Deck 13: Condensation and Hydrolysis Reactions
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Deck 13: Condensation and Hydrolysis Reactions
1
ATP provides the metabolic link between anabolism and catabolism.
True
2
The following is an example of a phosphodiester. 

True
3
Amidation reactions would be part of a catabolic pathway.
False
4
pH has little effect on the products of hydrolysis reactions.
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5
Alkaline phosphatase is an enzyme involved in some of the hydrolysis reactions in the human body.
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6
When the following "protein" formed, five molecules of water were produced. 

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7
When three molecules of the amino acid alanine, shown below, react
the polymer segment formed would be: 


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8
A carbohydrate is a polymer composed of simple sugar units.
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9
Consider the following reaction.
If the energy used for the reaction is obtained from ATP, the reaction will go to completion.

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10
Consider the following reaction.
This reaction is a hydrolysis reaction.

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11
During dehydration reactions, the hydrogen atom maybe removed from an oxygen atom whereas in a condensation reaction the hydrogen is removed from a carbon atom.
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12
An amine is a stronger base than an amide.
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13
Like a thioester, an amide contains a carbonyl group.
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14
If two molecules of a 1-butanol undergo a condensation reaction, the product of the reaction must be dibutyl ether.
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15
The bond enclosed in the circle forms during an esterification reaction. 

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16
Consider the structure of propyl myristate.
Saponification using KOH would produce the "soap" shown below. 


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17
The structure for dipropyl ether is: 

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18
The following type of reaction is utilized by biological systems in obtaining large amounts of energy from food. 

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19
The following molecule was formed from the reaction of four alcohol molecules. 

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20
The formation of a copolymer requires that three different molecules react to form the polymer.
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21
During catabolism as nutrients are burned, the carbon atoms of the organic molecules end up as carbon dioxide and the hydrogen atoms end up as H+.
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22
What is the organic product of the following reaction if carried out at 110 °C? 
A)
B)
C)
D)
E)

A)

B)

C)

D)

E)

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23
If oxalic acid which contains two carboxylic acids groups and ethylene diamine which contains two amine groups react, the type of bond formed in the polymers is
A)an ester.
B)an ether.
C)an amide.
D)a phosphoester.
A)an ester.
B)an ether.
C)an amide.
D)a phosphoester.
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24
In the formation of a polymer, which of the following reaction types would not be involved?
A)hydrolysis
B)condensation
C)amidation
D)esterification
A)hydrolysis
B)condensation
C)amidation
D)esterification
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25
Which of the following functional groups does not contain a carbonyl group?
A)ester
B)amide
C)ether
D)All contain a carbonyl group.
A)ester
B)amide
C)ether
D)All contain a carbonyl group.
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26
The following reaction would be coupled to anabolic reactions.
ATP
ADP + P
ATP

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27
Which of the following functional groups is not produced from a condensation reaction?
A)alcohol
B)amide
C)ester
D)ether
E)phosphoester
A)alcohol
B)amide
C)ester
D)ether
E)phosphoester
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28
Consider the polymer formed from equal numbers of the two amino acids glycine and alanine. Which of the following is not a property of this polymer?
A)copolymer
B)contains amide bonds
C)formed by an esterification reaction
D)might be part of a protein
A)copolymer
B)contains amide bonds
C)formed by an esterification reaction
D)might be part of a protein
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29
The name of the following compound is: 
A)butyl hexyl ether
B)decyl ether
C)cyclohexyl butyl ether
D)butyl cyclohexyl ether

A)butyl hexyl ether
B)decyl ether
C)cyclohexyl butyl ether
D)butyl cyclohexyl ether
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30
Consider the image shown below. The bond indicated by the arrow represents the bond that is broken when ADP forms . 

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31
In addition to water, what is(are) the product(s) of the following reaction? 
A)
B)
C)
D)
E)All of the above are possible products.

