Deck 14: Aqueous Equilibria: Acids and Bases
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Deck 14: Aqueous Equilibria: Acids and Bases
1
An Arrhenius base is best defined as a
A)proton donor.
B)hydroxide acceptor.
C)substance that dissociates in water to produce aqueous hydrogen ions.
D)substance that dissociates in water to produce aqueous hydroxide ions.
A)proton donor.
B)hydroxide acceptor.
C)substance that dissociates in water to produce aqueous hydrogen ions.
D)substance that dissociates in water to produce aqueous hydroxide ions.
substance that dissociates in water to produce aqueous hydroxide ions.
2
When dissolved in water,which of the following compounds is an Arrhenius base?
A)CH3OH
B)HOCl
C)KOH
D)KCl
A)CH3OH
B)HOCl
C)KOH
D)KCl
KOH
3
Which Br∅nsted-Lowry acid has the strongest conjugate base?
A)HBr
B)HClO4
C)HF
D)HI
A)HBr
B)HClO4
C)HF
D)HI
HF
4
A Br∅nsted-Lowry acid is best defined as a substance that can
A)accept a hydroxide ion.
B)donate a hydroxide ion.
C)accept a proton.
D)donate a proton.
A)accept a hydroxide ion.
B)donate a hydroxide ion.
C)accept a proton.
D)donate a proton.
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5
What is the conjugate base of the Br∅nsted-Lowry acid HPO42-?
A)H3PO4
B)H2PO4-
C)HPO42-
D)PO43-
A)H3PO4
B)H2PO4-
C)HPO42-
D)PO43-
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6
What is the strongest Br∅nsted-Lowry acid in the chemical reaction shown below?
2 HNO3(aq)+ Ba(OH)2(aq)→ Ba(NO3)2(aq)+ 2 H2O(l)
A)HNO3
B)Ba(OH)2
C)Ba(NO3)2
D)H2O
2 HNO3(aq)+ Ba(OH)2(aq)→ Ba(NO3)2(aq)+ 2 H2O(l)
A)HNO3
B)Ba(OH)2
C)Ba(NO3)2
D)H2O
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7
Write a balanced equation for the dissociation of the Br∅nsted-Lowry acid HSO4- in water.
A)HSO4-(aq)+ H2O(l)⇌ H2SO4(aq)+ OH-(aq)
B)HSO4-(aq)+ H2O(l)⇌ SO42-(aq)+ H3O+(aq)
C)HSO4-(aq)+ H2O(l)⇌ SO32-(aq)+ OH-(aq)
D)HSO4-(aq)+ H2O(l)⇌ SO3(g)+ OH-(aq)+ H2O(l)
A)HSO4-(aq)+ H2O(l)⇌ H2SO4(aq)+ OH-(aq)
B)HSO4-(aq)+ H2O(l)⇌ SO42-(aq)+ H3O+(aq)
C)HSO4-(aq)+ H2O(l)⇌ SO32-(aq)+ OH-(aq)
D)HSO4-(aq)+ H2O(l)⇌ SO3(g)+ OH-(aq)+ H2O(l)
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8
When dissolved in water,which of the following compounds is an Arrhenius acid?
A)HCN
B)NaOH
C)NaF
D)CH3CH2OH
A)HCN
B)NaOH
C)NaF
D)CH3CH2OH
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9
In the following chemical equation indicate the reactant that is a Br∅nsted-Lowry acid.
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCN
B)H2O
C)H3O+
D)CN-
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCN
B)H2O
C)H3O+
D)CN-
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10
An Arrhenius acid is best defined as a
A)hydroxide donor.
B)proton acceptor.
C)substance that dissociates in water to produce aqueous hydrogen ions.
D)substance that dissociates in water to produce aqueous hydroxide ions.
A)hydroxide donor.
B)proton acceptor.
C)substance that dissociates in water to produce aqueous hydrogen ions.
D)substance that dissociates in water to produce aqueous hydroxide ions.
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11
What are the conjugate acid-base pairs in the following chemical reaction?
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)NH3,H2O and NH4+,OH-
B)NH3,NH4+ and H2O,OH-
C)NH3,OH- and H2O,NH4+
D)NH3 and NH4+
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)NH3,H2O and NH4+,OH-
B)NH3,NH4+ and H2O,OH-
C)NH3,OH- and H2O,NH4+
D)NH3 and NH4+
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12
Which one of the following can behave either as a Br∅nsted-Lowry acid or a Br∅nsted-Lowry base in an aqueous solution reaction?
