Deck 13: Carbohydrates
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Deck 13: Carbohydrates
1
The breakdown of glucose to chemical energy for the cells to do work is an example of ________.
A)oxidation
B)respiration
C)reduction
D)anabolism
E)mutarotation
A)oxidation
B)respiration
C)reduction
D)anabolism
E)mutarotation
oxidation
2
Which of the following compounds is chiral?
A)H ∣
H - C - H
∣
H
B)H ∣
HO - C - OH
∣
H
C)
∣
HO - C - H
∣
Cl
D)Br ∣
H - C - OH
∣
H
E)Cl ∣
Br - C - Cl
∣
Br
A)H ∣
H - C - H
∣
H
B)H ∣
HO - C - OH
∣
H
C)

HO - C - H
∣
Cl
D)Br ∣
H - C - OH
∣
H
E)Cl ∣
Br - C - Cl
∣
Br

HO - C - H
∣
Cl
3
A monosaccharide that consists of 5 carbon atoms,one of which is in a ketone group,is classified as a(n)________.
A)aldotetrose
B)aldopentose
C)aldohexose
D)ketotetrose
E)ketopentose
A)aldotetrose
B)aldopentose
C)aldohexose
D)ketotetrose
E)ketopentose
ketopentose
4
Stereoisomers that are nonsuperimposable mirror images of each other are known as ________.
A)enantiomers
B)achiral isomers
C)superimposable isomers
D)anomers
E)Fischer projections
A)enantiomers
B)achiral isomers
C)superimposable isomers
D)anomers
E)Fischer projections
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5
Which group of carbohydrates cannot be hydrolyzed to give simpler carbohydrates?
A)monosaccharides
B)disaccharides
C)trisaccharides
D)tetrasaccharides
E)polysaccharides
A)monosaccharides
B)disaccharides
C)trisaccharides
D)tetrasaccharides
E)polysaccharides
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6
In the carbon cycle,carbon dioxide and water are converted to glucose and oxygen by ________.
A)large animals
B)insects
C)mushrooms
D)green plants
E)earthworms
A)large animals
B)insects
C)mushrooms
D)green plants
E)earthworms
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7
One difference between D-glucose and L-glucose is ________.
A)the open-chain form of L-glucose does not exist
B)it is not possible to make L-glucose
C)L-glucose has a 5-membered ring,and D-glucose has a 6-membered ring
D)only D-glucose can act as a substrate in metabolic reactions
E)L-glucose cannot form a closed structure
A)the open-chain form of L-glucose does not exist
B)it is not possible to make L-glucose
C)L-glucose has a 5-membered ring,and D-glucose has a 6-membered ring
D)only D-glucose can act as a substrate in metabolic reactions
E)L-glucose cannot form a closed structure
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8
How many different substituents are required on a carbon atom for it to be chiral?
A)one
B)two
C)three
D)four
E)Any number from 1 to 4; chiralty does not depend on substitution.
A)one
B)two
C)three
D)four
E)Any number from 1 to 4; chiralty does not depend on substitution.
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9
A carbohydrate that gives two molecules when it is completely hydrolyzed is known as a ________.
A)monosaccharide
B)disaccharide
C)polysaccharide
D)starch
E)trisaccharide
A)monosaccharide
B)disaccharide
C)polysaccharide
D)starch
E)trisaccharide
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10
In the L- isomer of a Fischer projection of a monosaccharide,the -OH group furthest from the carbonyl is written ________.
A)on the left of the top chiral carbon
B)on the right of the top chiral carbon
C)on the left of the middle chiral carbon
D)on the left of the bottom chiral carbon
E)on the right of the bottom chiral carbon
A)on the left of the top chiral carbon
B)on the right of the top chiral carbon
C)on the left of the middle chiral carbon
D)on the left of the bottom chiral carbon
E)on the right of the bottom chiral carbon
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11
Chiral drugs consist of only one enantiomer.The benefits of using a pure enantiomer,rather than a mixture,include ________.
A)higher potency (lower total dose of drug)
B)elimination of side effects
C)reduced chances of drug interactions
D)all of the above
E)none of the above
A)higher potency (lower total dose of drug)
B)elimination of side effects
C)reduced chances of drug interactions
D)all of the above
E)none of the above
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12
Achiral compounds are those which ________.
