Deck 11: Solutions and Their Colligative Properties
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Deck 11: Solutions and Their Colligative Properties
1
Which of the following will have the largest lattice energy?
A) NaF
B) NaCl
C) NaBr
D) NaI
E) CsCl
A) NaF
B) NaCl
C) NaBr
D) NaI
E) CsCl
NaF
2
Indicate which aqueous solution has the fastest evaporation rate.
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
0.1 M KCl
3
The vapor pressure of an aqueous solution is found to be 24.9 mm Hg at 25°C. What is the mole fraction of solute in this solution? The vapor pressure of water is 25.756 mm Hg at 25°C.
A) 0.967
B) 0.0332
C) 1.03
D) 0.0344
E) 0.976
A) 0.967
B) 0.0332
C) 1.03
D) 0.0344
E) 0.976
0.0332
4
Which of the following is needed to calculate the lattice energy of an ionic compound?
A) enthalpy of solution
B) enthalpy of combustion
C) specific heat
D) ionization energy
E) enthalpy of solvation
A) enthalpy of solution
B) enthalpy of combustion
C) specific heat
D) ionization energy
E) enthalpy of solvation
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5
Calculate the lattice energy of sodium fluoride from the following data: Ionization energy of Na: 496 kJ/mol
Electron affinity of F: -328 kJ/mol
Energy to vaporize Na: 108 kJ/mol
F2 bond energy: 160 kJ/mol
Energy change for the reaction:
Na(s) +
F2(g) NaF(s); H = -575 kJ
A) 931 kJ/mol
B) -931 kJ/mol
C) -1011 kJ/mol
D) 1011 kJ/mol
E) -851 kJ/mol
Electron affinity of F: -328 kJ/mol
Energy to vaporize Na: 108 kJ/mol
F2 bond energy: 160 kJ/mol
Energy change for the reaction:
Na(s) +

A) 931 kJ/mol
B) -931 kJ/mol
C) -1011 kJ/mol
D) 1011 kJ/mol
E) -851 kJ/mol
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6
Indicate which aqueous solution has the slowest evaporation rate.
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.1 M NaBr
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.1 M NaBr
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7
Which of the solutions shown here will have the highest vapor pressure? White circles indicate solvent molecules; black circles indicate molecules of a nonvolatile solute.
A)
B)
C)
D)
A)

B)

C)

D)

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8
Determine the energy change for the reaction Li(s) +
Cl2(g) LiCl(s)
From the following data:
Lattice energy of LiCl = -861 kJ/mol
Energy to vaporize Li = 159 kJ/mol
Ionization energy of Li = 520 kJ/mol
Cl2 bond energy: 240 kJ/mol
Electron affinity of Cl: -349 kJ/mol
A) -411 kJ/mol
B) -528 kJ/mol
C) 311 kJ/mol
D) -861 kJ/mol
E) -291 kJ/mol

From the following data:
Lattice energy of LiCl = -861 kJ/mol
Energy to vaporize Li = 159 kJ/mol
Ionization energy of Li = 520 kJ/mol
Cl2 bond energy: 240 kJ/mol
Electron affinity of Cl: -349 kJ/mol
A) -411 kJ/mol
B) -528 kJ/mol
C) 311 kJ/mol
D) -861 kJ/mol
E) -291 kJ/mol
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9
At 25°C, the vapor pressure of pure water is 25.756 mm Hg. What is the vapor pressure of water in a 0.500 m solution of sodium chloride?
A) 25.52 mm Hg
B) 0.2301 mm Hg
C) 0.4602 mm Hg
D) 25.35 mm Hg
E) 12.88 mm Hg
A) 25.52 mm Hg
B) 0.2301 mm Hg
C) 0.4602 mm Hg
D) 25.35 mm Hg
E) 12.88 mm Hg
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10
Which listing of ionic compounds is in order of increasing melting point?
A) NaF < MgF2 < AlF3
B) MgF2 < NaF < AlF3
C) AlF3 < MgF2 < NaF
D) AlF3 < NaF < MgF2
E) NaF < AlF3 < MgF2
A) NaF < MgF2 < AlF3
B) MgF2 < NaF < AlF3
C) AlF3 < MgF2 < NaF
D) AlF3 < NaF < MgF2
E) NaF < AlF3 < MgF2
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11
Which of the solutions shown here will have the lowest vapor pressure? White circles indicate solvent molecules; black circles indicate molecules of a nonvolatile solute.
A)
B)
C)
D)
A)