A)HSO3-
B)NH3
C)HI
D)H3PO4
A)HSO3-
B)NH3
C)HI
D)H3PO4
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13
What is the conjugate acid of the Br∅nsted-Lowry base HAsO42-?
A)H2AsO4-
B)AsO43-
C)H2O
D)H3O+
A)H2AsO4-
B)AsO43-
C)H2O
D)H3O+
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14
What are the Br∅nsted-Lowry bases in the following chemical reaction?
C5H5N(aq)+ H2O(l)⇌ C5H5NH+(aq)+ OH-(aq)
A)C5H5N,H2O
B)C5H5N,C5H5NH+
C)C5H5N,OH-
D)C5H5N,H2O,OH-
C5H5N(aq)+ H2O(l)⇌ C5H5NH+(aq)+ OH-(aq)
A)C5H5N,H2O
B)C5H5N,C5H5NH+
C)C5H5N,OH-
D)C5H5N,H2O,OH-
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15
What are the Br∅nsted-Lowry acids in the following chemical reaction?
HBr(sol)+ CH3COOH(sol)⇌ CH3C(OH)2+(sol)+ Br-(sol)
A)HBr,CH3COOH
B)HBr,CH3C(OH)2+
C)CH3COOH,CH3C(OH)2+
D)CH3COOH,Br-
HBr(sol)+ CH3COOH(sol)⇌ CH3C(OH)2+(sol)+ Br-(sol)
A)HBr,CH3COOH
B)HBr,CH3C(OH)2+
C)CH3COOH,CH3C(OH)2+
D)CH3COOH,Br-
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16
Which of the following Br∅nsted-Lowry acids does not behave as a strong acid when it is dissolved in water?
A)HBr
B)HCl
C)HNO2
D)HClO4
A)HBr
B)HCl
C)HNO2
D)HClO4
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17
Identify the conjugate acid/base pairs present in an aqueous solution of hydrogen sulfate ion,
HSO4-.
A)HSO4-/SO42- and H3O+/H2O
B)H2SO4/HSO4- and H2O/OH-
C)HSO4-/H2O and H3O+/SO42-
D)HSO4-/H2O and H2SO4/OH-
HSO4-.
A)HSO4-/SO42- and H3O+/H2O
B)H2SO4/HSO4- and H2O/OH-
C)HSO4-/H2O and H3O+/SO42-
D)HSO4-/H2O and H2SO4/OH-
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18
Which Br∅nsted-Lowry base has the strongest conjugate acid?
A)CH3CO2-
B)CN-
C)F-
D)NO3-
A)CH3CO2-
B)CN-
C)F-
D)NO3-
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19
Indicate all the Br∅nsted-Lowry acids in the following chemical reaction.
HCl(aq)+ H2O(aq)⇌ H3O+(aq)+ Cl-(aq)
A)HCl,H2O
B)HCl,H3O+
C)HCl,Cl-
D)HCl,H2O,H3O+
HCl(aq)+ H2O(aq)⇌ H3O+(aq)+ Cl-(aq)
A)HCl,H2O
B)HCl,H3O+
C)HCl,Cl-
D)HCl,H2O,H3O+
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20
Which one of the following species acts as a Br∅nsted-Lowry acid in water?
A)NaH
B)NH4+
C)CH3NH2
D)C6H6
A)NaH
B)NH4+
C)CH3NH2
D)C6H6
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21
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest).
HClO4(aq)+ H2O(l)→ H3O+(aq)+ ClO4-(aq)
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq)
A)HClO4 > H3O+ > HNO2
B)HClO4 > HNO2 > H3O+
C)H3O+ > HClO4 > HNO2
D)H3O+ > HNO2 > HClO4
HClO4(aq)+ H2O(l)→ H3O+(aq)+ ClO4-(aq)
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq)
A)HClO4 > H3O+ > HNO2
B)HClO4 > HNO2 > H3O+
C)H3O+ > HClO4 > HNO2
D)H3O+ > HNO2 > HClO4
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22
What is the geometric shape of the hydrated proton;that is,the hydronium ion H3O+?
A)angular
B)pyramidal
C)trigonal planar
D)tetrahedral
A)angular
B)pyramidal
C)trigonal planar
D)tetrahedral
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23
The following pictures represent aqueous solutions of binary acids of the type HA where the water molecules have been omitted for clarity. 
