?
A)high melting point
B)poor solubility in water
C)low boiling point
D)covalent bonding
E)high flammability
A)high melting point
B)poor solubility in water
C)low boiling point
D)covalent bonding
E)high flammability
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10
Carbon atoms always have how many covalent bonds?
A)one
B)two
C)three
D)four
E)five
A)one
B)two
C)three
D)four
E)five
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11
Hydrocarbons are the primary constituents of ________.
A)drugs
B)food flavors
C)fuels
D)fruit juices
E)disinfectants
A)drugs
B)food flavors
C)fuels
D)fruit juices
E)disinfectants
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12
What is the condensed structural formula for an alkane with four carbon atoms?
A)
-CH
CH- 
B)
- 
C)

D)C-C-C-C
E)
A)



B)




C)


D)C-C-C-C
E)

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13
What is the IUPAC name of 
A)ethane
B)propane
C)butane
D)pentane
E)hexane

A)ethane
B)propane
C)butane
D)pentane
E)hexane
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14
How many valence electrons does carbon have?
A)one
B)two
C)three
D)four
E)five
A)one
B)two
C)three
D)four
E)five
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15
The skeletal formula shown is that of ________. 
A)butane
B)pentane
C)hexane
D)heptane
E)octane

A)butane
B)pentane
C)hexane
D)heptane
E)octane
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16
What is the IUPAC name of this compound? 
A)hexane
B)heptane
C)octane
D)butane
E)pentane

A)hexane
B)heptane
C)octane
D)butane
E)pentane
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17
A hydrocarbon contains only the elements ________.
A)hydrogen and oxygen
B)carbon and oxygen
C)carbon and hydrogen
D)carbon,hydrogen,and oxygen
E)carbon,hydrogen,and nitrogen
A)hydrogen and oxygen
B)carbon and oxygen
C)carbon and hydrogen
D)carbon,hydrogen,and oxygen
E)carbon,hydrogen,and nitrogen
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18
What is the IUPAC name of this compound? 
A)pentane
B)hexane
C)heptane
D)octane
E)methylbutane

A)pentane
B)hexane
C)heptane
D)octane
E)methylbutane
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19
The carbon atoms in saturated hydrocarbons ________.
A)have only single bonds
B)contain at least one double bond
C)contain at least one triple bond
D)contain a benzene ring
E)contain both a double and a triple bond
A)have only single bonds
B)contain at least one double bond
C)contain at least one triple bond
D)contain a benzene ring
E)contain both a double and a triple bond
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20
The simplest cycloalkane has ________.
A)one carbon atom
B)two carbon atoms
C)three carbon atoms
D)four carbon atoms
E)five carbon atoms
A)one carbon atom
B)two carbon atoms
C)three carbon atoms
D)four carbon atoms
E)five carbon atoms
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21
What is the IUPAC name for a five-carbon continuous-chain alkane?
A)methane
B)ethane
C)propane
D)butane
E)pentane
A)methane
B)ethane
C)propane
D)butane
E)pentane
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22
What is the IUPAC name of this compound? 
A)1,1-dichlorobutane
B)1,2,-dichlorobutane
C)1,3-dichlorobutane
D)1,4-dichlorobutane
E)dichlorobutane

A)1,1-dichlorobutane
B)1,2,-dichlorobutane
C)1,3-dichlorobutane
D)1,4-dichlorobutane
E)dichlorobutane
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23
According to the IUPAC convention,alkyl substituents on a hydrocarbon chain should be listed in which order?
A)alphabetical including prefixes
B)alphabetical without considering prefixes
C)in order with the substituent having the largest number of carbons first
D)in order with the substituent having the smallest number of carbons first
E)in order with the substituent having the largest total number of carbons first
A)alphabetical including prefixes
B)alphabetical without considering prefixes
C)in order with the substituent having the largest number of carbons first
D)in order with the substituent having the smallest number of carbons first
E)in order with the substituent having the largest total number of carbons first
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24
What is the IUPAC name for a ten-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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25
What is the IUPAC name for an eight-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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26
Compounds that have the same molecular formula but different arrangements of atoms are called ________.
A)isomers
B)isotopes
C)indicators
D)isozymes
E)isometrics
A)isomers
B)isotopes
C)indicators
D)isozymes
E)isometrics
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27
What is the mame for a six-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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28
Isomers are molecules that share the same formula and have ________.
A)a different shape to the molecule
B)the same arrangement of atoms within the molecule
C)a different arrangement of atoms within the molecule
D)identical boiling points
E)the same shape in each molecule
A)a different shape to the molecule
B)the same arrangement of atoms within the molecule
C)a different arrangement of atoms within the molecule
D)identical boiling points
E)the same shape in each molecule
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29
What is the IUPAC name of this compound?

