Deck 12: Solutions
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Deck 12: Solutions
1
In a solution made by dissolving 50 grams of calcium chloride (CaCl2)in 1000 grams of water, which component is considered to be the solute?
A)Water is the solute.
B)Both water and calcium chloride are solutes in this example.
C)Calcium chloride is the solute.
D)The solute cannot be determined from the information given.
A)Water is the solute.
B)Both water and calcium chloride are solutes in this example.
C)Calcium chloride is the solute.
D)The solute cannot be determined from the information given.
Calcium chloride is the solute.
2
Which of the following is not a solution?
A)ice in water
B)vinegar in water
C)sugar in water
D)metal alloys
A)ice in water
B)vinegar in water
C)sugar in water
D)metal alloys
ice in water
3
Which of the following solutions are possible?
A)Both the solvent and solute are liquids.
B)Both the solvent and solute are solids.
C)The solvent is a liquid and the solute is a gas.
D)All of them are possible.
A)Both the solvent and solute are liquids.
B)Both the solvent and solute are solids.
C)The solvent is a liquid and the solute is a gas.
D)All of them are possible.
All of them are possible.
4
Which of the following has the lowest hydration energy?
A)sodium chloride
B)magnesium chloride
C)aluminum chloride
D)silicon tetrachloride
A)sodium chloride
B)magnesium chloride
C)aluminum chloride
D)silicon tetrachloride
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5
Henry's law gives the relationship between ________.
A)colligative properties and the freezing point
B)solubility of a gas and concentration
C)solubility of a gas and pressure
D)hydrophobic and hydrophilic solutions
A)colligative properties and the freezing point
B)solubility of a gas and concentration
C)solubility of a gas and pressure
D)hydrophobic and hydrophilic solutions
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6
In a solution made by dissolving 200 grams of sugar in 1000 grams of water, which component is considered to be the solvent?
A)Water is the solvent.
B)Both water and sugar are solvents in this example.
C)Sugar is the solvent.
D)The solvent cannot be determined from the information given.
A)Water is the solvent.
B)Both water and sugar are solvents in this example.
C)Sugar is the solvent.
D)The solvent cannot be determined from the information given.
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7
What is the molarity of 3.68 mL of a solution containing 0.0025 moles of calcium chloride?
A)6.8 × 10-4 M
B)0.68 M
C)1.5 M
D)6.8 × 10-3 M
A)6.8 × 10-4 M
B)0.68 M
C)1.5 M
D)6.8 × 10-3 M
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8
Under what conditions would a gas be most soluble in a liquid?
A)high temperature and high pressure
B)high temperature and low pressure
C)low temperature and high pressure
D)low temperature and low pressure
A)high temperature and high pressure
B)high temperature and low pressure
C)low temperature and high pressure
D)low temperature and low pressure
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9
Sterling silver is a solution (ALLOY)of ________.
A)silver and zinc
B)silver and gold
C)silver and copper
D)silver and iron
A)silver and zinc
B)silver and gold
C)silver and copper
D)silver and iron
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10
The spherical structure of a soap molecule that is formed when in contact with water is called ________.
A)detergent
B)hydrophobic end
C)hydrophilic end
D)micelle
A)detergent
B)hydrophobic end
C)hydrophilic end
D)micelle
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11
Which end, the polar end or the nonpolar end, of a detergent molecule is attracted to water?
A)the polar end
B)both the polar and the nonpolar end
C)neither the polar nor the nonpolar end
D)the nonpolar end
A)the polar end
B)both the polar and the nonpolar end
C)neither the polar nor the nonpolar end
D)the nonpolar end
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12
In a dilute saline solution the solute is in the form of ________.
A)Na+ and Cl-
B)NaCl (s)
C)NaCl (ℓ)
D)both A and B
A)Na+ and Cl-
B)NaCl (s)
C)NaCl (ℓ)
D)both A and B
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13
Which of the following statements is correct?
A)Temperature usually increases the solubility of a solid in water.
B)Pressure usually increases the solubility of a gas in water.
C)Solubility involves the statement "like dissolves like".
D)All of the above statements are correct.
A)Temperature usually increases the solubility of a solid in water.