Arrange the acids in order of increasing acid strength.
A)D < C < A < B
B)D < C < B < A
C)D < B < A < C
D)D < A < C < B

Arrange the acids in order of increasing acid strength.
A)D < C < A < B
B)D < C < B < A
C)D < B < A < C
D)D < A < C < B
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24
Calculate the hydronium ion concentration in an aqueous solution that contains 2.50 × 10-4 M in hydroxide ion.
A)4)00 × 10-9 M
B)4)00 × 10-10 M
C)4)00 × 10-11 M
D)5)00 × 10-11 M
A)4)00 × 10-9 M
B)4)00 × 10-10 M
C)4)00 × 10-11 M
D)5)00 × 10-11 M
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25
An acidic solution at 25°C has
A)[H3O+] > [OH-] > 1 × 10-7 M.
B)[H3O+] > 1 × 10-7 M > [OH-].
C)[H3O+] = [OH-] > 1 × 10-7 M.
D)[H3O+] < 1 × 10-7 M > [OH-].
A)[H3O+] > [OH-] > 1 × 10-7 M.
B)[H3O+] > 1 × 10-7 M > [OH-].
C)[H3O+] = [OH-] > 1 × 10-7 M.
D)[H3O+] < 1 × 10-7 M > [OH-].
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26
Calculate the hydroxide ion concentration in an aqueous solution that contains 3.50 × 10-3 M in hydronium ion.
A)2)86 × 10-4 M
B)2)86 × 10-11 M
C)2)86 × 10-12 M
D)3)50 × 10-12 M
A)2)86 × 10-4 M
B)2)86 × 10-11 M
C)2)86 × 10-12 M
D)3)50 × 10-12 M
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27
Which is not a hydrate of a proton?
A)H3O+
B)H9O4+
C)H25O11+
D)H43O21+
A)H3O+
B)H9O4+
C)H25O11+
D)H43O21+
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28
A solution with a hydrogen ion concentration of 3.25 × 10-2 M is ________ and has a hydroxide concentration of ________.
A)acidic,3.08 × 10-12 M
B)acidic,3.08 × 10-13 M
C)basic,3.08 × 10-12 M
D)basic,3.08 × 10-13 M
A)acidic,3.08 × 10-12 M
B)acidic,3.08 × 10-13 M
C)basic,3.08 × 10-12 M
D)basic,3.08 × 10-13 M
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29
The following pictures represent aqueous solutions of binary acids of the type HA where the water molecules have been omitted for clarity. 
Determine the strongest acid of the set.
A)A
B)B
C)C
D)D

Determine the strongest acid of the set.
A)A
B)B
C)C
D)D
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30
At 50°C the value of Kw is 5.5 × 10-14.A basic solution at 50°C has
A)[H3O+] < [OH-] < 2 × 10-7 M.
B)[H3O+] < 2 × 10-7 M < [OH-].
C)[H3O+] = [OH-] < 2 × 10-7 M.
D)[H3O+] > 2 × 10-7 M < [OH-].
A)[H3O+] < [OH-] < 2 × 10-7 M.
B)[H3O+] < 2 × 10-7 M < [OH-].
C)[H3O+] = [OH-] < 2 × 10-7 M.
D)[H3O+] > 2 × 10-7 M < [OH-].
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31
Normal rainfall has a concentration of OH- that is 3.98 × 10-9.The concentration of H3O+ in normal rainfall is
A)greater than 3.98 × 10-9,and the rain is acidic.
B)greater than 3.98 × 10-9,and the rain is basic.
C)less than 3.98 × 10-9,and the rain is acidic.
D)less than 3.98 × 10-9,and the rain is basic.
A)greater than 3.98 × 10-9,and the rain is acidic.
B)greater than 3.98 × 10-9,and the rain is basic.
C)less than 3.98 × 10-9,and the rain is acidic.
D)less than 3.98 × 10-9,and the rain is basic.
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32
From the following chemical reactions determine the relative Br∅nsted-Lowry base strengths (strongest to weakest).
2 NaH(s)+ H2O(l)→ 2 NaOH + H2(g)
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)H- > OH- > NH3
B)H- > NH3 > OH-
C)OH-> H- > NH3
D)OH- > NH3 > H-
2 NaH(s)+ H2O(l)→ 2 NaOH + H2(g)
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)H- > OH- > NH3
B)H- > NH3 > OH-
C)OH-> H- > NH3
D)OH- > NH3 > H-
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33
From the following chemical reactions determine the relative Br∅nsted-Lowry base strengths (strongest to weakest).