B)

C)

D)

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12
Which of the following is not typically needed to calculate the lattice energy of an ionic compound?
A) enthalpy of vaporization
B) bond enthalpy
C) enthalpy of solution
D) electron affinity
E) ionization energy
A) enthalpy of vaporization
B) bond enthalpy
C) enthalpy of solution
D) electron affinity
E) ionization energy
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13
Indicate which aqueous solution has the lowest vapor pressure.
A) 0.1 M KCl
B) 0.1 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
A) 0.1 M KCl
B) 0.1 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
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14
Indicate which aqueous solution has the highest vapor pressure.
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
A) 0.1 M KCl
B) 0.2 M Na2CO3
C) 0.2 M NaCl
D) 0.1 M MgCl2
E) 0.2 M MgCl2
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15
Which of the following compounds has the largest melting point?
A) NaF
B) KCl
C) RbCl
D) BeF2
E) NaCl
A) NaF
B) KCl
C) RbCl
D) BeF2
E) NaCl
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16
Which of the following requires the smallest energy to separate the ions?
A) CaF2
B) KF
C) NaF
D) MgF2
E) LiF
A) CaF2
B) KF
C) NaF
D) MgF2
E) LiF
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17
Which of the following ranks the compounds from lowest to highest lattice energy?
A) NaF < MgF2 < CaF2 < KF
B) KF < NaF < CaF2 < MgF2
C) MgF2 < CaF2 < NaF < KF
D) CaF2 < KF < NaF < MgF2
E) MgF2 < CaF2 < KF < NaF
A) NaF < MgF2 < CaF2 < KF
B) KF < NaF < CaF2 < MgF2
C) MgF2 < CaF2 < NaF < KF
D) CaF2 < KF < NaF < MgF2
E) MgF2 < CaF2 < KF < NaF
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18
Coulomb's law states that the interaction energy between ions depends __________
A) only on the ionic charges.
B) only on the distance between the ions.
C) directly on both the ionic charges and the distance between the ions.
D) on the temperature.
E) directly on the ionic charges and inversely on the distance between the ions.
A) only on the ionic charges.
B) only on the distance between the ions.
C) directly on both the ionic charges and the distance between the ions.
D) on the temperature.
E) directly on the ionic charges and inversely on the distance between the ions.
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19
What is the vapor pressure of an aqueous solution that has a solute mol fraction of = 0.100? The vapor pressure of water is 25.756 mm Hg at 25°C.
A) 23.2 mm Hg
B) 2.58 mm Hg
C) 25.8 mm Hg
D) 0.900 mm Hg
E) 22.3 mm Hg
A) 23.2 mm Hg
B) 2.58 mm Hg
C) 25.8 mm Hg
D) 0.900 mm Hg
E) 22.3 mm Hg
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20
Which of the following will require the greatest energy input to separate the ions?
A) MgI2
B) MgF2
C) MgCl2
D) MgBr2
E) NaCl
A) MgI2
B) MgF2
C) MgCl2
D) MgBr2
E) NaCl
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21
Click, Clack, and Jim have identical icy driveways. Click buys 10 lb of NaCl, Clack buys 10 lb of CaCl2, and Jim buys 10 lb of MgCl2. They spread these salts on their driveways. Which driveway will deice more effectively? (Assume that ideal dissociation of the salts occurs, and that colligative properties are the only consideration.)
A) Click's driveway will deice best.
B) Clack's driveway will deice best.
C) Jim's driveway will deice best.
D) The three driveways will deice to the same extent.
E) Clack and Jim's driveways will deice better than Click's.
A) Click's driveway will deice best.
B) Clack's driveway will deice best.
C) Jim's driveway will deice best.
D) The three driveways will deice to the same extent.
E) Clack and Jim's driveways will deice better than Click's.
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22
Which statement regarding osmotic pressure is not correct? Osmotic pressure __________
A) increases with increasing temperature.
B) increases with increasing molar concentration of solute.