B)Pressure usually increases the solubility of a gas in water.
C)Solubility involves the statement "like dissolves like".
D)All of the above statements are correct.
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14
The statement "like dissolves like" justifies why ________.
A)water will dissolve ethyl alcohol
B)octane will dissolve methane
C)water will not dissolve fats
D)All of the above statements are correct.
A)water will dissolve ethyl alcohol
B)octane will dissolve methane
C)water will not dissolve fats
D)All of the above statements are correct.
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15
Which end, the polar end or the nonpolar end, of a detergent molecule is attracted to dirt particles?
A)the polar end
B)both the polar and the nonpolar end
C)neither the polar nor the nonpolar end
D)the nonpolar end
A)the polar end
B)both the polar and the nonpolar end
C)neither the polar nor the nonpolar end
D)the nonpolar end
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16
How are solubility and temperature generally related in a system consisting of a solid solute and a liquid solvent?
A)Solubility generally increases with increasing temperature.
B)Solubility generally increases with decreasing temperature.
C)Changing the temperature has no effect on solubility.
D)Solubility generally decreases with increasing temperature.
A)Solubility generally increases with increasing temperature.
B)Solubility generally increases with decreasing temperature.
C)Changing the temperature has no effect on solubility.
D)Solubility generally decreases with increasing temperature.
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17
If a solute is to be soluble in a given solvent, which step in the solution-making process must have a negative value for its energy?
A)the physical separation of solvent particles
B)the physical separation of solute particles
C)the formation of solvent/solute interactions
D)All three of the preceding steps must be negative for a solute to be soluble.
A)the physical separation of solvent particles
B)the physical separation of solute particles
C)the formation of solvent/solute interactions
D)All three of the preceding steps must be negative for a solute to be soluble.
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18
Which of the following statements is correct?
A)Difference in energy attributed to solvent separation consumes energy.
B)Difference in energy attributed to solute separation consumes energy.
C)Solvation releases energy.
D)All the above statements are correct.
A)Difference in energy attributed to solvent separation consumes energy.
B)Difference in energy attributed to solute separation consumes energy.
C)Solvation releases energy.
D)All the above statements are correct.
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19
Which of the following has the highest hydration energy?
A)sodium chloride
B)magnesium chloride
C)aluminum chloride
D)silicon tetrachloride
A)sodium chloride
B)magnesium chloride
C)aluminum chloride
D)silicon tetrachloride
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20
How are the solubilities of gases (solutes)in liquids (solvents)affected by changing pressure?
A)Gases are more soluble in liquids when pressure is decreased.
B)Pressure has no effect on how soluble a gas is in a liquid.
C)Gases are less soluble in liquids when pressure is increased.
D)Gases are more soluble when the pressure is increased.
A)Gases are more soluble in liquids when pressure is decreased.
B)Pressure has no effect on how soluble a gas is in a liquid.
C)Gases are less soluble in liquids when pressure is increased.
D)Gases are more soluble when the pressure is increased.
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21
Which of the following is not a colligative property?
A)molarity
B)freezing point depression
C)vapor pressure lowering
D)boiling point elevation
A)molarity
B)freezing point depression
C)vapor pressure lowering
D)boiling point elevation
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22
An impurity ________ the boiling point of a compound.
A)decreases
B)increases
C)has no effect on
D)One cannot say unless the physical properties of the compound are known.
A)decreases
B)increases
C)has no effect on
D)One cannot say unless the physical properties of the compound are known.
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23
500 mL 0.4 M aluminum nitrate solution contains ________ moles of aluminum ions and ________ moles of nitrate ions.
A)0.6; 0.2
B)0.2; 0.4
C)0.2; 0.6
D)0.2; 0.2
A)0.6; 0.2
B)0.2; 0.4
C)0.2; 0.6
D)0.2; 0.2
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24
Which of the following is water insoluble?
A)octane, C8H18
B)ethanol, C2H5OH
C)sodium sulfate, Na2SO4
D)acetic acid, the active ingredient in vinegar, CH3COOH
A)octane, C8H18
B)ethanol, C2H5OH
C)sodium sulfate, Na2SO4
D)acetic acid, the active ingredient in vinegar, CH3COOH
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25
25 mL 0.1 M NaCl contains ________ g NaCl.
