Deck 14: Chemical Equilibrium

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Question
What is △n for the following equation in relating Kc to Kp?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)4
B)-4
C)-2
D)2
E)1
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Question
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant.
A(g)+ 2B(g)⇌ AB2(g)Kc = 59
AB2(g)+ B(g)⇌ AB3(g)Kc = ?
A(g)+ 3B(g)⇌ AB3(g)Kc = 478

A)3.5 × 10-5
B)2.8 × 104
C)8.1
D)0.12
E)89
Question
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
H2(g)+ Br2(g)⇌ 2 HBr(g)Kc = 3.8 × 104
2 HBr(g)⇌ H2(g)+ Br2(g)Kc = ?

A)1.9 × 104
B)5.3 × 10-5
C)2.6 × 10-5
D)6.4 × 10-4
E)1.6 × 103
Question
Express the equilibrium constant for the following reaction.
2 CH3Cl(g)+ Cl2(g)⇌ 2 CH2Cl2(g)+ H2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
C)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
E)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
Question
Give the direction of the reaction,if K >> 1.

A)The forward reaction is favored.
B)The reverse reaction is favored.
C)Neither direction is favored.
D)If the temperature is raised,then the forward reaction is favored.
E)If the temperature is raised,then the reverse reaction is favored.
Question
Express the equilibrium constant for the following reaction.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
C)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
E)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
Question
In which of the following reactions will Kc = Kp?

A)H2(g)+ I2(g)⇌ 2 HI(g)
B)CH4(g)+ H2O(g)⇌ CO(g)+ 3 H2(g)
C)N2O4(g)⇌ 2NO2(g)
D)CO(g)+ 2 H2(g)⇌ CH3OH(g)
E)N2(g)+ 3 H2(g)⇌ 2 NH3(g)
Question
Express the equilibrium constant for the following reaction.
H2(g)+ Br2(g)⇌ 2 HBr(g)

A)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
C)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
E)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
Question
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant.
A(g)+ B(g)⇌ AB(g)Kc = 0.24
AB(g)+ A(g)⇌ A2B(g)Kc = 3.8
2 A(g)+ B(g)⇌ A2B(g)Kc = ?

A)4.0
B)0.91
C)3.6
D)16
E)0.63
Question
In which of the following reactions will Kc = Kp?

A)4 NH3(g)+ 3 O2(g)⇌ 2 N2(g)+ 6 H2O(g)
B)SO3(g)+ NO(g)⇌ SO2(g)+ NO2(g)
C)2 N2(g)+ O2(g)⇌ 2 N2O(g)
D)2 SO2(g)+ O2(g)⇌ 2 SO3(g)
E)None of the above reactions have Kc = Kp.
Question
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
N2O4(g)⇌ 2 NO2(g)Kc = 1.46
3 N2O4(g)⇌ 6 NO2(g)Kc = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
Question
Which of the following statements is false?

A)When K >> 1,the forward reaction is favored and essentially goes to completion.
B)When K << 1,the reverse reaction is favored and the forward reaction does not proceed to a great extent.
C)When K ≈ 1,neither the forward or reverse reaction is strongly favored,and about the same amount of reactants and products exist at equilibrium.
D)K >> 1 implies that the reaction is very fast at producing products.
E)None of the above
Question
Give the direction of the reaction,if K << 1.

A)The forward reaction is favored.
B)The reverse reaction is favored.
C)Neither direction is favored.
D)If the temperature is raised,then the forward reaction is favored.
E)If the temperature is raised,then the reverse reaction is favored.
Question
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
2 HD(g)⇌ H2(g)+ D2(g)Kc = 0.28
2 H2(g)+ 2 D2(g)⇌ 4 HD(g)Kc = ?

A)7.8 × 10-2
B)3.6
C)0.53
D)13
E)1.9
Question
Express the equilibrium constant for the following reaction.
PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
C)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
E)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
Question
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
2 SO2(g)+ O2(g)⇌ 2 SO3(g)Kc = 1.7 × 106
SO3(g)⇌ 1/2 O2(g)+ SO2(g)Kc = ?

A)3.4 × 102
B)8.5
C)1.3 × 103
D)1.2 × 10-6
E)7.7 × 10-4
Question
What is △n for the following equation in relating Kc to Kp?
2 NH3(g)⇌ N2(g)+ 3 H2(g)

A)4
B)-4
C)-2
D)2
E)1
Question
What is △n for the following equation in relating Kc to Kp?
H2(g)+ Br2(g)⇌ 2 HBr(g)

A)0
B)-1
C)-2
D)2
E)1
Question
Express the equilibrium constant for the following reaction.
2 P(g)+ 3 Cl2(g)⇌ 2 PCl3(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
C)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
E)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =   <div style=padding-top: 35px>
Question
What is △n for the following equation in relating Kc to Kp?
2 SO2(g)+ O2(g)⇌ 2 SO3(g)

A)3
B)-1
C)-2
D)2
E)1
Question
Which of the following statements are true?

