Deck 12: Alcohols, thiols, ethers, aldehydes, and Ketones
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Deck 12: Alcohols, thiols, ethers, aldehydes, and Ketones
1
Alcohols contain which functional group?
A)amine
B)amide
C)hydroxyl
D)thiol
A)amine
B)amide
C)hydroxyl
D)thiol
hydroxyl
2
Which of the following compounds contains an alcohol functional group?
A)
-
-O-H

B)O
-
-H
C)
-O
- 
D)O
-
-
- 
E)
-O-CH2

A)





B)O


C)




D)O




E)








3
A tertiary alcohol has a hydroxyl group bonded to a(n)________.
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon.
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon.
carbon bonded to three alkyl groups
4
A secondary alcohol has a hydroxyl group bonded to a(n)________.
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon.
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon.
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5
The compound
-SH is in the organic family known as ________.
A)ethers
B)thiols
C)alcohols
D)sulfides
E)amino acids


A)ethers
B)thiols
C)alcohols
D)sulfides
E)amino acids
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6
Which one of the following compounds is an alcohol?
A)
B)
C)
-CH
CH

D)
-O-

E)
-S-H
A)

B)

C)




D)




E)

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7
What is the common name of this compound? 
A)cyclopentyl ethyl ether
B)cyclopentyl ethyl ketone
C)1-cyclopropyl-1-ethylalcohol
D)ethylcyclopentanol
E)3-cyclopentylethanol

A)cyclopentyl ethyl ether
B)cyclopentyl ethyl ketone
C)1-cyclopropyl-1-ethylalcohol
D)ethylcyclopentanol
E)3-cyclopentylethanol
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8
The alcohol in this list that would be most soluble in water is ________.
A)ethanol
B)1-octanol
C)1-pentanol
D)1-hexanol
E)1-heptanol
A)ethanol
B)1-octanol
C)1-pentanol
D)1-hexanol
E)1-heptanol
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9
Thiols are strong-smelling compounds responsible for ________.
A)fruity odors
B)sharp odors
C)flowery odors
D)skunky or bad smelling odors
E)salty odors
A)fruity odors
B)sharp odors
C)flowery odors
D)skunky or bad smelling odors
E)salty odors
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10
Which of the following compounds is a secondary alcohol?
A)
- CH-O-

B)
-O-H
C)OH

D)
-
-CH3
H
E)
- CH - OH

A)




B)

C)OH






D)




E)



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11
The common name for the compound
- O-
is ________.
A)3-pentanol
B)ethyl propyl ether
C)3-hexanol
D)3-ether pentane
E)ethyl propyl ketone





A)3-pentanol
B)ethyl propyl ether
C)3-hexanol
D)3-ether pentane
E)ethyl propyl ketone
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12
What is the IUPAC name of this compound? OH
-
-

A)butanol
B)propanol
C)2-propanol
D)2-methylbutanol
E)2-methyl-2-propanol





A)butanol
B)propanol
C)2-propanol
D)2-methylbutanol
E)2-methyl-2-propanol
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13
Thiols have structures similar to alcohols except that they contain ________.
A)three alcohol groups
B)more than one carbon
C)sulfur in place of oxygen in the functional group
D)lithium in place of oxygen in the functional group
E)nitrogen in place of oxygen in the functional group
A)three alcohol groups
B)more than one carbon
C)sulfur in place of oxygen in the functional group
D)lithium in place of oxygen in the functional group
E)nitrogen in place of oxygen in the functional group
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14
Which of the following compounds is a weak acid?
A)ethanol
B)ethanal
C)phenol
D)hexanol
E)acetone
A)ethanol
B)ethanal
C)phenol
D)hexanol
E)acetone
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15
Which of the following compounds contains an ether functional group?
A)
-
-O-H

B)O
-
-H
C)
-O
- 
D)O
-
-
- 
E)
-O-H
A)





B)O


C)




D)O




E)

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16
The common name of
-O-
is ________.
A)dimethyl ether
B)diethyl ether
C)2-etherbutane
D)butyl ether
E)dibutyl ether