HNO3(aq)+ H2O(l)→ H3O+(aq)+ NO3-(aq)
HF(aq)+ H2O(l)⇌ H3O+(aq)+ F-(aq)
A)HNO3 > H3O+ > HF
B)NO3- > H2O > F-
C)F- > H2O > NO3-
D)F- > NO3- > H2O
HNO3(aq)+ H2O(l)→ H3O+(aq)+ NO3-(aq)
HF(aq)+ H2O(l)⇌ H3O+(aq)+ F-(aq)
A)HNO3 > H3O+ > HF
B)NO3- > H2O > F-
C)F- > H2O > NO3-
D)F- > NO3- > H2O
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34
A solution with a hydroxide ion concentration of 4.15 × 10-4 M is ________ and has a hydrogen ion concentration of ________.
A)acidic,2.41 × 10-10 M
B)acidic,2.41 × 10-11 M
C)basic,2.41 × 10-10 M
D)basic,2.41 × 10-11 M
A)acidic,2.41 × 10-10 M
B)acidic,2.41 × 10-11 M
C)basic,2.41 × 10-10 M
D)basic,2.41 × 10-11 M
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35
If the ionization constant of water,Kw,at 40°C is 2.92 × 10-14,then what is the hydronium ion concentration for a neutral solution?
A)[H3O+] < 1.00 × 10-7 M
B)[H3O+] > 1.71 × 10-7 M
C)[H3O+] = 1.71 × 10-7 M
D)[H3O+] < 1.71 × 10-7 M
A)[H3O+] < 1.00 × 10-7 M
B)[H3O+] > 1.71 × 10-7 M
C)[H3O+] = 1.71 × 10-7 M
D)[H3O+] < 1.71 × 10-7 M
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36
Using the conjugate acid-base pairs listed below,complete the following equation with the pair that gives an equilibrium constant Kc > 1.
_____ + HSO3- ⇌ _____ + H2SO3
A)CH3CO2H/ CH3CO2-
B)HCO2H/ HCO2-
C)HNO2/NO2-
D)HNO3/NO3-
_____ + HSO3- ⇌ _____ + H2SO3
A)CH3CO2H/ CH3CO2-
B)HCO2H/ HCO2-
C)HNO2/NO2-
D)HNO3/NO3-
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37
Using the conjugate acid-base pairs listed below,complete the following equation with the pair that gives an equilibrium constant Kc > 1.
_____ + H2CO3 ⇌ _____ + HCO3-
A)HF/F-
B)HCl/Cl-
C)HOCl/OCl-
D)HSO42-/SO42-
_____ + H2CO3 ⇌ _____ + HCO3-
A)HF/F-
B)HCl/Cl-
C)HOCl/OCl-
D)HSO42-/SO42-
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38
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest).
HClO4(sol)+ CH3COOH(l)→ CH3C2(OH)2+(sol)+ ClO4-(aq)
H2SO4(sol)+ CH3COOH(l)⇌ CH3C(OH)2+(sol)+ HSO4-(sol)
A)HClO4 > H2SO4 > CH3COOH
B)HClO4 > H2SO4 > CH3C(OH)2+
C)HClO4 > CH3COOH > H2SO4
D)HClO4 > CH3C(OH)2+ > H2SO4
HClO4(sol)+ CH3COOH(l)→ CH3C2(OH)2+(sol)+ ClO4-(aq)
H2SO4(sol)+ CH3COOH(l)⇌ CH3C(OH)2+(sol)+ HSO4-(sol)
A)HClO4 > H2SO4 > CH3COOH
B)HClO4 > H2SO4 > CH3C(OH)2+
C)HClO4 > CH3COOH > H2SO4
D)HClO4 > CH3C(OH)2+ > H2SO4
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39
The equilibrium constant,K,for the reaction shown below has a value 1.8 × 10-5.In this reaction which is the strongest acid and which is the strongest base?
CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq)
A)CH3CO2H and CH3CO2-
B)CH3CO2H and H2O
C)H3O+ and H2O
D)H3O+ and CH3CO2-
CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq)
A)CH3CO2H and CH3CO2-
B)CH3CO2H and H2O
C)H3O+ and H2O
D)H3O+ and CH3CO2-
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40
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest).