A)Dynamic equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction.
B)The equilibrium constant for the forward reaction is equal to the equilibrium constant for the reverse reaction.
C)A reaction quotient (Q)larger than the equilibrium constant (K)means that the reaction will favor the production of more products.
D)Dynamic equilibrium indicates that the amount of reactants and products are equal.
E)All of the above are true.
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 M,[O2]eq = 4.1 M,[N2O]eq = 3.3 × 10-18 M.
2 N2(g)+ O2(g)⇌ 2 N2O(g)

A)2.2 × 10-19
B)4.5 × 1018
C)2.0 × 10-37
D)5.0 × 1036
E)4.9 × 10-17
Question
For which reaction will Kp = Kc?

A)S(s)+ O2(g)⇌ SO2(g)
B)2 HgO(s)⇌ Hg(l)+ O2(g)
C)CaCO3(s)⇌ CaO(s)+ CO2(g)
D)H2CO3(s)⇌ H2O(l)+ CO2(g)
E)2 H2O(l)⇌ 2 H2(g)+ O2(g)
Question
Calculate P [NO]eq,if P [NOCl]eq = 0.33 atm,P [Cl2]eq = 0.50 atm,and Kp = 1.9 × 10-2.
2 NOCl(g)⇌ 2 NO(g)+ Cl2(g)

A)1.7 atm
B)0.0042 atm
C)0.30 atm
D)0.064 atm
E)0.087 atm
Question
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm.
2 CO(g)+ O2(g)⇌ 2 CO2(g)

A)3.6 × 10-21
B)2.8 × 1020
C)4.6 × 1011
D)2.2 × 10-12
E)3.6 × 10-15
Question
The reaction below has a Kc value of 61.What is the value of Kp for this reaction at 500 K?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)15
B)61
C)28
D)3.6 × 10-2
E)1.9 × 10-2
Question
Which of the following statements is true?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the forward reaction will proceed to form more products.
C)If Q = K,it means the reaction is at equilibrium.
D)All of the above are true.
E)None of the above are true.
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 M,[H2]eq = 1.1 M,[NH3]eq = 0.47 M.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)3.5
B)0.28
C)9.1
D)0.11
E)0.78
Question
The reaction below has a Kc value of 1.0 × 1012.What is the value of Kp for this reaction at 500 K?
2 SO2(g)+ O2(g)⇌ 2 SO3(g)

A)4.2 × 10-11
B)1.0 × 1012
C)2.4 × 10-12
D)4.1 × 1013
E)2.4 × 1010
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 M,[HI]eq = 5.6 × 10-16 M,[Cl2]eq = 0.0019 M.
2 HCl(g)+ I2(s)⇌ 2 HI(g)+ Cl2(g)

A)8.2 × 10-18
B)2.9 × 1031
C)1.2 × 1017
D)1.4 × 10-19
E)3.5 × 10-32
Question
Express the equilibrium constant for the following reaction.
P4(s)+ 5 O2(g)⇌ P4O10(s)

A)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =   <div style=padding-top: 35px>
B)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =   <div style=padding-top: 35px>
C)K = [O2]-5
D)K = [O2]5
E)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =   <div style=padding-top: 35px>
Question
The reaction below has a Kp value of 3.3 × 10-5.What is the value of Kc for this reaction at 700 K?
2 SO3(g)⇌ 2 SO2(g)+ O2(g)

A)5.7 × 10-7
B)1.7 × 106
C)3.3 × 10-5
D)3.0 × 104
E)1.9 × 10-3
Question
Calculate the value of [N2]eq if [H2]eq = 2.0 M,[NH3]eq = 0.5 M,and Kc = 2.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)0.016 M
B)0.031 M
C)0.062 M
D)0.40 M
E)62.5 M
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 M,[PCl3]eq = 0.23 M,[Cl2]eq = 4.4 M.
PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)1.8
B)0.93
C)0.55
D)1.1
E)0.76
Question
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 M,[I2]eq = 0.39 M,[HI]eq = 1.6 M.
H2(g)+ I2(g)⇌ 2 HI(g)

A)2.1 × 10-2
B)29
C)47
D)3.4 × 10-2
E)8.7 × 10-2
Question
The reaction below has a Kp value of 41.What is the value of Kc for this reaction at 400 K?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)2.4 × 10-2
B)4.4 × 104
C)41
D)2.3 × 10-5
E)1.9 × 104
Question
In a reaction mixture containing only reactants,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)It cannot be determined without concentrations.
Question
Express the equilibrium constant for the following reaction.
2 Na(s)+ 2 H2O(l)⇌ 2 NaOH(aq)+ H2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =   <div style=padding-top: 35px>
B)K = [H2][NaOH]-2
C)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =   <div style=padding-top: 35px>
D)K = [H2][NaOH]2
E)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =   <div style=padding-top: 35px>
Question
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl)eq = 0.22 atm,P(NO)eq = 0.10 atm,P(Cl2)eq = 0.081 atm.
2 NOCl(g)? 2 NO(g)+ Cl2(g)

A)3.7 × 10-2
B)60.
C)27
D)1.7 × 10-2
E)1.8 × 10-3
Question
Express the equilibrium constant for the following reaction.
KClO3(s)⇌ KClO(s)+ O2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>] <div style=padding-top: 35px>
B)K = [O2]-1
C)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>] <div style=padding-top: 35px>
D)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>] <div style=padding-top: 35px>
E)K = [O2]
Question
Consider the following reaction:
2 H2O(g)+ 2 SO2(g)⇌ 2 H2S(g)+ 3 O2(g)
A reaction mixture initially contains 2.8 M H2O and 2.6 M SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6.