C) is greater for 0.1 M Na2SO4 than for 0.1 M NaCl.
D) depends on the value of the gas constant R.
E) is the same for solutions with the same mass percent of solute.
A) increases with increasing temperature.
B) increases with increasing molar concentration of solute.
C) is greater for 0.1 M Na2SO4 than for 0.1 M NaCl.
D) depends on the value of the gas constant R.
E) is the same for solutions with the same mass percent of solute.
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23
Determine the molal concentration of a sugar solution in water that has a freezing point of -2.1°C. Kf = 1.86°C/m for water.
A) 1.13 m
B) -1.13 m
C) 3.91 m
D) -3.91 m
E) 0.113 m
A) 1.13 m
B) -1.13 m
C) 3.91 m
D) -3.91 m
E) 0.113 m
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24
Which solution, if either, would create the higher osmotic pressure (compared to pure water): one prepared from 1.0 g of NaCl in 10 mL of water or 1.0 g of CsBr in 10 mL of water?
A) They would have the same osmotic pressures.
B) NaCl would give the higher pressure.
C) CsBr would give the higher pressure.
D) It is impossible to tell.
E) These compounds are salts and do not produce an osmotic pressure.
A) They would have the same osmotic pressures.
B) NaCl would give the higher pressure.
C) CsBr would give the higher pressure.
D) It is impossible to tell.
E) These compounds are salts and do not produce an osmotic pressure.
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25
Which solution will have the lowest osmotic pressure when measured against pure water?
A) 0.10 M sodium chloride
B) 0.10 M sodium sulfate
C) 0.10 M sodium sulfide
D) 0.10 M sodium phosphate
E) 0.10 M sodium carbonate
A) 0.10 M sodium chloride
B) 0.10 M sodium sulfate
C) 0.10 M sodium sulfide
D) 0.10 M sodium phosphate
E) 0.10 M sodium carbonate
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26
What would be the freezing point of a 1 m solution of HCl in water (Kf = 1.86°C)?
A) 0.0°C
B) -1.86°C
C) -3.72°C
D) 1.86°C
E) -0.93°C
A) 0.0°C
B) -1.86°C
C) -3.72°C
D) 1.86°C
E) -0.93°C
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27
A solution is made by dissolving 100 g of essentially nonvolatile ethylene glycol (C2H6O2) in 500 g of water. What is the resulting freezing point of the solution (Kf = 1.86°C/m)?
A) -5.99°C
B) -1.86°C
C) -0.372°C
D) -1.61°C
E) -3.23°C
A) -5.99°C
B) -1.86°C
C) -0.372°C
D) -1.61°C
E) -3.23°C
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28
Which of the following would be most effective in melting ice on a sidewalk?
A) 1 kg NaCl
B) 1 kg KCl
C) 1 kg MgCl2
D) 1 kg CuCl
E) 1 kg CaCl2
A) 1 kg NaCl
B) 1 kg KCl
C) 1 kg MgCl2
D) 1 kg CuCl
E) 1 kg CaCl2
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29
You like boiled eggs for breakfast, but they take too long to cook, and you are always late to your early morning class. Lucky you! You have learned that adding table salt, NaCl (58.4 g/mol, 2.16 g/cm3), to water (Kb = 0.52oC/m) increases the temperature at which it boils. You figure that you can cook eggs faster at a higher temperature in boiling salty water! What increase in the boiling point do you expect if you add 1 tablespoon (1 tbsp = 14.8 cm3) of salt to one 8-oz cup of water (237 mL)?
A) 1.0°C
B) 2.4°C
C) 28°C
D) 1.5°C
E) 3.7°C
A) 1.0°C
B) 2.4°C
C) 28°C
D) 1.5°C
E) 3.7°C
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30
Isopropyl alcohol has a boiling point of 82.3°C. Solutions of isopropyl alcohol in water have normal boiling points less than 100°C. Is this observation consistent with the following equation? Explain. Tb = iKbm
A) No, boiling point elevation only pertains to ionic solutes.
B) No, boiling point elevation only pertains to nonvolatile solutes.
C) Yes, boiling point depression occurs for all solutions.
D) Yes, the boiling point depression constant for isopropyl alcohol is large.
E) No, isopropyl alcohol can hydrogen bond with water.
A) No, boiling point elevation only pertains to ionic solutes.