A)dimethyl ether
B)diethyl ether
C)2-etherbutane
D)butyl ether
E)dibutyl ether
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17
What kind of attractive forces do alcohols form between individual molecules?
A)oxygen bonds
B)hydrogen bonds
C)single bonds
D)carbon bonds
E)ionic bonds
A)oxygen bonds
B)hydrogen bonds
C)single bonds
D)carbon bonds
E)ionic bonds
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18
A phenol has an -OH group bonded to a(n)________.
A)singly substituted or unsubstituted carbon
B)disubstituted carbon
C)trisubstituted carbon
D)carbon.in a benzene ring
E)tetrasubstituted carbon
A)singly substituted or unsubstituted carbon
B)disubstituted carbon
C)trisubstituted carbon
D)carbon.in a benzene ring
E)tetrasubstituted carbon
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19
What is the IUPAC name for this compound? 
A)cyclopentanol
B)cyclohexanol
C)cyclobenzenol
D)phenol
E)glycerol

A)cyclopentanol
B)cyclohexanol
C)cyclobenzenol
D)phenol
E)glycerol
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20
A primary alcohol has a hydroxyl group bonded to a(n)________.
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon
A)carbon bonded to one alkyl group
B)carbon bonded to two alkyl groups
C)carbon bonded to three alkyl groups
D)aromatic carbon
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21
In all aldehydes except formaldehyde,the carbonyl group is bonded to how many hydrogen atoms?
A)one
B)two
C)three
D)four
A)one
B)two
C)three
D)four
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22
What is the IUPAC name for this compound? O
H
A)methyl aldehyde
B)1-ethanaldehyde
C)1-ethanone
D)ethanal
E)methanal


A)methyl aldehyde
B)1-ethanaldehyde
C)1-ethanone
D)ethanal
E)methanal
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23
When 2-methyl-2-butanol undergoes dehydration in acid,one product is ________.
A)2-methyl-2-butene
B)2-methylbutanone
C)2-pentanone
D)2-methylbutanal
E)hexene
A)2-methyl-2-butene
B)2-methylbutanone
C)2-pentanone
D)2-methylbutanal
E)hexene
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24
Which of the following compounds contains an aldehyde functional group?
A)
-
-O-H

B)O
-
-H
C)
-O
- 
D)O
-
-
- 
E)
- O - CH2

A)





B)O


C)




D)O




E)



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25
Formalin is ________.
A)another name for formaldehyde
B)a plastic
C)an aqueous solution of formaldehyde
D)an excellent solvent
E)a polymer
A)another name for formaldehyde
B)a plastic
C)an aqueous solution of formaldehyde
D)an excellent solvent
E)a polymer
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26
In the IUPAC naming system,an aldehyde is named by replacing the e of the name of the corresponding alkane with ________.
A)yne
B)ene
C)al
D)one
E)ol
A)yne
B)ene
C)al
D)one
E)ol
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27
In a ketone,the carbonyl group is bonded to how many hydrogen atoms?
A)none
B)one
C)two
D)three
E)four
A)none
B)one
C)two
D)three
E)four
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28
The skeletal formula represents what type of alcohol? 
A)primary
B)secondary
C)tertiary
D)quaternary
E)none

A)primary
B)secondary
C)tertiary
D)quaternary
E)none
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29
The skeletal formula represents what type of alcohol? 
A)primary
B)secondary
C)tertiary
D)quaternary
E)none

A)primary
B)secondary
C)tertiary
D)quaternary
E)none
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30
In the IUPAC naming system,a ketone is named by replacing the -e in the corresponding alkane name with ________.
A)yne
B)ene
C)al
D)one
E)ol
A)yne
B)ene
C)al
D)one
E)ol
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31
The carbonyl group consists of ________.
A)carbon-oxygen-hydrogen attached by single bonds
B)carbon and oxygen attached by a single bond
C)carbon and oxygen attached by a double bond
D)carbon and oxygen attached by a triple bond
E)a carbon-oxygen-carbon attached by single bonds
A)carbon-oxygen-hydrogen attached by single bonds
B)carbon and oxygen attached by a single bond
C)carbon and oxygen attached by a double bond
D)carbon and oxygen attached by a triple bond
E)a carbon-oxygen-carbon attached by single bonds
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32
Acetone is a ketone commonly used as a ________.
A)preservative
B)flavoring agent
C)fuel
D)solvent
E)drain cleaner
A)preservative
B)flavoring agent
C)fuel
D)solvent
E)drain cleaner
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33
What is the product when this compound undergoes gentle oxidation?
-
-
-
- OH