A)0.045 M
B)0.058 M
C)0.028 M
D)3.1 × 10-3 M
E)0.12 M
Question
Consider the following reaction and its equilibrium constant:
I2(g)⇌ 2I(g)Kp = 0.209
A reaction mixture contains 0.89 atm I2 and 1.77 atm I.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of reactants.
B)The reaction quotient will increase.
C)The reaction will shift in the direction of products.
D)The equilibrium constant will decrease.
E)The system is at equilibrium.
Question
Consider the following reaction and its equilibrium constant:
SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)Kc = 0.33
A reaction mixture contains 0.39 M SO2,0.14 M NO2,0.11 M SO3 and 0.14 M NO.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of reactants.
B)The equilibrium constant will decrease.
C)The reaction will shift in the direction of products.
D)The reaction quotient will decrease.
E)The system is at equilibrium.
Question
Consider the following reaction:
CO2(g)+ C(graphite)⇌ 2 CO(g)
A reaction mixture initially contains 0.56 atm CO2 and 0.32 atm CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25.

A)0.83 atm
B)0.31 atm
C)0.26 atm
D)0.58 atm
E)0.42 atm
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2.
D2(g)+ H2(g)⇌ 2 HD(g)Kp = 1.80
P(D2)eq = 1.1 × 10-3 atm P(HD)eq = 2.7 × 10-3 atm

A)2.7 atm
B)1.4 atm
C)0.73 atm
D)3.7 × 10-3 atm
E)8.1 × 10-4 atm
Question
Consider the following reaction: Xe(g)+ 2 F2(g)→ XeF4(g)
A reaction mixture initially contains 2.24 atm Xe and 4.27 atm F2.If the equilibrium pressure of Xe is 0.34 atm,find the equilibrium constant (Kp)for the reaction.

A)25
B)0.12
C)0.99
D)8.3
E)0.040
Question
Consider the following reaction:
COCl2(g)⇌ CO(g)+ Cl2(g0
A reaction mixture initially contains 1.6 M COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4.Calculate this based on the assumption that the answer is negligible compared to 1.6.

A)4.2 × 10-4 M
B)1.5 × 10-3 M
C)3.7 × 10-2 M
D)2.1 × 10-2 M
E)1.3 × 10-3 M
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO.
CO(g)+ 2 H2(g)⇌ CH3OH(l)Kp = 2.25 × 104
P(H2)eq = 0.52 atm

A)8.3 × 104 atm
B)1.2 × 10-5 atm
C)6.25 × 10-3 atm
D)8.5 × 10-5 atm
E)1.6 × 10-4 atm
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g).
NH2COONH4(s)⇌ 2 NH3(g)+ CO2(g)Kc = 1.58 × 10-8
[NH3]eq = 2.9 × 10-3 M

A)0.053 M
B)4.6 × 10-11 M
C)1.9 × 10-3 M
D)5.4 × 10-6 M
E)0.022 M
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g).
N2O4(g)⇌ 2 NO2(g) Kc = 0.21
[N2O4]eq = 0.039 M

A)1.22 M
B)9.0 × 10-2 M
C)7.8 × 10-2 M
D)8.2 × 10-3 M
E)11 M
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO3(g).
2 SO2(g)+ O2(g)⇌ 2 SO3(g)Kc = 1.7 × 108
[SO2]eq = 0.0034 M [O2]eq = 0.0018 M

A)1.9 M
B)1.0 × 103 M
C)0.53 M
D)9.6 × 10-4 M
E)0.73 M
Question
Consider the following reaction at equilibrium.What effect will adding some C have on the system?
CO2(g)+ C(graphite)⇌ 2 CO(g)

A)No effect will be observed since C is not included in the equilibrium expression.
B)The equilibrium constant will decrease.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will increase.
E)The reaction will shift to the right in the direction of products.
Question
Consider the following reaction:
NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.86 atm NO and 0.86 atm SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.78 atm
B)0.084 atm
C)0.012 atm
D)0.85 atm
E)0.048 atm
Question
Consider the following reaction and its equilibrium constant:
4 CuO(s)+ CH4(g)⇌ CO2(g)+ 4 Cu(s)+ 2 H2O(g)Kc = 1.10
A reaction mixture contains 0.22 M CH4,0.67 M CO2 and 1.3 M H2O.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of products.
B)The equilibrium constant will increase.
C)The reaction quotient will increase.
D)The reaction will shift in the direction of reactants.
E)The system is at equilibrium.
Question
Consider the following reaction:
CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)
A reaction mixture initially contains 2.9 M O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

A)1.9 M
B)1.7 M
C)2.2 M
D)1.2 M
E)0.59 M
Question
Consider the following reaction at equilibrium.What effect will adding more H2S have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the left.
B)No change will be observed.
C)The equilibrium constant will decrease.
D)The equilibrium constant will increase.
E)The reaction will shift in the direction of products.
Question
Consider the following reaction at equilibrium.What effect will adding more SO3 have on the system?
SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)

A)The reaction will shift in the direction of products.
B)The reaction will shift to decrease the pressure.
C)No change will occur since SO3 is not included in the equilibrium expression.
D)The reaction will shift in the direction of reactants.
E)The equilibrium constant will decrease.
Question
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g).
C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103
[C2H4]eq = 0.015 M [C2H5OH]eq = 1.69 M

A)9.9 × 10-7 M
B)80.M
C)1.0 M
D)1.68 M
E)0.013 M
Question
Consider the following reaction:
CH4(g)+ 2 H2S(g)⇌ CS2(g)+ 4 H2(g)
A reaction mixture initially contains 0.50 M CH4 and 0.75 M H2S.If the equilibrium concentration of H2 is 0.44 M,find the equilibrium constant (Kc)for the reaction.