B) No, boiling point elevation only pertains to nonvolatile solutes.
C) Yes, boiling point depression occurs for all solutions.
D) Yes, the boiling point depression constant for isopropyl alcohol is large.
E) No, isopropyl alcohol can hydrogen bond with water.
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31
You like boiled eggs for breakfast, but they take too long to cook, and you are always late to your early morning class. Lucky you! You have learned that adding table salt, NaCl (58.4 g/mol, 2.16 g/cm3), to water (Kb = 0.52oC/m) increases the temperature at which it boils. You figure that you can cook eggs faster at a higher temperature in boiling salty water! What increase in the boiling point do you expect if you add 4 tablespoons (1 tbsp = 14.8 cm3) of salt to 16 oz of water (474 mL)?
A) 14°C
B) 4.8°C
C) 28°C
D) 3.0°C
E) 8.4°C
A) 14°C
B) 4.8°C
C) 28°C
D) 3.0°C
E) 8.4°C
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32
A newspaper article suggested using a fertilizer such as ammonium sulfate or ammonium nitrate to lower the melting point of ice on sidewalks because many of the deicing salts can damage lawns and sidewalks. Which of the following compounds would give the largest freezing point depression when 100 g of the compound are dissolved in 1 kg of solvent?
A) NH4NO3 (80.1 g/mol)
B) (NH4)2SO4 (132.1 g/mol)
C) MgSO4 (120.4 g/mol)
D) CaCl2 (111.0 g/mol)
E) MgCl2 (95.2 g/mol)
A) NH4NO3 (80.1 g/mol)
B) (NH4)2SO4 (132.1 g/mol)
C) MgSO4 (120.4 g/mol)
D) CaCl2 (111.0 g/mol)
E) MgCl2 (95.2 g/mol)
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33
Which of the following would not be effective in melting ice on a sidewalk?
A) NaCl
B) KCl
C) MgCl2
D) CuCl
E) CaCl2
A) NaCl
B) KCl
C) MgCl2
D) CuCl
E) CaCl2
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34
The normal temperature range of the liquid phase of pure water is 0°C to 100°C. Which of the following solutions will have the largest temperature range for the liquid state?
A) 1 M aqueous ethanol solution
B) 1 M aqueous potassium bromide solution
C) 1 M aqueous acetic acid solution
D) 1 M aqueous magnesium bromide solution
E) 1 M aqueous magnesium sulfate
A) 1 M aqueous ethanol solution
B) 1 M aqueous potassium bromide solution
C) 1 M aqueous acetic acid solution
D) 1 M aqueous magnesium bromide solution
E) 1 M aqueous magnesium sulfate
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35
Which statement is not correct? Determination of molar mass of an unknown sample by an osmotic pressure measurement requires that __________
A) the solute dissolved in the solution is pure.
B) the solute is a nonelectrolyte.
C) the molecules of the solute do not pass through the semipermeable membrane.
D) the mass of the solute dissolved in the solution is known in advance.
E) the molar concentration of the solute in the solution is known in advance.
A) the solute dissolved in the solution is pure.
B) the solute is a nonelectrolyte.
C) the molecules of the solute do not pass through the semipermeable membrane.
D) the mass of the solute dissolved in the solution is known in advance.
E) the molar concentration of the solute in the solution is known in advance.
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36
In the process of dialysis, a special semipermeable membrane allows both small molecules and water to pass through, but not large protein molecules. These membranes are used to separate these small molecules and ions from much larger proteins. If a mixture of proteins and small molecules were separated from pure water by a dialysis membrane as shown in the figure, which way would the molecules flow? 
A) Both water and small molecules would pass through into the pure water.
B) Only the proteins would pass through into the pure water.
C) Water would enter the solution while small molecules would pass through into the pure water.
D) Only small molecules would pass through the membrane, water and proteins would not.
E) Only water would pass through the membrane into the solution.