A)have no "handedness"
B)have different mirror images
C)are nonsuperimposable
D)have the same formula but different structures
E)have a carbon attached to four different atoms
A)have no "handedness"
B)have different mirror images
C)are nonsuperimposable
D)have the same formula but different structures
E)have a carbon attached to four different atoms
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13
Fructose does not undergo hydrolysis because it is a ________.
A)aldose
B)hexose
C)reducing sugar
D)monosaccharide
E)disaccharide
A)aldose
B)hexose
C)reducing sugar
D)monosaccharide
E)disaccharide
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14
An enantiomer is ________.
A)a stereoisomer that is not a mirror image of another molecule
B)a stereoisomer whose mirror image cannot be superimposed
C)a diastereoisomer
D)a constitutional isomer
E)a geometric isomer
A)a stereoisomer that is not a mirror image of another molecule
B)a stereoisomer whose mirror image cannot be superimposed
C)a diastereoisomer
D)a constitutional isomer
E)a geometric isomer
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15
A monosaccharide that contains 4 carbon atoms,one of which is in an aldehyde group,is classified as a(n)________.
A)aldopentose
B)aldohexose
C)ketopentose
D)aldotetrose
E)ketotetrose
A)aldopentose
B)aldohexose
C)ketopentose
D)aldotetrose
E)ketotetrose
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16
A monosaccharide that contains 6 carbon atoms,one of which is in an aldehyde group,is classified as a(n)________.
A)aldopentose
B)aldohexose
C)ketopentose
D)aldotetrose
E)ketotetrose
A)aldopentose
B)aldohexose
C)ketopentose
D)aldotetrose
E)ketotetrose
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17
Chirality occurs when stereoisomers have mirror images that are ________.
A)superimposable
B)the same
C)not superimposable
D)not visible to one another
E)identical
A)superimposable
B)the same
C)not superimposable
D)not visible to one another
E)identical
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18
Photosynthesis uses ________ as an energy source.
A)glucose
B)carbon dioxide
C)chlorophyll
D)oxygen
E)sunlight
A)glucose
B)carbon dioxide
C)chlorophyll
D)oxygen
E)sunlight
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19
The sugar also known as dextrose,and blood sugar is ________.
A)glucose
B)galactose
C)fructose
D)lactose
E)sucrose
A)glucose
B)galactose
C)fructose
D)lactose
E)sucrose
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20
Which of the following objects is chiral? Assume that each object has no markings or printing.
A)an pencil
B)a baseball bat
C)a glove
D)a hockey puck
E)a drinking glass
A)an pencil
B)a baseball bat
C)a glove
D)a hockey puck
E)a drinking glass
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21
When glucose is oxidized the product is ________.
A)glucitol
B)gluconic acid
C)sucrose
D)galactose
E)maltose
A)glucitol
B)gluconic acid
C)sucrose
D)galactose
E)maltose
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22
Aspartame® and Saccharin® are two examples of ________.
A)disaccharides
B)polysaccharides
C)chlorosaccharides
D)alcohol sweeteners
E)noncarbohydrate sweeteners
A)disaccharides
B)polysaccharides
C)chlorosaccharides
D)alcohol sweeteners
E)noncarbohydrate sweeteners
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23
The form of glucose is the ________ isomer. 
A)alpha
B)beta
C)delta
D)second
E)keto

A)alpha
B)beta
C)delta
D)second
E)keto
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24
Which of the following contains a β-1,4-glycosidic bond?
A)galactose
B)lactose
C)maltose
D)sucrose
E)amylose
A)galactose
B)lactose
C)maltose
D)sucrose
E)amylose
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25
A glycosidic bond between two monosaccharides can also be classified as a(n)________.
A)double bond
B)ester bond
C)ether bond
D)achiral bond
E)alcohol bond
A)double bond
B)ester bond
C)ether bond
D)achiral bond
E)alcohol bond
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26
Glucose can have the structure shown below.It can be classified as a(n)________. 
A)ribose
B)ketose
C)disaccharide
D)monosaccharide
E)ketone