A)0.23
B)0.038
C)2.9
D)10.
E)0.34
Question
Consider the following reaction and its equilibrium constant:
I2(g)+ Br2(g)⇌ 2 IBr(g)Kc = 1.1 × 102
A reaction mixture contains 0.41 M I2,0.27 M Br2 and 3.5 M IBr.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of products.
B)The reaction will shift in the direction of reactants.
C)The reaction quotient will decrease.
D)The equilibrium constant will increase.
E)The system is at equilibrium.
Question
Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system?
C3H8(g)+ 5 O2(g)⇌ 3 CO2(g)+ 4 H2O(l)ΔH° = -2220 kJ

A)The reaction will shift to the right in the direction of products.
B)The reaction will shift to the left in the direction of reactants.
C)The equilibrium constant will increase.
D)The equilibrium constant will decrease.
E)No effect will be observed.
Question
Why is an equilibrium constant unitless?
Question
Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system?
CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)

A)The equilibrium constant will decrease.
B)No effect will be observed.
C)The reaction will shift to the right in the direction of products.
D)The equilibrium constant will increase.
E)The reaction will shift to the left in the direction of reactants.
Question
Consider the following reaction at equilibrium.What effect will reducing the pressure of the reaction mixture have on the system?
Xe(g)+ 2 F2(g)→ XeF4(g)

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)No effect will be observed.
D)The reaction will shift to the right in the direction of products.
E)The equilibrium constant will decrease.
Question
Consider the following reaction at equilibrium.What effect will adding 1 atm of Ar to the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
Question
Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system? Xe(g)+ 2 F2(g)→ XeF4(g)

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)No effect will be observed.
D)The reaction will shift to the right in the direction of products.
E)The equilibrium constant will decrease.
Question
Consider the following reaction at equilibrium.What effect will increasing the pressure of the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
Question
Consider the following reaction at equilibrium.What effect will adding water have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
Question
Consider the following reaction at equilibrium.What effect will increasing the volume of the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
Question
Why aren't solids or liquids included in an equilibrium expression?
Question
Match the following.
Q < K

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
Question
Match the following.
Q = K

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
Question
Match the following.
K ≈ 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
Question
Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system?
Fe3O4(s)+ CO(g)⇌ 3 FeO(s)+ CO2(g)ΔH°= +35.9 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)The equilibrium constant will decrease.
D)No effect will be observed.
E)The reaction will shift to the right in the direction of products.
Question
Match the following.
Q >> 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
Question
Match the following.
K << 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
Question
Can the Kp and Kc for a reaction ever have the same value? Why or why not?
Question
Consider the following reaction at equilibrium.What effect will decreasing the temperature have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
Question
Explain dynamic equilibrium.Use the generic reaction A(g)⇌ B(g)to explain.
Question
Consider the following reaction at equilibrium.What effect will adding a catalyst have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
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Deck 14: Chemical Equilibrium
1
What is △n for the following equation in relating Kc to Kp?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)4
B)-4
C)-2
D)2
E)1
-2
2
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant.
A(g)+ 2B(g)⇌ AB2(g)Kc = 59
AB2(g)+ B(g)⇌ AB3(g)Kc = ?
A(g)+ 3B(g)⇌ AB3(g)Kc = 478

A)3.5 × 10-5
B)2.8 × 104
C)8.1
D)0.12
E)89
8.1
3
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
H2(g)+ Br2(g)⇌ 2 HBr(g)Kc = 3.8 × 104
2 HBr(g)⇌ H2(g)+ Br2(g)Kc = ?

A)1.9 × 104
B)5.3 × 10-5
C)2.6 × 10-5
D)6.4 × 10-4
E)1.6 × 103
2.6 × 10-5
4
Express the equilibrium constant for the following reaction.
2 CH3Cl(g)+ Cl2(g)⇌ 2 CH2Cl2(g)+ H2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
C)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
D)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
E)K = <strong>Express the equilibrium constant for the following reaction. 2 CH<sub>3</sub>Cl(g)+ Cl<sub>2</sub>(g)⇌ 2 CH<sub>2</sub>Cl<sub>2</sub>(g)+ H<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
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5
Give the direction of the reaction,if K >> 1.

A)The forward reaction is favored.
B)The reverse reaction is favored.
C)Neither direction is favored.
D)If the temperature is raised,then the forward reaction is favored.
E)If the temperature is raised,then the reverse reaction is favored.
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6
Express the equilibrium constant for the following reaction.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
C)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
D)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
E)K = <strong>Express the equilibrium constant for the following reaction. N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)⇌ 2 NH<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
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7
In which of the following reactions will Kc = Kp?