A)hexanal
B)2,2-dimethylbutanal
C)2,2-dimethyl-4-butanone
D)3,3-dimethyl-1-butanone
E)3,3-dimethylbutanal







A)hexanal
B)2,2-dimethylbutanal
C)2,2-dimethyl-4-butanone
D)3,3-dimethyl-1-butanone
E)3,3-dimethylbutanal
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34
Three functional groups found in this compound are ________. 
A)alcohol,aromatic,and ether
B)alcohol,aldehyde,and ether
C)alcohol,ether,and ketone
D)aldehyde,ether,and carboxylic acid
E)cycloalkene,alcohol,and carboxylic acid

A)alcohol,aromatic,and ether
B)alcohol,aldehyde,and ether
C)alcohol,ether,and ketone
D)aldehyde,ether,and carboxylic acid
E)cycloalkene,alcohol,and carboxylic acid
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35
Which of the following compounds contains a ketone functional group?
A)
-
-O-H

B)O
-
-H
C)
-O
- 
D)O
-
-
- 
E)
- O - CH2

A)





B)O


C)




D)O




E)



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36
Formaldehyde is used industrially to make ________.
A)polymers
B)insulating materials
C)carpeting
D)all of the above
E)none of the above
A)polymers
B)insulating materials
C)carpeting
D)all of the above
E)none of the above
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37
The dehydration product of
-O-H in the presence of acid is ________.
A)
C

B)cyclopropane
C)cyclopropene
D)propene
E)propyne



A)




B)cyclopropane
C)cyclopropene
D)propene
E)propyne
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38
The dehydration of an alcohol in the presence of a strong acid yields ________.
A)an alkane
B)an alkene
C)a ketone
D)an alcohol
E)an aldehyde
A)an alkane
B)an alkene
C)a ketone
D)an alcohol
E)an aldehyde
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39
The common name for butanone,a readily available solvent,is ________.
A)methyl acetone
B)ethyl methyl ketone
C)β-butanone
D)butyl ketone
E)butyl ether
A)methyl acetone
B)ethyl methyl ketone
C)β-butanone
D)butyl ketone
E)butyl ether
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40
In a tertiary alcohol,how many alkyl groups are attached to the carbon atom bonded to the -OH group?
A)none
B)one
C)two
D)three
E)four
A)none
B)one
C)two
D)three
E)four
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41
The oxygen atom in alcohols decreases water solubility of the molecule.
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42
An aldehyde forms a carboxylic acid by ________.
A)oxidation
B)reduction
C)hydrolysis
D)neutralization
E)hydrogenation
A)oxidation
B)reduction
C)hydrolysis
D)neutralization
E)hydrogenation
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43
Thiols contain the -SH group.
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44
In the dehydration of an alcohol to an alkene,what is produced in addition to the alkene?
A)water
B)hydrogen
C)oxygen
D)carbon dioxide
E)carbon monoxide
A)water
B)hydrogen
C)oxygen
D)carbon dioxide
E)carbon monoxide
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45
In the oxidation of an alcohol to a ketone,there is ________.
A)a loss of hydrogen
B)a loss of oxygen
C)a loss of carbon
D)a gain of hydrogen
E)a gain of oxygen
A)a loss of hydrogen
B)a loss of oxygen
C)a loss of carbon
D)a gain of hydrogen
E)a gain of oxygen
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46
Phenol was formerly used as an antiseptic.
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47
Alcohols,ethers,and phenols contain only carbon-oxygen only single bonds.
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48
Secondary alcohols are oxidized to ________.
A)carboxylic acids
B)ketones
C)aldehydes
D)esters
E)ethers
A)carboxylic acids
B)ketones
C)aldehydes
D)esters
E)ethers
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49
Thiols can be oxidized to ________.
A)disulfides
B)aldehydes
C)ketones
D)carboxylic acids
E)thioethers
A)disulfides
B)aldehydes
C)ketones
D)carboxylic acids
E)thioethers
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50
Ethers can only be straight chain compounds.
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51
Which of the following compounds would give a positive Tollens' test?
A)methanol
B)acetone
C)diethyl ether
D)phenol
E)butanal
A)methanol
B)acetone
C)diethyl ether
D)phenol
E)butanal
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52
Alcohols can form hydrogen bonds.
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53
Ethyl ether has been replaced by halogenated anesthetics,which have fewer side effects.
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54
What classification of alcohol undergoes oxidation to yield a ketone?
A)primary alcohol
B)both primary and secondary alcohols
C)secondary alcohol
D)all classes of alcohols
E)both secondary and tertiary alcohols
A)primary alcohol
B)both primary and secondary alcohols
C)secondary alcohol
D)all classes of alcohols
E)both secondary and tertiary alcohols
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55
When a primary alcohol is strongly oxidized,the product is ________.
A)another alcohol
B)a carboxylic acid
C)an aldehyde
D)an alkane
E)a ketone
A)another alcohol
B)a carboxylic acid
C)an aldehyde
D)an alkane
E)a ketone
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56
What classification of alcohol is resistant to oxidation?
A)primary
B)secondary
C)tertiary
D)quaternary
E)none
A)primary
B)secondary
C)tertiary
D)quaternary
E)none
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57
Tertiary alcohols are oxidized to ________.
A)secondary alcohols
B)ketones
C)aldehydes
D)carboxylic acids
E)none of the above
A)secondary alcohols
B)ketones
C)aldehydes
D)carboxylic acids
E)none of the above
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58
This is the skeletal formula for an ether. 