HCl(aq)+ H2O(l)→ H3O+(aq)+ Cl-(aq)
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCl > HCN > H3O+
B)HCl > H3O+ > HCN
C)H3O+ > HCl > HCN
D)HCN > H3O+ > HCl
HCl(aq)+ H2O(l)→ H3O+(aq)+ Cl-(aq)
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCl > HCN > H3O+
B)HCl > H3O+ > HCN
C)H3O+ > HCl > HCN
D)HCN > H3O+ > HCl
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41
At 25°C,the pH of a vinegar solution is 2.60.What are the values of [H3O+] and [OH-] in the solution?
A)3)99 × 10-12 M,2.51 × 10-3 M
B)2)51 × 10-3 M,3.98 × 10-12 M
C)2)51 × 10-3 M,11.40 M
D)2)60 M,11.40 M
A)3)99 × 10-12 M,2.51 × 10-3 M
B)2)51 × 10-3 M,3.98 × 10-12 M
C)2)51 × 10-3 M,11.40 M
D)2)60 M,11.40 M
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42
What is the hydroxide ion concentration and the pH for a hydrochloric acid solution that has a hydronium ion concentration of 1.50 × 10-4 M?
A)6)67 × 10-10 M,4.82
B)6)67 × 10-10 M,9.18
C)6)67 × 10-11 M,3.82
D)6)67 × 10-11 M,10.18
A)6)67 × 10-10 M,4.82
B)6)67 × 10-10 M,9.18
C)6)67 × 10-11 M,3.82
D)6)67 × 10-11 M,10.18
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43
What is the hydronium ion concentration of an acid rain sample that has a pH of 3.15?
A)1)41 × 10-11 M
B)7)08 × 10-4 M
C)3)15 M
D)10.85 M
A)1)41 × 10-11 M
B)7)08 × 10-4 M
C)3)15 M
D)10.85 M
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44
An acidic solution at 25°C will have a hydronium ion concentration ________ and a pH value ________.
A)[H3O+] > 1 × 10-7 M,pH > 7.00
B)[H3O+] > 1 × 10-7 M,pH < 7.00
C)[H3O+] < 1 × 10-7 M,pH > 7.00
D)[H3O+] < 1 × 10-7 M,pH < 7.00
A)[H3O+] > 1 × 10-7 M,pH > 7.00
B)[H3O+] > 1 × 10-7 M,pH < 7.00
C)[H3O+] < 1 × 10-7 M,pH > 7.00
D)[H3O+] < 1 × 10-7 M,pH < 7.00
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45
What is the hydroxide ion concentration of a lye solution that has a pH of 11.20?
A)6)31 × 10-12 M
B)1)58 × 10-3 M
C)2)80 M
D)11.20 M
A)6)31 × 10-12 M
B)1)58 × 10-3 M
C)2)80 M
D)11.20 M
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46
What is the hydronium ion concentration and the pH for an aqueous solution of NH3 that has a hydroxide ion concentration of 2.25 × 10-3 M?
A)4)44 × 10-11 M,3.65
B)4)44 × 10-11 M,10.35
C)4)44 × 10-12 M,2.65
D)4)44 × 10-12 M,11.35
A)4)44 × 10-11 M,3.65
B)4)44 × 10-11 M,10.35
C)4)44 × 10-12 M,2.65
D)4)44 × 10-12 M,11.35
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47
What is the pH of a solution prepared by dissolving 0.15 gram of solid CaO (lime)in enough water to make 2.00 L of aqueous Ca(OH)2 (limewater)?
CaO(s)+ H2O(l)→ Ca2+(aq)+ 2 OH-(aq)
A)2)57
B)2)87
C)11.13
D)11.43
CaO(s)+ H2O(l)→ Ca2+(aq)+ 2 OH-(aq)
A)2)57
B)2)87
C)11.13
D)11.43
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48
Human tears have a concentration of H3O+ that is 3.16 × 10-8.The concentration of OH- in human tears is
A)greater than 3.16 × 10-7 and tears are acidic.
B)greater than 3.16 ×10-7 and tears are basic.
C)less than 3.16 × 10-7 and tears are acidic.
D)less than 3.16 × 10-7 and tears are basic.
A)greater than 3.16 × 10-7 and tears are acidic.
B)greater than 3.16 ×10-7 and tears are basic.
C)less than 3.16 × 10-7 and tears are acidic.