A)0.0025
B)0.15
C)2.5
D)0.25
A)0.0025
B)0.15
C)2.5
D)0.25
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26
What is the freezing point of a sugar solution prepared by dissolving 375.00 g of sucrose (342.3 g/mol)in 1500.0 g of water (Kf of water = 1.86 °C)?
A)1.36 °C
B)-1.36 °C
C)-1.86 °C
D)-0.465 °C
A)1.36 °C
B)-1.36 °C
C)-1.86 °C
D)-0.465 °C
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27
500 mL 0.4 M potassium dichromate contains ________ moles of potassium ions and ________ moles of dichromate ions.
A)0.4; 0.2
B)0.2; 0.4
C)0.4; 0.6
D)0.2; 0.2
A)0.4; 0.2
B)0.2; 0.4
C)0.4; 0.6
D)0.2; 0.2
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28
The molarity of a solution that contains 5.85 g NaCl in 2.0 L solution is ________.
A)2.93 M
B)0.05 M
C)5.0 M
D)0.29 M
A)2.93 M
B)0.05 M
C)5.0 M
D)0.29 M
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29
How many grams of water are in 100 g of a 30 mass % sugar solution?
A)30
B)60
C)70
D)100
A)30
B)60
C)70
D)100
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30
Phenolphthalein turns ________ when the solution is basic.
A)clear
B)blue
C)pink
D)orange
A)clear
B)blue
C)pink
D)orange
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31
To prepare 100 mL 0.4 M HCl from a stock solution of 2 M HCl one needs to ________.
A)dilute 20 mL 2 M HCl with 100 mL HCl
B)dilute 20 mL 2 M HCl with enough water to make a total volume of 100 mL solution
C)use 500 mL 2 M HCl and boil it down to a final volume of 100 mL solution
D)dilute 80 mL 2 M HCl to a total volume of 100 mL solution
A)dilute 20 mL 2 M HCl with 100 mL HCl
B)dilute 20 mL 2 M HCl with enough water to make a total volume of 100 mL solution
C)use 500 mL 2 M HCl and boil it down to a final volume of 100 mL solution
D)dilute 80 mL 2 M HCl to a total volume of 100 mL solution
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32
A 0.2119 g sample of an acid, HA, was neutralized by 34.7 mL 0.0500 M NaOH solution. The molecular mass of the acid is ________.
A)61
B)92
C)122
D)244
A)61
B)92
C)122
D)244
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33
An impurity ________ the melting point of a compound.
A)decreases
B)increases
C)has no effect on
D)One cannot say unless the physical properties of the compound are known.
A)decreases
B)increases
C)has no effect on
D)One cannot say unless the physical properties of the compound are known.
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34
200. mL 0.100 M NaCl contains ________ g NaCl.
A)1.17
B)11.7
C)117
D)5.85
A)1.17
B)11.7
C)117
D)5.85
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35
Which of the following is water soluble?
A)CCl4
B)C2H5OH
C)C8H18
D)CH3CH2OCH2CH3
A)CCl4
B)C2H5OH
C)C8H18
D)CH3CH2OCH2CH3
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36
How many grams of NaCl are in 200 g of a 10 mass % salt solution?
A)10
B)20
C)40
D)80
A)10
B)20
C)40
D)80
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37
4.173 g of an organic compound (non-electrolyte)lowered the freezing point of 100.0 g nitrobenzene by 2.6 °C. If the Kf of nitrobenzene is 8.1 °C, the molecular mass of the non-electrolyte is ________.
A)260
B)195
C)65
D)130
A)260
B)195
C)65
D)130
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38
A 2.154 g sample of an unknown non-electrolyte is dissolved in 50 g of water (Kf of water = 1.86 °C). If the solution freezes at -1.23 °C, the molecular mass of the non-electrolyte is ________.
A)33
B)65
C)130
D)260
A)33
B)65
C)130
D)260
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39
500 mL 0.4 M calcium nitrite contains ________ moles of calcium ions and ________ moles of nitrite ions.
