Deck 4: Molecular Compounds
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Deck 4: Molecular Compounds
1
Which of the following structures is likely to exist?
A)

B)

C)

D)

E)None of these may exist.
A)

B)

C)

D)

E)None of these may exist.

2
When two atoms share one or more pairs of electrons,a covalent bond is formed.
True
3
A chemical bond formed when two atoms share six electrons is a ________ bond;it is best described as ________.
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
triple;covalent
4
For the dot structure shown the most likely elements are X =________ and Y = ________. 
A)carbon;hydrogen
B)carbon;fluorine
C)carbon;oxygen
D)hydrogen;carbon
E)fluorine;carbon

A)carbon;hydrogen
B)carbon;fluorine
C)carbon;oxygen
D)hydrogen;carbon
E)fluorine;carbon
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5
For the structure shown,the most likely elements are X = ________ and Y = ________. 
A)carbon;oxygen
B)carbon;hydrogen
C)nitrogen;oxygen
D)oxygen;carbon
E)oxygen;hydrogen

A)carbon;oxygen
B)carbon;hydrogen
C)nitrogen;oxygen
D)oxygen;carbon
E)oxygen;hydrogen
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6
A chemical bond formed between two identical atoms is a(an)________ bond.
A)atomic
B)covalent
C)hydrogen
D)ionic
E)molecular
A)atomic
B)covalent
C)hydrogen
D)ionic
E)molecular
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7
Which element is most likely to form three covalent bonds?
A)C
B)Si
C)P
D)S
E)Se
A)C
B)Si
C)P
D)S
E)Se
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8
In a covalent compound,the bond length can be defined as the distance between
A)any two pairs of electrons.
B)the two largest atoms.
C)two nuclei when the repulsion is greatest.
D)two nuclei when the attraction is greatest.
E)two nuclei when repulsion and attraction are balanced.
A)any two pairs of electrons.
B)the two largest atoms.
C)two nuclei when the repulsion is greatest.
D)two nuclei when the attraction is greatest.
E)two nuclei when repulsion and attraction are balanced.
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9
Which element is most likely to make two covalent bonds in the formation of a molecular compound?
A)phosphorus
B)sulfur
C)bromine
D)nitrogen
A)phosphorus
B)sulfur
C)bromine
D)nitrogen
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10
A triple bond involves the sharing of ________ pairs of electrons between the atoms
A)1
B)2
C)3
D)4
E)5
A)1
B)2
C)3
D)4
E)5
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11
When a non-metal atom bonds with another non-metal atom,an ionic bond is formed.
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12
The smallest possible unit of a covalent compound is a(an)
A)atom.
B)cation.
C)formula unit.
D)molecule.
E)polyatomic ion.
A)atom.
B)cation.
C)formula unit.
D)molecule.
E)polyatomic ion.
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13
Which group contains only elements which normally exist as diatomic molecules?
A)nitrogen;sulfur,bromine
B)helium;neon,argon
C)nitrogen;oxygen,fluorine
D)hydrogen;lithium,sodium
E)oxygen;phosphorus,germanium
A)nitrogen;sulfur,bromine
B)helium;neon,argon
C)nitrogen;oxygen,fluorine
D)hydrogen;lithium,sodium
E)oxygen;phosphorus,germanium
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14
A chemical bond formed when two atoms share three pairs of electrons is a ________ bond;it is best described as ________.
A)double;covalent
B)single;covalent
C)triple;covalent
D)double;ionic
E)triple;ionic
A)double;covalent
B)single;covalent
C)triple;covalent
D)double;ionic
E)triple;ionic
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15
A chemical bond formed when two atoms share one pair of electrons is a ________ bond;it is best described as ________.
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
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16
Which representation of a hydrogen molecule is not correct?
A)H=H
B)H2
C)H:H
D)H-H
E)none of the above
A)H=H
B)H2
C)H:H
D)H-H
E)none of the above
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17
A chemical bond formed when two atoms share two pairs of electrons is a ________ bond;it is best described as ________.
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
A)double;covalent
B)double;ionic
C)single;covalent
D)single;ionic
E)triple;covalent
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18
The covalent bonding model is most useful in describing which of the following compounds?
A)CoCl2
B)MgCl2
C)NiCl2
D)SCl2
E)none of the above
A)CoCl2
B)MgCl2
C)NiCl2
D)SCl2
E)none of the above
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19
Which group in the Periodic Table is most likely to contain the element X in the molecule whose dot structure is shown? 
A)2A
B)3A
C)4A
D)5A
E)6A

A)2A
B)3A
C)4A
D)5A
E)6A
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20
Which element is most likely to be "X" in the diatomic molecule shown? 
A)nitrogen
B)oxygen
C)fluorine
D)hydrogen
E)helium

