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Deck 11: Organometallic Compounds

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Question
Which of the following organometallic reagents is most reactive?

A) CH3CH2CH2CH2Li
B) CH3CH2CH2CH2MgBr
C) (CH3CH2CH2CH2)2CuLi
D) (CH3CH2CH2CH2)2Zn
E) (CH3CH2CH2CH2)2Cd
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Question
Which of the following solvents is suitable for the preparation of a Grignard reagent?

A) hexane
B) tetrahydrofuran
C) ethanol
D) diethyl ether
E) B and D
Question
Which halide is most often used to prepare a Grignard reagent?

A) F
B) Cl
C) Br
D) I
E) any of the above
Question
What is the product of the following reaction?
<strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>

A) <strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>
B) <strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>
C) <strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>
D) <strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>
E) <strong>What is the product of the following reaction? </strong> A) B) C) D) E) <div style=padding-top: 35px>
Question
What is the major product of the reaction shown here? <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>

A) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>
B) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>
C) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>
D) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>
E) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E) <div style=padding-top: 35px>
Question
The following reaction is an example of a ____________ reaction.
<strong>The following reaction is an example of a ____________ reaction. </strong> A) Gillman B) Grignard C) Heck D) Grubbs/metathesis E) Suzuki <div style=padding-top: 35px>

A) Gillman
B) Grignard
C) Heck
D) Grubbs/metathesis
E) Suzuki
Question
What type of reaction could not be used to accomplish the following? <strong>What type of reaction could not be used to accomplish the following? </strong> A) Gillman ((CH<sub>2</sub>=CH)<sub>2</sub>CuLi) B) Grignard (CH<sub>2</sub>=CHMgBr) C) Heck (CH<sub>2</sub>=CH<sub>2</sub>) D) Suzuki (CH<sub>2</sub>=CHB(OR)<sub>2</sub>) E) All of the above could be used. <div style=padding-top: 35px>

A) Gillman ((CH2=CH)2CuLi)
B) Grignard (CH2=CHMgBr)
C) Heck (CH2=CH2)
D) Suzuki (CH2=CHB(OR)2)
E) All of the above could be used.
Question
What type of reaction could be used to accomplish the following? <strong>What type of reaction could be used to accomplish the following? </strong> A) Gillman B) Grignard C) Heck D) Suzuki E) Grubbs/metathesis <div style=padding-top: 35px>

A) Gillman
B) Grignard
C) Heck
D) Suzuki
E) Grubbs/metathesis
Question
What type of reaction could be used to accomplish the following? <strong>What type of reaction could be used to accomplish the following? </strong> A) Gillman B) Grignard C) Heck D) Suzuki E) metathesis <div style=padding-top: 35px>

A) Gillman
B) Grignard
C) Heck
D) Suzuki
E) metathesis
Question
Which of the following would be an unlikely final product of a metathesis reaction?

A) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E) <div style=padding-top: 35px>
B) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E) <div style=padding-top: 35px>
C) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E) <div style=padding-top: 35px>
D) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E) <div style=padding-top: 35px>
E) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E) <div style=padding-top: 35px>
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Deck 11: Organometallic Compounds
1
Which of the following organometallic reagents is most reactive?

A) CH3CH2CH2CH2Li
B) CH3CH2CH2CH2MgBr
C) (CH3CH2CH2CH2)2CuLi
D) (CH3CH2CH2CH2)2Zn
E) (CH3CH2CH2CH2)2Cd
CH3CH2CH2CH2Li
2
Which of the following solvents is suitable for the preparation of a Grignard reagent?

A) hexane
B) tetrahydrofuran
C) ethanol
D) diethyl ether
E) B and D
B and D
3
Which halide is most often used to prepare a Grignard reagent?

A) F
B) Cl
C) Br
D) I
E) any of the above
Br
4
What is the product of the following reaction?
<strong>What is the product of the following reaction? </strong> A) B) C) D) E)

A) <strong>What is the product of the following reaction? </strong> A) B) C) D) E)
B) <strong>What is the product of the following reaction? </strong> A) B) C) D) E)
C) <strong>What is the product of the following reaction? </strong> A) B) C) D) E)
D) <strong>What is the product of the following reaction? </strong> A) B) C) D) E)
E) <strong>What is the product of the following reaction? </strong> A) B) C) D) E)
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5
What is the major product of the reaction shown here? <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)

A) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)
B) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)
C) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)
D) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)
E) <strong>What is the major product of the reaction shown here? </strong> A) B) C) D) E)
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6
The following reaction is an example of a ____________ reaction.
<strong>The following reaction is an example of a ____________ reaction. </strong> A) Gillman B) Grignard C) Heck D) Grubbs/metathesis E) Suzuki

A) Gillman
B) Grignard
C) Heck
D) Grubbs/metathesis
E) Suzuki
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7
What type of reaction could not be used to accomplish the following? <strong>What type of reaction could not be used to accomplish the following? </strong> A) Gillman ((CH<sub>2</sub>=CH)<sub>2</sub>CuLi) B) Grignard (CH<sub>2</sub>=CHMgBr) C) Heck (CH<sub>2</sub>=CH<sub>2</sub>) D) Suzuki (CH<sub>2</sub>=CHB(OR)<sub>2</sub>) E) All of the above could be used.

A) Gillman ((CH2=CH)2CuLi)
B) Grignard (CH2=CHMgBr)
C) Heck (CH2=CH2)
D) Suzuki (CH2=CHB(OR)2)
E) All of the above could be used.
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8
What type of reaction could be used to accomplish the following? <strong>What type of reaction could be used to accomplish the following? </strong> A) Gillman B) Grignard C) Heck D) Suzuki E) Grubbs/metathesis

A) Gillman
B) Grignard
C) Heck
D) Suzuki
E) Grubbs/metathesis
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9
What type of reaction could be used to accomplish the following? <strong>What type of reaction could be used to accomplish the following? </strong> A) Gillman B) Grignard C) Heck D) Suzuki E) metathesis

A) Gillman
B) Grignard
C) Heck
D) Suzuki
E) metathesis
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10
Which of the following would be an unlikely final product of a metathesis reaction?

A) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E)
B) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E)
C) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E)
D) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E)
E) <strong>Which of the following would be an unlikely final product of a metathesis reaction?</strong> A) B) C) D) E)
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