A) Both water and small molecules would pass through into the pure water.
B) Only the proteins would pass through into the pure water.
C) Water would enter the solution while small molecules would pass through into the pure water.
D) Only small molecules would pass through the membrane, water and proteins would not.
E) Only water would pass through the membrane into the solution.
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37
Calculate the minimum pressure that must be applied to achieve reverse osmosis of 0.504 M NaCl at 22C.
A) 0.906 atm
B) 92.2 atm
C) 0.909 atm
D) 12.2 atm
E) 24.4 atm
A) 0.906 atm
B) 92.2 atm
C) 0.909 atm
D) 12.2 atm
E) 24.4 atm
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38
What is the molality of a solution produced by dissolving 14.40 g of LiCl (42.39 g/mol) in water to make 0.104 L of solution with a density of 1.102 g/mL?
A) 0.340 m
B) 3.39 m
C) 3.27 m
D) 3.74 m
E) 2.96 m
A) 0.340 m
B) 3.39 m
C) 3.27 m
D) 3.74 m
E) 2.96 m
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39
The concentration unit of molality is symbolized as
A) M
B) m
C) "M"
D) mol
E) mo
A) M
B) m
C) "M"
D) mol
E) mo
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40
You are working as an intern in a biochemistry lab. Your advisor just isolated an enzyme and asks you to determine its molar mass using osmosis. You dissolve 1.0 g of the enzyme in water to make 250 mL of solution. You measure the osmotic pressure, and find it to be 3.5 torr at 298 K. You report that the molar mass is __________ g/mol.
A) between 0 and 1000
B) between 1000 and 5000
C) between 5000 and 10,000
D) between 10,000 and 20,000
E) between 20,000 and 50,000
A) between 0 and 1000
B) between 1000 and 5000
C) between 5000 and 10,000
D) between 10,000 and 20,000
E) between 20,000 and 50,000
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41
A saline solution is administered intravenously to patients who cannot take fluid orally and are in danger of dehydration. The osmotic pressure of this solution must match that of blood to prevent hemolysis or crenation of blood cells. What mass of sodium chloride (58.44 g/mol) is needed to produce 100.0 mL of saline solution with an osmotic pressure of 7.83 atm at a body temperature of 37°C?
A) 0.899 g
B) 8.99 g
C) 18.0 g
D) 1.80 g
E) 0.450 g
A) 0.899 g
B) 8.99 g
C) 18.0 g
D) 1.80 g
E) 0.450 g
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42
Gasoline is primarily a mixture of hydrocarbons and is sold with an octane rating that is based on a comparison with the combustion properties of isooctane. Gasoline usually contains an isomer of isooctane called tetramethylbutane (C8H18), which has an enthalpy of vaporization of 43.3 kJ/mol and a boiling point of 106.5°C. Determine the vapor pressure of tetramethylbutane on a very hot summer day when the temperature is 38°C.
A) 80.0 torr
B) 36.7 torr
C) 67.8 torr
D) 47.9 torr
E) 89.3 torr
A) 80.0 torr
B) 36.7 torr
C) 67.8 torr
D) 47.9 torr
E) 89.3 torr
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43
A solution contains 6.50 mol water, 0.300 mol sucrose, and 0.200 mol glucose. The solutes are nonvolatile. What is the vapor pressure of the solution at 35°C given that the vapor pressure of water is 42.2 torr?
A) 35.0 torr
B) 36.0 torr
C) 37.0 torr
D) 39.2 torr
E) 39.0 torr
A) 35.0 torr
B) 36.0 torr
C) 37.0 torr
D) 39.2 torr
E) 39.0 torr
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44
Calculate the molality of a solution containing 0.355 mol sodium hydrogen carbonate (baking soda) and 245 g of water.
A) 1.45 m
B) 1.12 10-2 m
C) 2.11 m
D) 1.12 10-3 m
E) 0.0211 m
A) 1.45 m
B) 1.12 10-2 m
C) 2.11 m
D) 1.12 10-3 m
E) 0.0211 m
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45
Portable lanterns and stoves used for camping often use a mixture of hydrocarbons for fuel. One such hydrocarbon is an alkane called n-pentane. These lanterns and stoves are often difficult to light on a cold day because the fuel has a low vapor pressure at low temperatures. Determine the vapor pressure of n-pentane on a night when the temperature is 0.0oC. The enthalpy of vaporization of n-pentane is 27.6 kJ/mol, and its boiling point is 36.0°C.