A)nitrogen
B)oxygen
C)fluorine
D)hydrogen
E)helium
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21
Which representation of a methane molecule is not correct? (A methane molecule is composed of one carbon atom and four hydrogen atoms. )
A)C
B)

C)

D)

E)none of the above
A)C

B)

C)

D)

E)none of the above
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22
What is the molecular geometry of PH3?
A)linear
B)trigonal planar
C)tetrahedral
D)bent
E)trigonal pyramidal
A)linear
B)trigonal planar
C)tetrahedral
D)bent
E)trigonal pyramidal
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23
The total number of valence electrons in a molecule of SOF2 is
A)26.
B)24.
C)18.
D)20.
E)22.
A)26.
B)24.
C)18.
D)20.
E)22.
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24
Draw the Lewis structure for the a molecule of ethylamine,CH3CH2NH2.
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25
Which of the following structures is the correct structure for SOCl2?
A)

B)

C)

D)

E)

A)

B)

C)

D)

E)

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26
In a Lewis dot structure the electrons which complete an octet but are not located between two atoms are referred to as
A)bonding pairs.
B)delta minus electrons.
C)excess electrons.
D)filled shells.
E)lone pairs.
A)bonding pairs.
B)delta minus electrons.
C)excess electrons.
D)filled shells.
E)lone pairs.
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27
The molecule SiCl4 has a ________ shape.
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
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28
The VSEPR model of molecular structure requires a knowledge of ________ to predict the geometry of an atom in a molecule.
A)the number of atoms bonded to the atom of interest
B)the total number of atoms in the molecule
C)the number of electron pairs on the atom of interest
D)both A and C
E)none of the above
A)the number of atoms bonded to the atom of interest
B)the total number of atoms in the molecule
C)the number of electron pairs on the atom of interest
D)both A and C
E)none of the above
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29
Explain why it is unlikely that an organic molecule would have an odd number of valence electrons.
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30
A molecule in which the central atom forms one double bond and two single bonds is said to have a ________ shape.
A)bent
B)linear
C)trigonal planar
D)pyramidal
E)tetrahedral
A)bent
B)linear
C)trigonal planar
D)pyramidal
E)tetrahedral
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31
In forming covalent bonds where the octet rule is obeyed,sulfur usually forms ________ bonds and chlorine usually forms ________ bonds.
A)one;one
B)two;two
C)one;two
D)two;one
E)six;seven
A)one;one
B)two;two
C)one;two
D)two;one
E)six;seven
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32
Which property is most closely associated with covalent molecules?
A)It is a gas at room temperature.
B)It conducts electricity when dissolved in water.
C)It has a very high melting point.
D)It is composed of a metal and a nonmetal.
E)none of these.
A)It is a gas at room temperature.
B)It conducts electricity when dissolved in water.
C)It has a very high melting point.
D)It is composed of a metal and a nonmetal.
E)none of these.
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33
Which property could describe a covalent compound?
A)It conducts electricity when melted.
B)It is a gas at room temperature.
C)It is composed of a non-metal and a metal.
D)It conducts electricity when dissolved in water.
E)none of the above
A)It conducts electricity when melted.
B)It is a gas at room temperature.
C)It is composed of a non-metal and a metal.
D)It conducts electricity when dissolved in water.
E)none of the above
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34
The number of valence electrons in the acetic acid molecule (CH3CO2H)is
A)0.
B)8.
C)16.
D)24.
E)32.
A)0.
B)8.
C)16.
D)24.
E)32.
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35
How many double bonds are there in a molecule of SF2?
A)0
B)1
C)2
D)3
E)4
A)0
B)1
C)2
D)3
E)4
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36
A molecule in which the central atom forms three single bonds and has one lone pair is said to have a ________ shape.
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
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37
A molecule in which the central atom has no lone pairs and forms four single bonds is said to have a ________ shape.
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
A)bent
B)linear
C)planar
D)pyramidal
E)tetrahedral
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38
Which set of properties would identify an unknown white solid as a molecular compound?
I.Contains a metal.
II.Has a definite crystal structure.
III.Dissolves in water,but not in organic liquids.
IV.Melts at 80 degrees Celsius.
V.Does not conduct electricity when melted.
A)I,II,III
B)I,III,V
C)II,III,IV
D)II,IV,V
E)I,IV,V
I.Contains a metal.
II.Has a definite crystal structure.
III.Dissolves in water,but not in organic liquids.
IV.Melts at 80 degrees Celsius.
V.Does not conduct electricity when melted.
A)I,II,III
B)I,III,V
C)II,III,IV
D)II,IV,V
E)I,IV,V
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39
Covalent compounds form distinct molecules,and therefore may exist as gases,liquids,or solids at room temperature,depending on the characteristics of the compound.
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40
The element least likely to obey the octet rule in forming chemical bonds is
A)boron.
B)carbon.
C)nitrogen.
D)oxygen.
E)fluorine.
A)boron.
B)carbon.
C)nitrogen.
D)oxygen.
E)fluorine.
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41
The bond angle in the molecule H2S is ________ because the ________.
A)exactly 109.5°;S atom has four charge clouds
B)greater than 109.5°;lone pairs allow the bond angle to expand
C)less than 109.5°;lone pairs force the hydrogen atoms closer together
D)exactly 120°;lone pairs are counted as one charge cloud
E)exactly 180°;the S atom has two bonds
A)exactly 109.5°;S atom has four charge clouds
B)greater than 109.5°;lone pairs allow the bond angle to expand
C)less than 109.5°;lone pairs force the hydrogen atoms closer together
D)exactly 120°;lone pairs are counted as one charge cloud
E)exactly 180°;the S atom has two bonds
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42
Which of the following molecules has a CCH bond angle of 180°?
A)HCCH
B)H2CCH2
C)H3CCH3
D)H3CCHO
E)none of them
A)HCCH
B)H2CCH2
C)H3CCH3
D)H3CCHO
E)none of them
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43
According to VSEPR theory,a molecule with three charge clouds including one lone pair would have a ________ shape.
A)bent
B)linear
C)tetrahedral
D)trigonal planar t
E)pyramidal
A)bent
B)linear
C)tetrahedral
D)trigonal planar t
E)pyramidal
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44
A section of the Periodic Table containing main group elements is shown.If the elements W,X,Y,and Z have electronegativity values of 1.0,2.0,2.5,and 3.5,respectively,which bond is ionic? 
A)WY
B)WZ
C)XY
D)XZ
E)YZ