A)H2(g)+ I2(g)⇌ 2 HI(g)
B)CH4(g)+ H2O(g)⇌ CO(g)+ 3 H2(g)
C)N2O4(g)⇌ 2NO2(g)
D)CO(g)+ 2 H2(g)⇌ CH3OH(g)
E)N2(g)+ 3 H2(g)⇌ 2 NH3(g)
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8
Express the equilibrium constant for the following reaction.
H2(g)+ Br2(g)⇌ 2 HBr(g)

A)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
C)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
D)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
E)K = <strong>Express the equilibrium constant for the following reaction. H<sub>2</sub>(g)+ Br<sub>2</sub>(g)⇌ 2 HBr(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
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9
The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant.
A(g)+ B(g)⇌ AB(g)Kc = 0.24
AB(g)+ A(g)⇌ A2B(g)Kc = 3.8
2 A(g)+ B(g)⇌ A2B(g)Kc = ?

A)4.0
B)0.91
C)3.6
D)16
E)0.63
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10
In which of the following reactions will Kc = Kp?

A)4 NH3(g)+ 3 O2(g)⇌ 2 N2(g)+ 6 H2O(g)
B)SO3(g)+ NO(g)⇌ SO2(g)+ NO2(g)
C)2 N2(g)+ O2(g)⇌ 2 N2O(g)
D)2 SO2(g)+ O2(g)⇌ 2 SO3(g)
E)None of the above reactions have Kc = Kp.
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11
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
N2O4(g)⇌ 2 NO2(g)Kc = 1.46
3 N2O4(g)⇌ 6 NO2(g)Kc = ?

A)2.13
B)0.685
C)3.11
D)1.46
E)1.13
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12
Which of the following statements is false?

A)When K >> 1,the forward reaction is favored and essentially goes to completion.
B)When K << 1,the reverse reaction is favored and the forward reaction does not proceed to a great extent.
C)When K ≈ 1,neither the forward or reverse reaction is strongly favored,and about the same amount of reactants and products exist at equilibrium.
D)K >> 1 implies that the reaction is very fast at producing products.
E)None of the above
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13
Give the direction of the reaction,if K << 1.

A)The forward reaction is favored.
B)The reverse reaction is favored.
C)Neither direction is favored.
D)If the temperature is raised,then the forward reaction is favored.
E)If the temperature is raised,then the reverse reaction is favored.
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14
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
2 HD(g)⇌ H2(g)+ D2(g)Kc = 0.28
2 H2(g)+ 2 D2(g)⇌ 4 HD(g)Kc = ?

A)7.8 × 10-2
B)3.6
C)0.53
D)13
E)1.9
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15
Express the equilibrium constant for the following reaction.
PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
C)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
D)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
E)K = <strong>Express the equilibrium constant for the following reaction. PCl<sub>5</sub>(g)⇌ PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
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16
The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant.
2 SO2(g)+ O2(g)⇌ 2 SO3(g)Kc = 1.7 × 106
SO3(g)⇌ 1/2 O2(g)+ SO2(g)Kc = ?

A)3.4 × 102
B)8.5
C)1.3 × 103
D)1.2 × 10-6
E)7.7 × 10-4
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17
What is △n for the following equation in relating Kc to Kp?
2 NH3(g)⇌ N2(g)+ 3 H2(g)

A)4
B)-4
C)-2
D)2
E)1
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18
What is △n for the following equation in relating Kc to Kp?
H2(g)+ Br2(g)⇌ 2 HBr(g)

A)0
B)-1
C)-2
D)2
E)1
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19
Express the equilibrium constant for the following reaction.
2 P(g)+ 3 Cl2(g)⇌ 2 PCl3(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
C)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
D)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
E)K = <strong>Express the equilibrium constant for the following reaction. 2 P(g)+ 3 Cl<sub>2</sub>(g)⇌ 2 PCl<sub>3</sub>(g)</strong> A)K =   B)K =   C)K =   D)K =   E)K =
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20
What is △n for the following equation in relating Kc to Kp?
2 SO2(g)+ O2(g)⇌ 2 SO3(g)

A)3
B)-1
C)-2
D)2
E)1
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21
Which of the following statements are true?

A)Dynamic equilibrium occurs when the rate of the forward reaction equals the rate of the reverse reaction.
B)The equilibrium constant for the forward reaction is equal to the equilibrium constant for the reverse reaction.
C)A reaction quotient (Q)larger than the equilibrium constant (K)means that the reaction will favor the production of more products.
D)Dynamic equilibrium indicates that the amount of reactants and products are equal.
E)All of the above are true.
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22
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 M,[O2]eq = 4.1 M,[N2O]eq = 3.3 × 10-18 M.
2 N2(g)+ O2(g)⇌ 2 N2O(g)

A)2.2 × 10-19
B)4.5 × 1018
C)2.0 × 10-37
D)5.0 × 1036
E)4.9 × 10-17
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23
For which reaction will Kp = Kc?