A)2,2-dimethylpentane
B)2,4-dimethylpentane
C)heptane
D)2-methylhexane
E)1,1,3-trimethylbutane

A)2,2-dimethylpentane
B)2,4-dimethylpentane
C)heptane
D)2-methylhexane
E)1,1,3-trimethylbutane
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30
In a condensed structural formula,each carbon atom is ________.
A)shown with all individual atoms and bonds drawn
B)shown with only the other carbon atoms
C)grouped with its bonded hydrogen atoms
D)not explicitly shown
E)written in lowercase letters
A)shown with all individual atoms and bonds drawn
B)shown with only the other carbon atoms
C)grouped with its bonded hydrogen atoms
D)not explicitly shown
E)written in lowercase letters
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31
What is the IUPAC name for a four-carbon continuous-chain alkane?
A)methane
B)ethane
C)propane
D)butane
E)pentane
A)methane
B)ethane
C)propane
D)butane
E)pentane
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32
What is the IUPAC name for a seven-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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33
What is the IUPAC name of the following compound?

A)heptane
B)methylhexane
C)5-methylhexane
D)2-methylhexane
E)2-methylpentane

A)heptane
B)methylhexane
C)5-methylhexane
D)2-methylhexane
E)2-methylpentane
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34
What type of compound is
-
?
A)alkane
B)branched alkane
C)cycloalkane
D)haloalkane
E)isomer



A)alkane
B)branched alkane
C)cycloalkane
D)haloalkane
E)isomer
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35
What is the IUPAC name of the nine-carbon continuous-chain alkane?
A)hexane
B)heptane
C)octane
D)nonane
E)decane
A)hexane
B)heptane
C)octane
D)nonane
E)decane
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36
When drawing a structural formula,the first step is to draw ________.
A)the substituents
B)the most highly substituted carbons
C)the saturated carbons
D)the main carbon chain
E)the functional group
A)the substituents
B)the most highly substituted carbons
C)the saturated carbons
D)the main carbon chain
E)the functional group
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37
According to the IUPAC convention,alkyl group names should be located ________ of the name of the main chain.
A)in front
B)at the end
C)in the middle
A)in front
B)at the end
C)in the middle
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38
What is the IUPAC name for this alkane? 
A)2-ethyl-3-methylpentane
B)4-ethyl-3-methylpentane
C)3,4-dimethylhexane
D)2,3-diethylbutane
E)octane

A)2-ethyl-3-methylpentane
B)4-ethyl-3-methylpentane
C)3,4-dimethylhexane
D)2,3-diethylbutane
E)octane
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39
What is the IUPAC name of the alkyl group
-
-
-?
A)propane
B)methyl
C)ethane
D)ethyl
E)propyl



A)propane
B)methyl
C)ethane
D)ethyl
E)propyl
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40
According to the IUPAC convention for chemical naming,which part of a hydrocarbon is selected as the main chain for a hydrocarbon chain?
A)the most highly branched chain
B)the shortest chain
C)the longest chain drawn in a straight line
D)the longest continuous chain,regardless of bends
E)the chain with the most substituted carbons in it
A)the most highly branched chain
B)the shortest chain
C)the longest chain drawn in a straight line
D)the longest continuous chain,regardless of bends
E)the chain with the most substituted carbons in it
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41
Which of the following compounds could have the molecular formula C7H16 ?
A)hexane
B)pentane
C)2-methylheptane
D)2,3-dimethylpentane
E)3-ethylhexane
A)hexane
B)pentane
C)2-methylheptane
D)2,3-dimethylpentane
E)3-ethylhexane
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42
The reaction for the combustion of heptane is https://storage.examlex.com/TB6077/
. How many liters of CO2 at STP are produced from the complete combustion of 2.00 moles of heptane?
A)44.8 L
B)22.4 L
C)157 L
D)246 L
E)314 L

A)44.8 L
B)22.4 L
C)157 L
D)246 L
E)314 L
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43
A hydrocarbon with a double bond is a(n)________.
A)alkane
B)alkene
C)alkyne
D)alcohol
E)saturated compound
A)alkane
B)alkene
C)alkyne
D)alcohol
E)saturated compound
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44
What is the IUPAC name of this alkane? 
A)4-ethyl-2,2-dimethylpentane
B)2-ethyl-4,4-dimethylpentane
C)2,2,4-trimethylhexane
D)2-ethyl-2,2-dimethylpentane
E)3,5,5-trimethylhexane