A)WY
B)WZ
C)XY
D)XZ
E)YZ
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45
Explain how it is possible for CCl4 to have polar bonds but be a non-polar molecule.A diagram may be helpful in your answer,but it must be explained.
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46
A bond where the electrons are shared equally is called a(an)________ bond.
A)polar covalent
B)coordinate covalent
C)nonpolar covalent
D)ionic
E)none of the above
A)polar covalent
B)coordinate covalent
C)nonpolar covalent
D)ionic
E)none of the above
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47
Consider a bent molecule,such as H2Se,in which the central atom has two lone pairs of electrons.The electronegativities of H and Se are 2.1 and 2.4,respectively.Based on these values and on consideration of molecular geometry,the H-Se bond can be considered almost ________ and the molecule is ________.
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
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48
What is the systematic name of ICl3?
A)iodine chloride
B)iodine(III)chloride
C)triiodine chloride
D)iodine trichloride
E)tri(iodine chloride)
A)iodine chloride
B)iodine(III)chloride
C)triiodine chloride
D)iodine trichloride
E)tri(iodine chloride)
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49
The carbon dioxide molecule is linear.The electronegativities of C and O are 2.5 and 3.5,respectively.Based on these values and on consideration of molecular geometry,the C-O bond is ________ and the molecule is ________.
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
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50
Consider the molecule SiCl4.The electronegativity values for Si and Cl are 1.8 and 3.0,respectively.Based on these values and on consideration of molecular geometry,the Si-Cl bond is ________ and the molecule is ________.
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
A)polar;polar
B)nonpolar;nonpolar
C)polar;nonpolar
D)nonpolar;polar
E)none of the above
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51
The water molecule has a ________ geometry because its central atom has ________ bonds and ________ lone pairs of electrons.
A)bent;two;two
B)linear;two;two
C)pyramidal;three;one
D)tetrahedral;four;zero
E)planar triangular;three;one
A)bent;two;two
B)linear;two;two
C)pyramidal;three;one
D)tetrahedral;four;zero
E)planar triangular;three;one
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52
A section of the Periodic Table containing main group elements is shown.Which bond would be least polar? 
A)WX
B)YZ
C)WZ
D)WY
E)cannot be determined without more specific information