A)S(s)+ O2(g)⇌ SO2(g)
B)2 HgO(s)⇌ Hg(l)+ O2(g)
C)CaCO3(s)⇌ CaO(s)+ CO2(g)
D)H2CO3(s)⇌ H2O(l)+ CO2(g)
E)2 H2O(l)⇌ 2 H2(g)+ O2(g)
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24
Calculate P [NO]eq,if P [NOCl]eq = 0.33 atm,P [Cl2]eq = 0.50 atm,and Kp = 1.9 × 10-2.
2 NOCl(g)⇌ 2 NO(g)+ Cl2(g)

A)1.7 atm
B)0.0042 atm
C)0.30 atm
D)0.064 atm
E)0.087 atm
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25
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm.
2 CO(g)+ O2(g)⇌ 2 CO2(g)

A)3.6 × 10-21
B)2.8 × 1020
C)4.6 × 1011
D)2.2 × 10-12
E)3.6 × 10-15
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26
The reaction below has a Kc value of 61.What is the value of Kp for this reaction at 500 K?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)15
B)61
C)28
D)3.6 × 10-2
E)1.9 × 10-2
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27
Which of the following statements is true?

A)If Q < K,it means the reverse reaction will proceed to form more reactants.
B)If Q > K,it means the forward reaction will proceed to form more products.
C)If Q = K,it means the reaction is at equilibrium.
D)All of the above are true.
E)None of the above are true.
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28
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 M,[H2]eq = 1.1 M,[NH3]eq = 0.47 M.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)3.5
B)0.28
C)9.1
D)0.11
E)0.78
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29
The reaction below has a Kc value of 1.0 × 1012.What is the value of Kp for this reaction at 500 K?
2 SO2(g)+ O2(g)⇌ 2 SO3(g)

A)4.2 × 10-11
B)1.0 × 1012
C)2.4 × 10-12
D)4.1 × 1013
E)2.4 × 1010
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30
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 M,[HI]eq = 5.6 × 10-16 M,[Cl2]eq = 0.0019 M.
2 HCl(g)+ I2(s)⇌ 2 HI(g)+ Cl2(g)

A)8.2 × 10-18
B)2.9 × 1031
C)1.2 × 1017
D)1.4 × 10-19
E)3.5 × 10-32
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31
Express the equilibrium constant for the following reaction.
P4(s)+ 5 O2(g)⇌ P4O10(s)

A)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =
B)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =
C)K = [O2]-5
D)K = [O2]5
E)K = <strong>Express the equilibrium constant for the following reaction. P<sub>4</sub>(s)+ 5 O<sub>2</sub>(g)⇌ P<sub>4</sub>O<sub>10</sub>(s)</strong> A)K =   B)K =   C)K = [O<sub>2</sub>]<sup>-5</sup> D)K = [O<sub>2</sub>]<sup>5</sup> E)K =
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32
The reaction below has a Kp value of 3.3 × 10-5.What is the value of Kc for this reaction at 700 K?
2 SO3(g)⇌ 2 SO2(g)+ O2(g)

A)5.7 × 10-7
B)1.7 × 106
C)3.3 × 10-5
D)3.0 × 104
E)1.9 × 10-3
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33
Calculate the value of [N2]eq if [H2]eq = 2.0 M,[NH3]eq = 0.5 M,and Kc = 2.
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)0.016 M
B)0.031 M
C)0.062 M
D)0.40 M
E)62.5 M
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34
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 M,[PCl3]eq = 0.23 M,[Cl2]eq = 4.4 M.
PCl5(g)⇌ PCl3(g)+ Cl2(g)

A)1.8
B)0.93
C)0.55
D)1.1
E)0.76
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35
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [H2]eq = 0.14 M,[I2]eq = 0.39 M,[HI]eq = 1.6 M.
H2(g)+ I2(g)⇌ 2 HI(g)

A)2.1 × 10-2
B)29
C)47
D)3.4 × 10-2
E)8.7 × 10-2
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36
The reaction below has a Kp value of 41.What is the value of Kc for this reaction at 400 K?
N2(g)+ 3 H2(g)⇌ 2 NH3(g)

A)2.4 × 10-2
B)4.4 × 104
C)41
D)2.3 × 10-5
E)1.9 × 104
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37
In a reaction mixture containing only reactants,what is the value of Q?

A)-1
B)1
C)∞
D)0
E)It cannot be determined without concentrations.
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38
Express the equilibrium constant for the following reaction.
2 Na(s)+ 2 H2O(l)⇌ 2 NaOH(aq)+ H2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =
B)K = [H2][NaOH]-2
C)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =
D)K = [H2][NaOH]2
E)K = <strong>Express the equilibrium constant for the following reaction. 2 Na(s)+ 2 H<sub>2</sub>O(l)⇌ 2 NaOH(aq)+ H<sub>2</sub>(g)</strong> A)K =   B)K = [H<sub>2</sub>][NaOH]<sup>-2</sup> C)K =   D)K = [H<sub>2</sub>][NaOH]<sup>2</sup> E)K =
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39
Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(NOCl)eq = 0.22 atm,P(NO)eq = 0.10 atm,P(Cl2)eq = 0.081 atm.
2 NOCl(g)? 2 NO(g)+ Cl2(g)

A)3.7 × 10-2
B)60.
C)27
D)1.7 × 10-2
E)1.8 × 10-3
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40
Express the equilibrium constant for the following reaction.
KClO3(s)⇌ KClO(s)+ O2(g)

A)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>]
B)K = [O2]-1
C)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>]
D)K = <strong>Express the equilibrium constant for the following reaction. KClO<sub>3</sub>(s)⇌ KClO(s)+ O<sub>2</sub>(g)</strong> A)K =   B)K = [O<sub>2</sub>]<sup>-1</sup> C)K =   D)K =   E)K = [O<sub>2</sub>]
E)K = [O2]
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41
Consider the following reaction:
2 H2O(g)+ 2 SO2(g)⇌ 2 H2S(g)+ 3 O2(g)
A reaction mixture initially contains 2.8 M H2O and 2.6 M SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6.