D)less than 3.16 × 10-7 and tears are basic.
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49
What is the pH of a 0.020 M Ba(OH)2 solution?
A)1)40
B)1)70
C)12.30
D)12.60
A)1)40
B)1)70
C)12.30
D)12.60
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50
What is the pH of a 0.020 M HClO4 solution?
A)0)020
B)0)040
C)1)70
D)12.30
A)0)020
B)0)040
C)1)70
D)12.30
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51
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)4)8 - 6.0
B)6)0 - 7.6
C)7)6 - 8.2
D)> 8.2

A)4)8 - 6.0
B)6)0 - 7.6
C)7)6 - 8.2
D)> 8.2
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52
Calculate the pH for an aqueous solution of pyridine that contains 2.15 × 10-4 M hydroxide ion.
A)4)65 × 10-11
B)2)15 × 10-4
C)3)67
D)10.33
A)4)65 × 10-11
B)2)15 × 10-4
C)3)67
D)10.33
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53
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)3)2 - 4.4
B)4)8 - 6.0
C)6)0 - 7.6
D)8)2 - 10.0

A)3)2 - 4.4
B)4)8 - 6.0
C)6)0 - 7.6
D)8)2 - 10.0
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54
What is the pH of a solution prepared by diluting 25.00 mL of 0.10 M HCl with enough water to produce a total volume of 100.00 mL?
A)1)00
B)1)60
C)2)00
D)3)20
A)1)00
B)1)60
C)2)00
D)3)20
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55
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)3)2 - 4.4
B)4)8 - 6.0
C)6)0 - 7.6
D)8)2 - 10.0

A)3)2 - 4.4
B)4)8 - 6.0
C)6)0 - 7.6
D)8)2 - 10.0
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56
If the ionization constant of water,Kw,at 40°C is 2.92 × 10-14,then what is the hydronium ion concentration and pH for an acidic solution?
A)[H3O+] > 1.71 × 10-7 M and pH > 6.77
B)[H3O+] > 1.71 × 10-7 M and pH < 6.77
C)[H3O+] < 1.71 × 10-7 M and pH > 6.77
D)[H3O+] < 1.71 × 10-7 M and pH < 6.77
A)[H3O+] > 1.71 × 10-7 M and pH > 6.77
B)[H3O+] > 1.71 × 10-7 M and pH < 6.77
C)[H3O+] < 1.71 × 10-7 M and pH > 6.77
D)[H3O+] < 1.71 × 10-7 M and pH < 6.77
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57
Calculate the pH for an aqueous solution of acetic acid that contains 2.15 × 10-3 M hydronium ion.
A)4)65 × 10-12
B)2)15 × 10-3
C)2)67
D)11.33
A)4)65 × 10-12
B)2)15 × 10-3
C)2)67
D)11.33
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58
What statement is most consistent for an acid with a pH = 3?
A)one one-hundredth as strong as an acid with a pH of 5
B)half a strong as an acid with a pH = 5
C)twice as strong as an acid with a pH of 5
D)one hundred times as strong as an acid with a pH = 5
A)one one-hundredth as strong as an acid with a pH of 5
B)half a strong as an acid with a pH = 5
C)twice as strong as an acid with a pH of 5
D)one hundred times as strong as an acid with a pH = 5
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59
What is the pH of a 0.020 M RbOH solution?
A)0)020
B)0)040
C)1)70
D)12.30
A)0)020
B)0)040
C)1)70
D)12.30
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60
What is the pH of a solution prepared by diluting 25.00 mL of 0.020 M Ba(OH)2 with enough water to produce a total volume of 250.00 mL?
A)2)40
B)2)70
C)11.30
D)11.60
A)2)40
B)2)70
C)11.30
D)11.60
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61
The pH of 0.150 M CH3CO2H,acetic acid,is 2.78.What is the value of Ka for acetic acid?
A)2)8 × 10-6
B)1)9 × 10-5
C)1)7 × 10-3
D)1)1 × 10-2
A)2)8 × 10-6
B)1)9 × 10-5
C)1)7 × 10-3
D)1)1 × 10-2
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62
Vinegar is a 5.0% solution by weight of acetic acid (CH3CO2H)in water.Given that the pH for acetic acid is 2.41,the Ka = 1.8 × 10-5 and assuming the density of vinegar to be 1.00 g/cm3,what is the percent dissociation of acetic acid in vinegar?