A)ribose
B)ketose
C)disaccharide
D)monosaccharide
E)ketone
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27
Maltose can be classified as a(n)________.
A)disaccharide
B)polysaccharide
C)ketose
D)pentose
E)tetrasaccharide
A)disaccharide
B)polysaccharide
C)ketose
D)pentose
E)tetrasaccharide
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28
Which sugar is not a reducing sugar?
A)glucose
B)fructose
C)galactose
D)maltose
E)sucrose
A)glucose
B)fructose
C)galactose
D)maltose
E)sucrose
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29
Refer to the disaccharide below to answer the following question(s). 
In the figure above,the monosaccharide on the top is a(n)________.
A)aldopentose
B)ketopentose
C)aldohexose
D)aldoheptose
E)ketohexose

In the figure above,the monosaccharide on the top is a(n)________.
A)aldopentose
B)ketopentose
C)aldohexose
D)aldoheptose
E)ketohexose
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30
The disaccharide above contains a(n)________-glycosidic linkage.
A)α-1,4
B)β-1,4
C)α-2,4
D)β-2,4
E)α-2,6
A)α-1,4
B)β-1,4
C)α-2,4
D)β-2,4
E)α-2,6
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31
Refer to the disaccharide below to answer the following question(s). 
Hydrolysis of the disaccharide above gives the monosaccharides ________.
A)fructose and ribose
B)fructose and galactose
C)ribose and glucose
D)ribose and galactose
E)fructose and lactose

Hydrolysis of the disaccharide above gives the monosaccharides ________.
A)fructose and ribose
B)fructose and galactose
C)ribose and glucose
D)ribose and galactose
E)fructose and lactose
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32
Hyperglycemia is a condition in which ________.
A)the glucose level in the blood is about 100 mg/dL
B)the amount of glucose in the urine is lower than normal
C)the glucose level in the blood is higher than normal
D)the glucose level in the pancreas is lower than normal
E)the glucose level in the liver is lower than normal
A)the glucose level in the blood is about 100 mg/dL
B)the amount of glucose in the urine is lower than normal
C)the glucose level in the blood is higher than normal
D)the glucose level in the pancreas is lower than normal
E)the glucose level in the liver is lower than normal
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33
Galactose is a ________.
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
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34
Hypoglycemia is a condition in which ________.
A)the glucose level in the blood is about 100 mg/dL
B)the amount of glucose in the urine is higher than normal
C)the glucose level in the blood is higher than normal
D)the glucose level in the pancreas is higher than normal
E)the glucose level in the blood is lower than normal
A)the glucose level in the blood is about 100 mg/dL
B)the amount of glucose in the urine is higher than normal
C)the glucose level in the blood is higher than normal
D)the glucose level in the pancreas is higher than normal
E)the glucose level in the blood is lower than normal
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35
When glucose is reduced the product is ________.
A)glucitol
B)gluconic acid
C)sucrose
D)galactose
E)maltose
A)glucitol
B)gluconic acid
C)sucrose
D)galactose
E)maltose
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36
Refer to the disaccharide below to answer the following question(s). 
In the figure above,the monosaccharide on the bottom is a(n)________.
A)aldopentose
B)ketopentose
C)aldohexose
D)aldoheptose
E)ketohexose

In the figure above,the monosaccharide on the bottom is a(n)________.
A)aldopentose
B)ketopentose
C)aldohexose
D)aldoheptose
E)ketohexose
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37
Maltose is a ________.
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
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38
Benedict's test requires an aldehyde and an adjacent ________.
A)saturated carbon
B)ketone
C)hydroxyl
D)phenyl ring
E)acid
A)saturated carbon
B)ketone
C)hydroxyl
D)phenyl ring
E)acid
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39
In a disaccharide,two monosaccharides are joined by what kind of bond?
A)double
B)anomeric
C)alcohol
D)glycosidic
E)rotational
A)double
B)anomeric
C)alcohol
D)glycosidic
E)rotational
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40
Galactose is a product of enzymatic hydrolysis of ________.
A)lactose
B)glucose
C)maltose
D)erythrose
E)sucrose
A)lactose
B)glucose
C)maltose
D)erythrose
E)sucrose
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41
State whether each of these structures is the α- or β-form.