A)0.045 M
B)0.058 M
C)0.028 M
D)3.1 × 10-3 M
E)0.12 M
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42
Consider the following reaction and its equilibrium constant:
I2(g)⇌ 2I(g)Kp = 0.209
A reaction mixture contains 0.89 atm I2 and 1.77 atm I.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of reactants.
B)The reaction quotient will increase.
C)The reaction will shift in the direction of products.
D)The equilibrium constant will decrease.
E)The system is at equilibrium.
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43
Consider the following reaction and its equilibrium constant:
SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)Kc = 0.33
A reaction mixture contains 0.39 M SO2,0.14 M NO2,0.11 M SO3 and 0.14 M NO.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of reactants.
B)The equilibrium constant will decrease.
C)The reaction will shift in the direction of products.
D)The reaction quotient will decrease.
E)The system is at equilibrium.
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44
Consider the following reaction:
CO2(g)+ C(graphite)⇌ 2 CO(g)
A reaction mixture initially contains 0.56 atm CO2 and 0.32 atm CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25.

A)0.83 atm
B)0.31 atm
C)0.26 atm
D)0.58 atm
E)0.42 atm
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45
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2.
D2(g)+ H2(g)⇌ 2 HD(g)Kp = 1.80
P(D2)eq = 1.1 × 10-3 atm P(HD)eq = 2.7 × 10-3 atm

A)2.7 atm
B)1.4 atm
C)0.73 atm
D)3.7 × 10-3 atm
E)8.1 × 10-4 atm
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46
Consider the following reaction: Xe(g)+ 2 F2(g)→ XeF4(g)
A reaction mixture initially contains 2.24 atm Xe and 4.27 atm F2.If the equilibrium pressure of Xe is 0.34 atm,find the equilibrium constant (Kp)for the reaction.

A)25
B)0.12
C)0.99
D)8.3
E)0.040
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47
Consider the following reaction:
COCl2(g)⇌ CO(g)+ Cl2(g0
A reaction mixture initially contains 1.6 M COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4.Calculate this based on the assumption that the answer is negligible compared to 1.6.

A)4.2 × 10-4 M
B)1.5 × 10-3 M
C)3.7 × 10-2 M
D)2.1 × 10-2 M
E)1.3 × 10-3 M
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48
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO.
CO(g)+ 2 H2(g)⇌ CH3OH(l)Kp = 2.25 × 104
P(H2)eq = 0.52 atm

A)8.3 × 104 atm
B)1.2 × 10-5 atm
C)6.25 × 10-3 atm
D)8.5 × 10-5 atm
E)1.6 × 10-4 atm
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49
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g).
NH2COONH4(s)⇌ 2 NH3(g)+ CO2(g)Kc = 1.58 × 10-8
[NH3]eq = 2.9 × 10-3 M

A)0.053 M
B)4.6 × 10-11 M
C)1.9 × 10-3 M
D)5.4 × 10-6 M
E)0.022 M
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50
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of NO2(g).
N2O4(g)⇌ 2 NO2(g) Kc = 0.21
[N2O4]eq = 0.039 M

A)1.22 M
B)9.0 × 10-2 M
C)7.8 × 10-2 M
D)8.2 × 10-3 M
E)11 M
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51
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO3(g).
2 SO2(g)+ O2(g)⇌ 2 SO3(g)Kc = 1.7 × 108
[SO2]eq = 0.0034 M [O2]eq = 0.0018 M

A)1.9 M
B)1.0 × 103 M
C)0.53 M
D)9.6 × 10-4 M
E)0.73 M
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52
Consider the following reaction at equilibrium.What effect will adding some C have on the system?
CO2(g)+ C(graphite)⇌ 2 CO(g)

A)No effect will be observed since C is not included in the equilibrium expression.
B)The equilibrium constant will decrease.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will increase.
E)The reaction will shift to the right in the direction of products.
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53
Consider the following reaction:
NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g)
A reaction mixture initially contains 0.86 atm NO and 0.86 atm SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

A)0.78 atm
B)0.084 atm
C)0.012 atm
D)0.85 atm
E)0.048 atm
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54
Consider the following reaction and its equilibrium constant:
4 CuO(s)+ CH4(g)⇌ CO2(g)+ 4 Cu(s)+ 2 H2O(g)Kc = 1.10
A reaction mixture contains 0.22 M CH4,0.67 M CO2 and 1.3 M H2O.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of products.
B)The equilibrium constant will increase.
C)The reaction quotient will increase.
D)The reaction will shift in the direction of reactants.
E)The system is at equilibrium.
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55
Consider the following reaction:
CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)
A reaction mixture initially contains 2.9 M O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