A)0.4; 0.2
B)0.2; 0.4
C)0.4; 0.6
D)0.2; 0.2
A)0.4; 0.2
B)0.2; 0.4
C)0.4; 0.6
D)0.2; 0.2
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40
7.5 g calcium carbonate in a 150 mL aqueous solution will provide a ________ M solution.
A)0.10
B)0.50
C)1.0
D)2.0
A)0.10
B)0.50
C)1.0
D)2.0
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41
The solute in a sugar solution is water.
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42
C8H18 will dissolve in CCl4.
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43
Amalgams are solid solutions.
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44
Air is a gas solution where oxygen is the solvent.
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45
Dry cleaning uses perchloroethane to remove grease and oil from clothes.
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46
NH3 will dissolve in BF3.
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47
Nonpolar solutes will usually dissolve in polar solvents.
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48
Polar solutes will usually dissolve in polar solvents.
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49
A mixture is not necessarily a solution.
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50
Ca2+ is expected to have a greater energy of hydration than K+.
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51
10.0 mL 0.5 M sulfuric acid neutralizes ________ mL 0.5 M ammonium hydroxide.
A)5.0
B)10.
C)20.
D)40.
A)5.0
B)10.
C)20.
D)40.
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52
A 2.00 g sample of a non-electrolyte (molar mass = 118)is dissolved in 55.0 g benzene (Kf of benzene is
What is the freezing point depression of the solution?
A)1.58 °C
B)3.16 °C
C)0.79 °C
D)2.33 °C

A)1.58 °C
B)3.16 °C
C)0.79 °C
D)2.33 °C
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53
There is no difference between the "molarity" and the "percent composition" of a given solution.
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54
Transparent solutions are examples of homogeneous matter.
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55
10.0 mL 0.5 M HCl neutralizes ________ mL 0.5 M NaOH.
A)5.0
B)10.
C)20.
D)40.
A)5.0
B)10.
C)20.
D)40.
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56
10.0 mL 0.5 M sulfuric acid neutralizes ________ mL 0.5 M magnesium hydroxide.
A)5.0
B)10.
C)20.
D)40.
A)5.0
B)10.
C)20.
D)40.
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57
Vinegar is a liquid solution where acetic acid serves as the solvent.
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58
It is not possible to make a solution in which both the solute and the solvent are gases.
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59
Situations of great disorder are said to have "high entropies."
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60
The solvent in a saline solution is water.
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61
100 mL of 1.0 M KOH will neutralize 100 mL of 1.0 M H2SO4 solution.
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62
The process of surrounding solute ions with solvent molecules is called solvation.
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63
What are two physical properties of water that make it an especially useful and common solvent?
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64
The bends, a condition encountered by divers, is attributed to the rapid depressurized escape of nitrogen from blood.
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65
A 20 mass % NaOH solution is made by dissolving 5 g NaOH in 25 g water.
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66
A 1 mass % saline solution contains 1 g of NaCl plus 99 g of water.
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67
If a liquid is volatile it evaporates readily.
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68
Alloys are solid solutions.
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69
How does the phrase "like dissolves like" help to explain why a solute like sodium chloride (NaCl)and a solvent like water should form a solution?
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70
A hydrophobic group will be attracted to water.
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71
Starting with 100 mL of water, if you then add 30 grams of sodium chloride (NaCl)to the water, will the volume of the solution you make be less than/exactly/greater than 100 mL?
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72
Once the temperature of 100.°C is reached, liquid water spontaneously becomes
a gas.
a gas.
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73
Use the general rule "like dissolves like" to briefly explain why vegetable oil (nonpolar)will not dissolve in water (polar).
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74
For most molecular solids an increase in temperature generally causes an increase in solubility.
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75
A saline solution will boil at 100 °C.
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76
The addition of NaCl to water will decrease the freezing point.
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77
Molarity is defined as moles of solute per liter of solvent.
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78
25 mL of 0.2 M NaOH will neutralize 10 mL 0.5 M HCl solution.
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79
What are the three ways a given solution's "percent composition" can be described?
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80
Hydrocarbons, such as pentane C5H12, are water soluble.
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