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42
Identify each Fischer projection as the D- or L-isomer.


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43
Identify each Fischer projection as the D- or L-isomer.


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44
Under acid hydrolysis conditions,starch is converted to ________.
A)glucose
B)xylose
C)maltose
D)galactose
E)fructose
A)glucose
B)xylose
C)maltose
D)galactose
E)fructose
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45
Identify each Fischer projection as the D- or L-isomer.


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46
State whether each of these structures is the α- or β-form.


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47
Cellulose is not digestible by humans because it contains glucose units linked by ________-glycosidic bonds.
A)α-1,2
B)α-1,4
C)α-1,6
D)β-1,2
E)β-1,4
A)α-1,2
B)α-1,4
C)α-1,6
D)β-1,2
E)β-1,4
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48
Amylose is a ________.
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
A)monosaccharide
B)disaccharide
C)trisaccharide
D)polysaccharide
E)phosphosaccharide
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49
Humans cannot digest cellulose because they ________.
A)lack the necessary enzymes to digest β-glycosides
B)are allergic to β-glycosides
C)are poisoned by β-glycosides
D)have intestinal flora which use up β-glycosides
E)cannot digest chlorophyll
A)lack the necessary enzymes to digest β-glycosides
B)are allergic to β-glycosides
C)are poisoned by β-glycosides
D)have intestinal flora which use up β-glycosides
E)cannot digest chlorophyll
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50
Identify each Fischer projection as the D- or L-isomer.


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51
Amylose is a form of starch which has ________.
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and β-1,4-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and β-1,4-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
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52
Identify each Fischer projection as the D- or L-isomer.


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53
Cellulose is a polysaccharide which has ________.
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and α-1,6-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and α-1,6-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
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54
State whether each of these structures is the α- or β-form.


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55
State whether each of these structures is the α- or β-form.


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56
Amylose is a polysaccharide.
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57
State whether each of these structures is the α- or β-form.
Sucrose is a disaccharide.
Sucrose is a disaccharide.
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58
Amylopectin is a form of starch which has ________.
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and α-1,6-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
A)only β-1,4-bonds between glucose units
B)only α-1,4-links bonds glucose units
C)both α-1,4-and α-1,6-bonds between glucose units
D)hemiacetal links joining glucose units
E)carbon-carbon bonds joining glucose units
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59
Which of the following contains α-1,6-branches?
A)amylose
B)glycogen
C)cellulose
D)sucrose
E)maltose
A)amylose
B)glycogen
C)cellulose
D)sucrose
E)maltose
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60
State whether each of these structures is the α- or β-form.


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61
Amylopectin is a straight-chain polysaccharide.
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62
In beta-glucose,the new -OH group is above the plane of the ring.
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63
The product of oxidation of an aldose is a carboxylic acid.
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64
Enantiomers may have very different tastes or smells.
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65
Stereoisomers are not structural isomers.
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66
In the Fischer projection of D-glucose,the -OH group on the chiral carbon farthest from the aldehyde is to the left.
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67
In the Fischer projection of D-fructose,the -OH group on the chiral carbon farthest from the ketone is to the right.
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68
The product of reduction of xylose is xylitol.
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69
Aldehydes with an adjacent alcohol give a positive Benedict's test.
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70
A deep blue color in Benedict's test indicates the presence of an aldehyde with an adjacent alcohol.
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71
A reducing sugar gives a precipitate of silver metal with Benedict's reagent.
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72
Sucrose is a reducing sugar.
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73
In glucose,the -OH group on carbon 4 is above the plane of the ring.
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74
Sucrose is made up of glucose units only.
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75
Cellulose is a monosaccharide.
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76
The product of reduction of mannose is mannoic acid.
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77
The biological activity of one enantiomers may be very different from the biological activity of the other enantiomer.
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78
A chiral carbon atom can have fewer than four different groups bonded to it.
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79
Enantiomers are mirror images of each other.
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80
The glucose units in cellulose are connected by β-1,4-glycosidic bonds.
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