A)0)47%
B)1)5%
C)4)0%
D)5)0%
A)0)47%
B)1)5%
C)4)0%
D)5)0%
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63
What is the equilibrium constant expression (Ka)for the acid dissociation of nitrous acid HNO2? The equation of interest is
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)Ka = ([H3O+][NO2-])/([HNO2][H2O])
B)Ka = ([H3O+][NO2-])/([HNO2])
C)Ka = ([HNO2][H2O])/([H3O+][NO2-])
D)Ka = ([HNO2])/([H3O+][NO2-])
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)Ka = ([H3O+][NO2-])/([HNO2][H2O])
B)Ka = ([H3O+][NO2-])/([HNO2])
C)Ka = ([HNO2][H2O])/([H3O+][NO2-])
D)Ka = ([HNO2])/([H3O+][NO2-])
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64
What is the pH of a solution made by mixing 100.0 mL of 0.10 M HNO3,50.0 mL of 0.20 M HCl,and 100.0 mL of water? Assume that the volumes are additive.
A)0)30
B)0)82
C)1)00
D)1)10
A)0)30
B)0)82
C)1)00
D)1)10
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65
Determine the acid dissociation constant for a 0.10 M acetic acid solution that has a pH of 2.87.Acetic acid is a weak monoprotic acid and the equilibrium equation of interest is
CH3COOH(aq)+ H2O(l)⇌H3O+(aq)+ CH3CO23-(aq)
A)1)3 × 10-2
B)1)3 × 10-3
C)1)8 × 10-5
D)1)8 × 10-6
CH3COOH(aq)+ H2O(l)⇌H3O+(aq)+ CH3CO23-(aq)
A)1)3 × 10-2
B)1)3 × 10-3
C)1)8 × 10-5
D)1)8 × 10-6
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66
Potassium hydrogen phthalate (molar mass = 204.2 g/mol)is one of the most commonly used acids for standardizing solutions containing bases.KHP is a monoprotic weak acid with Ka = 3.91 × 10-6.Calculate the pH of the solution that results when 0.40 g of KHP is dissolved in enough water to produce 25.0 mL of solution.
A)2)10
B)3)26
C)4)30
D)5)41
A)2)10
B)3)26
C)4)30
D)5)41
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67
Para-Aminobenzoic acid (PABA),p-H2NC6H4(COOH),is used in some sunscreens and hair conditioning products.Calculate the pH of an aqueous solution with [PABA] = 0.030 M and
Ka = 2.2 × 10-5.
A)1)52
B)3)09
C)4)66
D)6)18
Ka = 2.2 × 10-5.
A)1)52
B)3)09
C)4)66
D)6)18
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68
What is the hydronium ion concentration of a 0.100 M hypochlorous acid solution with
Ka = 3.5 × 10-8? The equation for the dissociation of hypochlorous acid is:
HOCl(aq)+ H2O(l)⇌ H3O+(aq)+ OCl-(aq).
A)1)9 × 10-4
B)5)9 × 10-4
C)1)9 × 10-5
D)5)9 × 10-5
Ka = 3.5 × 10-8? The equation for the dissociation of hypochlorous acid is:
HOCl(aq)+ H2O(l)⇌ H3O+(aq)+ OCl-(aq).
A)1)9 × 10-4
B)5)9 × 10-4
C)1)9 × 10-5
D)5)9 × 10-5
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69
What is the equilibrium constant expression (Ka)for the acid dissociation of hydrocyanic acid HCN? The equation of interest is
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq).
A)Ka = ([H3O+][CN-])/([HCN][H2O])
B)Ka = ([H3O+][CN-])/([HCN])
C)Ka = ([HCN][H2O])/([H3O+][CN-])
D)Ka = ([HCN])/([H3O+][CN-])
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq).
A)Ka = ([H3O+][CN-])/([HCN][H2O])
B)Ka = ([H3O+][CN-])/([HCN])
C)Ka = ([HCN][H2O])/([H3O+][CN-])
D)Ka = ([HCN])/([H3O+][CN-])
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70
What is the pH of a solution made by mixing 100.00 mL of 0.20 M HCl with 50.00 mL of 0.10 M HCl? Assume that the volumes are additive.
A)0)15
B)0)52
C)0)78
D)1)70
A)0)15
B)0)52
C)0)78
D)1)70
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71
Determine the acid dissociation constant for a 0.020 M formic acid solution that has a pH of 2.74.Formic acid is a weak monoprotic acid and the equilibrium equation of interest is
HCOOH(aq)+ H2O(l)⇌ H3O+(aq)+ HCO2-(aq).