A)4-ethyl-2,2-dimethylpentane
B)2-ethyl-4,4-dimethylpentane
C)2,2,4-trimethylhexane
D)2-ethyl-2,2-dimethylpentane
E)3,5,5-trimethylhexane
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45
The complete combustion of 1 mole of pentane H12 ,will require how many moles of oxygen, O2 ?
A)1 mole
B)2 moles
C)5 moles
D)6 moles
E)8 moles
A)1 mole
B)2 moles
C)5 moles
D)6 moles
E)8 moles
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46
What is the name for a three-carbon saturated alkyl group?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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47
An alkyne is an organic compound that contains a ________ bond.
A)single
B)double
C)triple
D)aromatic
E)hydrogen
A)single
B)double
C)triple
D)aromatic
E)hydrogen
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48
What is the IUPAC name of
?
A)pentane
B)methylpentane
C)2-methylpentane
D)4-methylpentane
E)hexane

A)pentane
B)methylpentane
C)2-methylpentane
D)4-methylpentane
E)hexane
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49
An unsaturated compound always ________.
A)is a cycloalkane
B)contains a double bond
C)contains a triple bond
D)contains at least one double or triple bond
E)contains only single bonds
A)is a cycloalkane
B)contains a double bond
C)contains a triple bond
D)contains at least one double or triple bond
E)contains only single bonds
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50
Alkenes and alkynes are called unsaturated compounds because ________.
A)they have the maximum number of hydrogen atoms attached to each carbon in the compound
B)they have fewer hydrogen atoms attached to the carbon chain than alkanes
C)they have more hydrogen atoms attached to the carbon chain than alkanes
D)they have more carbon atoms than alkanes
E)they have fewer carbon atoms than alkanes
A)they have the maximum number of hydrogen atoms attached to each carbon in the compound
B)they have fewer hydrogen atoms attached to the carbon chain than alkanes
C)they have more hydrogen atoms attached to the carbon chain than alkanes
D)they have more carbon atoms than alkanes
E)they have fewer carbon atoms than alkanes
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51
What is the name for this three-carbon alkyl group?
CH3 -CH- CH3
A)propyl
B)isopropyl
C)butyl
D)methyl
E)ethyl
CH3 -CH- CH3
A)propyl
B)isopropyl
C)butyl
D)methyl
E)ethyl
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52
What is the name for a one-carbon alkyl substituent?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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53
An alkene is an organic compound that contains a ________ bond.
A)single
B)double
C)triple
D)aromatic
E)hydrogen
A)single
B)double
C)triple
D)aromatic
E)hydrogen
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54
What is the IUPAC name of 
A)hexane
B)dimethylbutane
C)3,3-dimethylbutane
D)2,2-dimethylbutane
E)2-dimethylbutane

A)hexane
B)dimethylbutane
C)3,3-dimethylbutane
D)2,2-dimethylbutane
E)2-dimethylbutane
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55
What is(are)the product(s)of the complete combustion of any hydrocarbon?
A)CO only
B)
only
C)CO + H2O
D)
+ H2O
E) H2O only
A)CO only
B)

C)CO + H2O
D)

E) H2O only
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56
Which of the compounds is a cycloalkene?
A) CH2=CH-CH=CH2
B)
C) CH3 -CH = CH2
D)
E)
A) CH2=CH-CH=CH2
B)

C) CH3 -CH = CH2
D)

E)

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57
The balanced equation for the complete combustion of
will give which of these product(s)?
A) CO2 only
B) C5H12O5 only
C)5CO2 + 5H20
D)5CO2 +6H20
E)10CO + 12H2O


A) CO2 only
B) C5H12O5 only
C)5CO2 + 5H20
D)5CO2 +6H20
E)10CO + 12H2O
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58
Which of the following pairs of formulas represent isomers?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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59
What is the name for a two-carbon saturated alkyl group?
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
A)methyl
B)ethyl
C)propyl
D)butyl
E)pentyl
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60
The reaction of butane with oxygen is called ________.
A)substitution
B)addition
C)neutralization
D)combustion
E)titration
A)substitution
B)addition
C)neutralization
D)combustion
E)titration
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61
What is the IUPAC name of the compound shown below?

A)2-pentene
B)trans-2-pentene
C)trans-3-pentene
D)cis-2-pentene
E)cis-3-pentene

A)2-pentene
B)trans-2-pentene
C)trans-3-pentene
D)cis-2-pentene
E)cis-3-pentene
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62
The IUPAC name of CH3 -CH
CH- CH3 is ________.
A)2-butene
B)2-butane
C)1-butene
D)butene
E)2-butyne

A)2-butene
B)2-butane
C)1-butene
D)butene
E)2-butyne
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63
Which of the following compounds is an alkyne?
A)

B)

C) CH3-CH2 -C
CH
D) H2C
CH-CH
CH2
E)2-pentene
A)



B)


C) CH3-CH2 -C

D) H2C


E)2-pentene
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64
What is the IUPAC name of the following compound?