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59
Tertiary alcohols cannot be oxidized because ________.
A)there are no oxygen atoms to remove from the alcohol carbon
B)there are no hydrogen atoms attached to the alcohol carbon
C)the alcohol carbon is bonded to four groups so no oxygen can be added to it
D)the alcohol carbon is bonded to four groups so no hydrogen can be added to it
E)the alcohol carbon is too electronegative to have hydrogen removed from it
A)there are no oxygen atoms to remove from the alcohol carbon
B)there are no hydrogen atoms attached to the alcohol carbon
C)the alcohol carbon is bonded to four groups so no oxygen can be added to it
D)the alcohol carbon is bonded to four groups so no hydrogen can be added to it
E)the alcohol carbon is too electronegative to have hydrogen removed from it
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60
Alcohols form hydrogen bonds; this accounts for their higher solubility when compared to similar-sized alkanes.
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61
Alcohols can be dehydrated to form alkenes.
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62
The carbonyl group does not have a dipole.
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63
Alcohols with more than four carbons are insoluble in water.
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64
Acetone is a three-carbon aldehyde.
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65
This compound is an aldehyde. 

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66
Phenols behave as weak acids in water.
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67
Ketones will give a positive Tollens' test.
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68
In a ketone,the carbonyl group is bonded to two alkyl or aromatic groups.
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69
The suffix -one indicates an aldehyde in the IUPAC system of naming.
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70
This alcohol can be oxidized to a ketone. 

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71
A tertiary alcohol can be easily oxidized to a carboxylic acid.
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72
Acetone is sometimes produced in pathological conditions such as diabetes or following extreme diets.
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73
All aldehydes have a carbonyl carbon bonded to at least two hydrogens.
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74
The suffix -al indicates an aldehyde in the IUPAC system of naming.
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75
Primary alcohols can be oxidized to either aldehydes or ketones.
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76
A secondary alcohol can be easily oxidized to a carboxylic acid.
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77
Secondary alcohols can be oxidized to ketones.
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78
Formaldehyde is used in solution as a germicide and preservative.
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