A)1)8 × 10-3
B)1)8 × 10-4
C)3)6 × 10-4
D)3)6 × 10-5
HCOOH(aq)+ H2O(l)⇌ H3O+(aq)+ HCO2-(aq).
A)1)8 × 10-3
B)1)8 × 10-4
C)3)6 × 10-4
D)3)6 × 10-5
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72
What is the hydronium ion concentration of a 0.100 M acetic acid solution with a Ka = 1.8 × 10-5? The equation for the dissociation of acetic acid is:
CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq).
A)1)3 × 10-2 M
B)4)2 × 10-2 M
C)1)3 × 10-3 M
D)4)2 × 10-3 M
CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq).
A)1)3 × 10-2 M
B)4)2 × 10-2 M
C)1)3 × 10-3 M
D)4)2 × 10-3 M
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73
Benzoic acid (C6H5CO2H = HBz)solutions are sometimes used in experiments to determine the molarity of a basic solution of unknown concentration.What is the pH of a 0.100 M solution of benzoic acid if Ka = 6.5 × 10-5 and the equilibrium equation of interest is
HBz(aq)+ H2O(l)⇌ H3O+ + Bz-(aq)?
A)1)00
B)2)59
C)4)19
D)5)19
HBz(aq)+ H2O(l)⇌ H3O+ + Bz-(aq)?
A)1)00
B)2)59
C)4)19
D)5)19
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74
The pH of 0.255 M HCN is 4.95.What is the value of Ka for hydrocyanic acid?
A)1)3 × 10-10
B)4)9 × 10-10
C)1)1 × 10-5
D)4)4 × 10-5
A)1)3 × 10-10
B)4)9 × 10-10
C)1)1 × 10-5
D)4)4 × 10-5
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75
What is the pH of a solution prepared by mixing 100.00 mL of 0.020 M Ca(OH)2 with 50.00 mL of 0.100 M NaOH? Assume that the volumes are additive.
A)12.67
B)12.78
C)12.95
D)13.25
A)12.67
B)12.78
C)12.95
D)13.25
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76
What is the percent dissociation of a benzoic acid solution with pH = 2.59? The acid dissociation constant for this monoprotic acid is 6.5 × 10-5.
A)0)50%
B)1)5%
C)2)5%
D)3)5%
A)0)50%
B)1)5%
C)2)5%
D)3)5%
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77
Determine the acid dissociation constant for a 0.010 M nitrous acid solution that has a pH of 2.70.Nitrous acid is a weak monoprotic acid and the equilibrium equation of interest is
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)8)0 × 10-3
B)2)0 × 10-3
C)5)0 × 10-4
D)4)0 × 10-4
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)8)0 × 10-3
B)2)0 × 10-3
C)5)0 × 10-4
D)4)0 × 10-4
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78
Vinegar is a 5.0% solution by weight of acetic acid (CH3CO2H)in water.Given that
Ka = 1.8 × 10-5 for acetic acid and assuming the density of vinegar to be 1.00 g/cm3,what is the pH of this vinegar solution?
A)2)00
B)2)41
C)2)87
D)4)74
Ka = 1.8 × 10-5 for acetic acid and assuming the density of vinegar to be 1.00 g/cm3,what is the pH of this vinegar solution?
A)2)00
B)2)41
C)2)87
D)4)74
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79
A tablet containing 500.0 mg of aspirin (acetylsalicylic acid or HC9H7O4)was dissolved in enough water to make 100 mL of solution.Given that Ka = 3.0 × 10-4 for aspirin,what is the pH of the solution?
A)1)57
B)2)54
C)3)52
D)5)08
A)1)57
B)2)54
C)3)52
D)5)08
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80
What is the strongest monoprotic acid of the following set if all the acids are at 0.100 M concentration?
A)hydrofluoric acid with Ka = 3.5 × 10-4
B)benzoic acid with Ka = 6.5 × 10-5
C)acetic acid with Ka = 1.8 × 10-5
D)hypochlorous acid with Ka = 3.5 × 10-8
A)hydrofluoric acid with Ka = 3.5 × 10-4
B)benzoic acid with Ka = 6.5 × 10-5
C)acetic acid with Ka = 1.8 × 10-5
D)hypochlorous acid with Ka = 3.5 × 10-8
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