A)

B)

C)

D)

E)All of the above are possible products.
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32
What is the organic product of the reaction of 1-butanol with propanoic acid?
A)
B)
C)
D)
A)

B)

C)

D)

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33
When the following segment of a polymer formed, how many different amino acids were used? 
A)1
B)2
C)3
D)4
E)5

A)1
B)2
C)3
D)4
E)5
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34
When a molecule with the following structure reacts with itself to from polymer, the type of functional group formed is a(n): 
A)ether
B)ester
C)amide
D)phosphoester

A)ether
B)ester
C)amide
D)phosphoester
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35
When an alcohol undergoes a condensation reaction, which of the following class of compounds might form?
A)ether
B)ketone
C)aldehyde
D)alkene
A)ether
B)ketone
C)aldehyde
D)alkene
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36
Predict the products of the following reaction. Assume the pH is 7. 
A)
B)
C)
D)
E)Both a and d could form at pH 7.

A)

B)

C)

D)

E)Both a and d could form at pH 7.
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37
Lactic acid fermentation supplies less energy than glucose oxidation.
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38
Consider the following structure:
This compound could be formed by the reaction of:
A)2-propanol and cyclopentanol
B)1-propanol and cyclopentanol
C)2-propanol and cyclohexanol
D)1-propanol and cyclohexanol

A)2-propanol and cyclopentanol
B)1-propanol and cyclopentanol
C)2-propanol and cyclohexanol
D)1-propanol and cyclohexanol
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39
All of the bonds that hold the units together to form a polymer are:
A)covalent bonds.
B)ionic bonds.
C)hydrogen bonds.
D)nonpolar bonds.
A)covalent bonds.
B)ionic bonds.
C)hydrogen bonds.
D)nonpolar bonds.
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40
The following reaction could be used to form ATP form ADP. 

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41
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
___________________ has the potential to be administered as a hydrochloride salt.

aspirin
ibuprofen
naproxen
celebrex
___________________ has the potential to be administered as a hydrochloride salt.
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42
Consider the following compounds.
These compound may be involved in the following types of reaction.
amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structure D is the product of the reaction of two alcohols in a(n) _______________________ reaction.

amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structure D is the product of the reaction of two alcohols in a(n) _______________________ reaction.
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43
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
______________________ can function as a proton acceptor.

aspirin
ibuprofen
naproxen
celebrex
______________________ can function as a proton acceptor.
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44
The hydrolysis of the following compounds produce energy as given in the parenthesis. Which of these reactions can drive the formation of ATP?
A)glycerol-1-phosphate (2.2 kcal/mol)
B)fructose-6-phosphate (3.8 kcal/mol)
C)glucose-6-phosphate (3.3 kcal/mol)
D)None of the reactions evolves enough energy.
A)glycerol-1-phosphate (2.2 kcal/mol)
B)fructose-6-phosphate (3.8 kcal/mol)
C)glucose-6-phosphate (3.3 kcal/mol)
D)None of the reactions evolves enough energy.
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45
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
_____________________would not increase the H3O+ concentration in the stomach.

aspirin
ibuprofen
naproxen
celebrex
_____________________would not increase the H3O+ concentration in the stomach.
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46
What are the products formed when the following substance undergoes hydrolysis? 
A)
B)
C)
D)

A)

B)

C)

D)

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47
ATP plays a role in all of the following processes except which one?
A)phosphorylation reactions
B)exothermic reactions
C)membrane transport
D)muscle contraction
A)phosphorylation reactions
B)exothermic reactions
C)membrane transport
D)muscle contraction
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48
When ethyl propyl ether is hydrolyzed, which of the following products form?
A)propanol and ethanol
B)propanoic acid and ethanoic acid
C)propanol and ethanoic acid
D)ethanol and propanoic acid
A)propanol and ethanol
B)propanoic acid and ethanoic acid
C)propanol and ethanoic acid
D)ethanol and propanoic acid
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49
Malonic acid and ethylene glycol react.
What is the product of the reaction of two molecules of malonic acid and one molecule of ethylene glycol?
A)
B)
C)
D)

A)

B)

C)

D)