A)1.9 M
B)1.7 M
C)2.2 M
D)1.2 M
E)0.59 M
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56
Consider the following reaction at equilibrium.What effect will adding more H2S have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the left.
B)No change will be observed.
C)The equilibrium constant will decrease.
D)The equilibrium constant will increase.
E)The reaction will shift in the direction of products.
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57
Consider the following reaction at equilibrium.What effect will adding more SO3 have on the system?
SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)

A)The reaction will shift in the direction of products.
B)The reaction will shift to decrease the pressure.
C)No change will occur since SO3 is not included in the equilibrium expression.
D)The reaction will shift in the direction of reactants.
E)The equilibrium constant will decrease.
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58
Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g).
C2H4(g)+ H2O(g)⇌ C2H5OH(g)Kc = 9.0 × 103
[C2H4]eq = 0.015 M [C2H5OH]eq = 1.69 M

A)9.9 × 10-7 M
B)80.M
C)1.0 M
D)1.68 M
E)0.013 M
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59
Consider the following reaction:
CH4(g)+ 2 H2S(g)⇌ CS2(g)+ 4 H2(g)
A reaction mixture initially contains 0.50 M CH4 and 0.75 M H2S.If the equilibrium concentration of H2 is 0.44 M,find the equilibrium constant (Kc)for the reaction.

A)0.23
B)0.038
C)2.9
D)10.
E)0.34
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60
Consider the following reaction and its equilibrium constant:
I2(g)+ Br2(g)⇌ 2 IBr(g)Kc = 1.1 × 102
A reaction mixture contains 0.41 M I2,0.27 M Br2 and 3.5 M IBr.Which of the following statements is true concerning this system?

A)The reaction will shift in the direction of products.
B)The reaction will shift in the direction of reactants.
C)The reaction quotient will decrease.
D)The equilibrium constant will increase.
E)The system is at equilibrium.
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61
Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system?
C3H8(g)+ 5 O2(g)⇌ 3 CO2(g)+ 4 H2O(l)ΔH° = -2220 kJ

A)The reaction will shift to the right in the direction of products.
B)The reaction will shift to the left in the direction of reactants.
C)The equilibrium constant will increase.
D)The equilibrium constant will decrease.
E)No effect will be observed.
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62
Why is an equilibrium constant unitless?
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63
Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system?
CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)

A)The equilibrium constant will decrease.
B)No effect will be observed.
C)The reaction will shift to the right in the direction of products.
D)The equilibrium constant will increase.
E)The reaction will shift to the left in the direction of reactants.
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64
Consider the following reaction at equilibrium.What effect will reducing the pressure of the reaction mixture have on the system?
Xe(g)+ 2 F2(g)→ XeF4(g)

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)No effect will be observed.
D)The reaction will shift to the right in the direction of products.
E)The equilibrium constant will decrease.
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65
Consider the following reaction at equilibrium.What effect will adding 1 atm of Ar to the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
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66
Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system? Xe(g)+ 2 F2(g)→ XeF4(g)

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)No effect will be observed.
D)The reaction will shift to the right in the direction of products.
E)The equilibrium constant will decrease.
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67
Consider the following reaction at equilibrium.What effect will increasing the pressure of the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
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68
Consider the following reaction at equilibrium.What effect will adding water have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
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69
Consider the following reaction at equilibrium.What effect will increasing the volume of the reaction mixture have on the system?
2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

A)The reaction will shift to the right in the direction of products.
B)No effect will be observed.
C)The reaction will shift to the left in the direction of reactants.
D)The equilibrium constant will decrease.
E)The equilibrium constant will increase.
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70
Why aren't solids or liquids included in an equilibrium expression?
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71
Match the following.
Q < K

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
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72
Match the following.
Q = K

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
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73
Match the following.
K ≈ 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
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74
Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system?
Fe3O4(s)+ CO(g)⇌ 3 FeO(s)+ CO2(g)ΔH°= +35.9 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will increase.
C)The equilibrium constant will decrease.
D)No effect will be observed.
E)The reaction will shift to the right in the direction of products.
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75
Match the following.
Q >> 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
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76
Match the following.
K << 1

A)Reaction will favor formation of reactants.
B)Reaction does not strongly favor reactants or products.
C)Reaction favors formation of more products.
D)Reaction has a larger amount of products than reactants.
E)Reaction is at equilibrium.
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77
Can the Kp and Kc for a reaction ever have the same value? Why or why not?
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78
Consider the following reaction at equilibrium.What effect will decreasing the temperature have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
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79
Explain dynamic equilibrium.Use the generic reaction A(g)⇌ B(g)to explain.
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80
Consider the following reaction at equilibrium.What effect will adding a catalyst have on the system?
CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

A)The reaction will shift to the left in the direction of reactants.
B)The equilibrium constant will decrease.
C)The equilibrium constant will increase.
D)The reaction will shift to the right in the direction of products.
E)No effect will be observed.
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Unlock for access to all 112 flashcards in this deck.
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Unlock Deck
Unlock for access to all 112 flashcards in this deck.