A)5-methyl-1-hexene
B)2-methyl-1-hexene
C)2-methyl-5-hexene
D)5-methyl-2-hexene
E)1-hexene

A)5-methyl-1-hexene
B)2-methyl-1-hexene
C)2-methyl-5-hexene
D)5-methyl-2-hexene
E)1-hexene
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65
The reaction of hydrogen ( H2 )and propene using a platinum catalyst is called ________.
A)combustion
B)substitution
C)addition
D)neutralization
E)condensation
A)combustion
B)substitution
C)addition
D)neutralization
E)condensation
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66
Some alkenes have geometric (cis-trans)isomers because ________.
A)the carbon atoms in the double bond cannot rotate
B)each of the carbon atoms in the double bond has four different groups attached to it
C)one of the carbon atoms in the double bond has two identical groups attached to it
D)the carbon atoms in the double bond are free to rotate
E)all of the carbon atoms in the compound are rigid and cannot rotate
A)the carbon atoms in the double bond cannot rotate
B)each of the carbon atoms in the double bond has four different groups attached to it
C)one of the carbon atoms in the double bond has two identical groups attached to it
D)the carbon atoms in the double bond are free to rotate
E)all of the carbon atoms in the compound are rigid and cannot rotate
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67
The compound 1-butyne contains ________.
A)all single bonds
B)a double bond
C)a triple bond
D)a ring structure
E)a bromine atom
A)all single bonds
B)a double bond
C)a triple bond
D)a ring structure
E)a bromine atom
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68
Which of the following pairs of compounds are cis-trans isomers?
A)
and 
B)
and 
C)
D)
and 
E)
and 
A)


B)


C)

D)


E)


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69
The IUPAC name for ethylene is ________.
A)ethane
B)cycloethane
C)ethyne
D)ethanene
E)ethene
A)ethane
B)cycloethane
C)ethyne
D)ethanene
E)ethene
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70
The IUPAC name for CH3-CH2 -C ≡ C-CH3 is ________.
A)3-pentyne
B)2-pentyne
C)pentyne
D)1-methylbutyne
E)2-propene
A)3-pentyne
B)2-pentyne
C)pentyne
D)1-methylbutyne
E)2-propene
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71
When naming an alkene,the parent chain is the longest carbon chain ________.
A)that does not contain the double bond
B)regardless of whether or not it contains the double bond
C)that contains at least one of the carbon atoms of the double bond
D)that contains both atoms of the double bond
E)that contains a branch
A)that does not contain the double bond
B)regardless of whether or not it contains the double bond
C)that contains at least one of the carbon atoms of the double bond
D)that contains both atoms of the double bond
E)that contains a branch
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72
Insects communicate with chemicals called ________.
A)markers
B)isomers
C)signals
D)pheromones
E)scents
A)markers
B)isomers
C)signals
D)pheromones
E)scents
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73
The hydrogenation of an alkene gives a(n)________.
A)alkane
B)alkene
C)alkyne
D)benzene
E)isomer
A)alkane
B)alkene
C)alkyne
D)benzene
E)isomer
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74
Which one of the following compounds has the smallest number of hydrogen atoms?
A)butyne
B)2-methylpropane
C)butene
D)2-methybutane
E)butane
A)butyne
B)2-methylpropane
C)butene
D)2-methybutane
E)butane
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75
What is the condensed structural formula for the compound 3-hexene?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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76
Which of the following compounds is an alkene?
A)
B)
C)
D)
E)cyclopentane
A)

B)

C)

D)

E)cyclopentane
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77
What is the IUPAC name of the compound shown below?

A)3-hexene
B)3-hexyne
C)trans-3-hexene
D)cis-2-hexene
E)cis-3-hexene

A)3-hexene
B)3-hexyne
C)trans-3-hexene
D)cis-2-hexene
E)cis-3-hexene
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78
What is the IUPAC name for the following compound? 
A)4-chloro-4,5-dimethyl-2-hexene
B)3-chloro-1,3,4-trimethyl-1-pentene
C)3-chloro-2,3-dimethyl-4-hexene
D)3-chloro-2,3,5-trimethyl-4-pentene
E)3-chloro-1,3,4,4-tetramethyl-1-butene

A)4-chloro-4,5-dimethyl-2-hexene
B)3-chloro-1,3,4-trimethyl-1-pentene
C)3-chloro-2,3-dimethyl-4-hexene
D)3-chloro-2,3,5-trimethyl-4-pentene
E)3-chloro-1,3,4,4-tetramethyl-1-butene
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79
Organic compounds with carbon-carbon double or triple bonds are classified as ________.
A)unsaturated compounds
B)saturated compounds
C)dilute solutions
D)concentrated solutions
E)substituted compounds
A)unsaturated compounds
B)saturated compounds
C)dilute solutions
D)concentrated solutions
E)substituted compounds
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80
What is the condensed structural formula of the compound propene?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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