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50
Upon hydrolysis, a thioester will produce:
A)an alcohol and an acid
B)an amine and an acid
C)a thiol and an acid
D)two alcohols
E)a phosphate and an alcohol
A)an alcohol and an acid
B)an amine and an acid
C)a thiol and an acid
D)two alcohols
E)a phosphate and an alcohol
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51
Consider the following compounds.
These compound may be involved in the following types of reaction.
amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Molecules of structure E can react with KOH in a(n) ___________________ reaction.

amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Molecules of structure E can react with KOH in a(n) ___________________ reaction.
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52
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
If taken together, ibuprofen could under go an acid-base reaction with __________________.

aspirin
ibuprofen
naproxen
celebrex
If taken together, ibuprofen could under go an acid-base reaction with __________________.
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53
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
________________________could be classified as an ester.

aspirin
ibuprofen
naproxen
celebrex
________________________could be classified as an ester.
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54
What was the structure of the repeating unit in this polymer? 
A)
B)
C)
D)

A)

B)

C)

D)

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55
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
_________________contains an ether functional group.

aspirin
ibuprofen
naproxen
celebrex
_________________contains an ether functional group.
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56
Consider the following compounds.
These compound may be involved in the following types of reaction.
amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Molecules of structure A could react with other molecules of A in a(n) ________________reaction to produce a very large molecule.

amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Molecules of structure A could react with other molecules of A in a(n) ________________reaction to produce a very large molecule.
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57
The following reaction is driven by the breakdown of ATP, what is the single chemical equation that combines these two reactions?

A)
B)
C)
D)


A)

B)

C)

D)

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58
What are the products of the hydrolysis of the following compound when carried out at a physiological pH? 
A)
B)
C)
D)

A)

B)

C)

D)

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59
What are the products of the hydrolysis of the following compound at physiological pH? 
A)
B)
C)
D)

A)

B)

C)

D)

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60
The following represent several common nonsteriodal,anti-inflammatory drugs (NSAIDs)available over the counter.
Fill the blanks with the appropriate term from the list below.More than one answer may be correct.
aspirin
ibuprofen
naproxen
celebrex
At physiological pH, ___________________ would exist as a negative ion.

aspirin
ibuprofen
naproxen
celebrex
At physiological pH, ___________________ would exist as a negative ion.
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61
Draw structure of the "polymer" of the condensation reaction of four molecules of ethylene glycol (HO-CH2-CH2-OH).
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62
Consider the following compounds.
These compound may be involved in the following types of reaction.
amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structure B and structure C could combine in a(n) __________________ reaction.

amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structure B and structure C could combine in a(n) __________________ reaction.
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63
Draw the structure of the product of the condensation reaction of the ethanol with benzoic acid (shown below). 

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64
What mass in grams of ATP (C10H16N5O13P3) must be used to supply 4.26 kcal to the cells?
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65
At her aerobics class, Rachelle notices a dull pain in her lower leg. When the pain does not go away after a couple of days, Rachelle decides to have her doctor check her leg. The doctor orders an X-ray, but the X-ray image shows no evidence of injury to the bone. To help him diagnose the cause of Rachelle's pain, the doctor orders a blood test to determine Rachelle's level of alkaline phosphatase (ALP).
a.) Alkaline phosphatase is an enzyme commonly found in ________________.
b.) Why would Rachelle's alkaline phosphatase level be significantly higher than normal given her stress fracture?
a.) Alkaline phosphatase is an enzyme commonly found in ________________.
b.) Why would Rachelle's alkaline phosphatase level be significantly higher than normal given her stress fracture?
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66
Draw the structure of the product of the reaction of cyclohexanol and 2-pentanol.
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67
Draw the structure of the product of the condensation reaction of the following substances.
acetic acid and diethylamine
acetic acid and diethylamine
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68
Draw the structure of the product of the condensation reaction of the phosphate ion with cyclohexanol.
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69
Consider the following compounds.
These compound may be involved in the following types of reaction.
amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structures E and F are the products of a(n) ____________________ reaction.

amidation
esterification
saponification
condensation
hydrolysis
polymerization
Fill in the blanks with the appropriate term from the list.More than one term may be correct.
Structures E and F are the products of a(n) ____________________ reaction.
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70
How much energy in kilocalories is needed to convert 1.75 mol of ADP to ATP?
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