A)WX
B)YZ
C)WZ
D)WY
E)cannot be determined without more specific information
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53
Which element listed is the least electronegative?
A)nitrogen
B)hydrogen
C)oxygen
D)fluorine
E)chlorine
A)nitrogen
B)hydrogen
C)oxygen
D)fluorine
E)chlorine
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54
Based on your knowledge of electronegativities determine whether the bonds between the following pairs of atoms are ionic,polar covalent or nonpolar covalent:
A) F-F
B) Cs-Br
C) N-S
A) F-F
B) Cs-Br
C) N-S
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55
Which element listed is the most electronegative?
A)aluminum
B)bromine
C)chlorine
D)iodine
E)sodium
A)aluminum
B)bromine
C)chlorine
D)iodine
E)sodium
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56
Draw the Lewis structure for CCl4.What is the molecular geometry of this compound? Is the molecule polar or nonpolar?
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57
A molecule that contains three identical polar bonds to the central atom will be
A)nonpolar if the geometry is planar triangular.
B)polar in all cases.
C)nonpolar in all cases.
D)impossible to tell the polarity.
E)either polar or nonpolar depending on the identity of the atoms bonded to the central atom.
A)nonpolar if the geometry is planar triangular.
B)polar in all cases.
C)nonpolar in all cases.
D)impossible to tell the polarity.
E)either polar or nonpolar depending on the identity of the atoms bonded to the central atom.
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58
A bond where the electrons are shared unequally is called a(an)________ bond.
A)polar covalent
B)coordinate covalent
C)nonpolar covalent
D)ionic
E)none of the above
A)polar covalent
B)coordinate covalent
C)nonpolar covalent
D)ionic
E)none of the above
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59
Which of the following compounds is likely to have ionic bonds between the atoms?
A)CH4
B)CaCl2
C)NBr3
D)SO2
E)All of these have covalent bonds.
A)CH4
B)CaCl2
C)NBr3
D)SO2
E)All of these have covalent bonds.
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60
A section of the Periodic Table containing main group elements is shown.If the elements W,X,Y,and Z have electronegativity values of 1.0,2.0,2.5,and 3.5,respectively,which bond is the least polar? 
A)WX
B)WZ
C)XY
D)XZ
E)YZ

A)WX
B)WZ
C)XY
D)XZ
E)YZ
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61
Match the following.
bromine pentafluoride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
bromine pentafluoride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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62
Match the following.
dinitrogen tetroxide
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
dinitrogen tetroxide
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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63
Match the following.
methane
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
methane
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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64
Match the following.
sulfur dioxide
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
sulfur dioxide
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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65
The formula for sulfur hexabromide is
A)SF6.
B)SBr6.
C)SBr4.
D)SiBr6.
E)SiB6.
A)SF6.
B)SBr6.
C)SBr4.
D)SiBr6.
E)SiB6.
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66
Match the following.
carbon tetrachloride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
carbon tetrachloride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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67
The formula for carbon disulfide is
A)CS2.
B)C2S.
C)CSi2.
D)CaS2.
E)(CS)2.
A)CS2.
B)C2S.
C)CSi2.
D)CaS2.
E)(CS)2.
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68
Match the following.
carbon monoxide
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
carbon monoxide
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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69
Although noble gases do not normally form covalent compounds,XeO3 has been prepared.The systematic name of this compound is
A)trioxy xenon.
B)trixenon trioxide.
C)xenon trioxide.
D)xenon(III)oxide.
E)none of the above
A)trioxy xenon.
B)trixenon trioxide.
C)xenon trioxide.
D)xenon(III)oxide.
E)none of the above
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70
If SiCl4 is named as a covalent compound,what would it be called?
A)silicon chloride
B)chlorosilicate
C)silicon tetrachloride
D)sulfur chloride
E)sulfur tetrachloride
A)silicon chloride
B)chlorosilicate
C)silicon tetrachloride
D)sulfur chloride
E)sulfur tetrachloride
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71
Match the following.
iodine monochloride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
iodine monochloride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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72
The formula for phosphorus pentafluoride is
A)PhF5.
B)PF5.
C)P5F.
D)(PF)5.
E)P5F5.
A)PhF5.
B)PF5.
C)P5F.
D)(PF)5.
E)P5F5.
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73
Match the following.
ammonia
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
ammonia
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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74
The compound BrF3 would be called
A)boron trifluoride.
B)triboron fluoride.
C)tri (bromine fluoride).
D)tribromine fluoride.
E)bromine trifluoride.
A)boron trifluoride.
B)triboron fluoride.
C)tri (bromine fluoride).
D)tribromine fluoride.
E)bromine trifluoride.
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75
Match the following.
iodine heptafluoride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
iodine heptafluoride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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76
Match the following.
phosphorus trichloride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
phosphorus trichloride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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77
Match the following.
oxygen difluoride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
oxygen difluoride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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78
Match the following.
sulfur hexafluoride
A)ICl
B)C
C)N
D)PC
E)

F)CO
G)S
H)S
I)O
J)Br
K)CC
L)I
sulfur hexafluoride
A)ICl
B)C

C)N

D)PC

E)


F)CO
G)S

H)S

I)O

J)Br

K)CC

L)I

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