A) 228 torr
B) 367 torr
C) 184 torr
D) 479 torr
E) 209 torr
A) 228 torr
B) 367 torr
C) 184 torr
D) 479 torr
E) 209 torr
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46
A solution is prepared by adding 0.300 mol glucose, which is not volatile, to 4.50 mol water. What is the vapor pressure of this solution at 25°C given that the vapor pressure of pure water is 23.8 torr?
A) 9.38 torr
B) 22.3 torr
C) 23.4 torr
D) 1.49 torr
E) 22.5 torr
A) 9.38 torr
B) 22.3 torr
C) 23.4 torr
D) 1.49 torr
E) 22.5 torr
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47
Which statement below regarding vapor pressure is not correct?
A) Vapor pressure is an intensive property.
B) The substance with the stronger intermolecular forces has the lower vapor pressure.
C) Vapor pressure increases with increasing temperature.
D) Pure water has a higher vapor pressure at a given temperature than seawater.
E) A nonvolatile solute increases the vapor pressure of the solvent.
A) Vapor pressure is an intensive property.
B) The substance with the stronger intermolecular forces has the lower vapor pressure.
C) Vapor pressure increases with increasing temperature.
D) Pure water has a higher vapor pressure at a given temperature than seawater.
E) A nonvolatile solute increases the vapor pressure of the solvent.
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48
What physical property is used to separate the hydrocarbon components in petroleum (crude oil)?
A) melting point
B) density
C) boiling point
D) molar mass
E) viscosity
A) melting point
B) density
C) boiling point
D) molar mass
E) viscosity
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49
Gasoline is primarily a mixture of hydrocarbons and is sold with an octane rating that is based on a comparison with the properties of isooctane (C8H18), which has an enthalpy of vaporization of 35.8 kJ/mol and a boiling point of 98.2°C. Determine the vapor pressure of isooctane on a very hot summer day when the temperature is 38°C.
A) 80.0 torr
B) 36.7 torr
C) 67.8 torr
D) 47.9 torr
E) 89.3 torr
A) 80.0 torr
B) 36.7 torr
C) 67.8 torr
D) 47.9 torr
E) 89.3 torr
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50
Which one of the ionic compounds below would you expect to have the largest (most negative) lattice energy?
A) MgO
B) CaO
C) SrO
D) BaO
E) BeO
A) MgO
B) CaO
C) SrO
D) BaO
E) BeO
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51
Which one of the ionic compounds below would you expect to have the smallest (least negative) lattice energy?
A) MgF2
B) MgCl2
C) MgBr2
D) MgI2
E) CaI2
A) MgF2
B) MgCl2
C) MgBr2
D) MgI2
E) CaI2
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52
Ethylene glycol is used in automobile radiators as an antifreeze. What will the freezing point of an antifreeze solution be if 2.5 L of ethylene glycol are mixed together with 2.5 L of water? The following information may be helpful to you. Ethylene glycol has a very low vapor pressure and is essentially nonvolatile. molar mass of ethylene glycol = 62.1 g/mol
Van't Hoff factor = 1
Density of ethylene glycol = 1.11 g/mL
Density of water = 1.00 g/mL
Kf for water = 1.86°C kg/mol
A) -39°C
B) -16°C
C) -1.6°C
D) -33°C
E) -24°C
Van't Hoff factor = 1
Density of ethylene glycol = 1.11 g/mL
Density of water = 1.00 g/mL
Kf for water = 1.86°C kg/mol
A) -39°C
B) -16°C
C) -1.6°C
D) -33°C
E) -24°C
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53
Which one of the ionic compounds below would you expect to have the largest (most negative) lattice energy?
A) MgF2
B) MgCl2
C) MgBr2
D) MgI2
E) CaI2
A) MgF2
B) MgCl2
C) MgBr2
D) MgI2
E) CaI2
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54
Which of the following aqueous solutions will have the lowest freezing point?
A) 0.1 m magnesium sulfate, MgSO4
B) 0.1 m potassium chloride, KCl
C) 0.08 m magnesium chloride, MgCl2
D) 0.04 m sodium sulfate, Na2SO4
E) 0.05 m sodium chloride, NaCl
A) 0.1 m magnesium sulfate, MgSO4
B) 0.1 m potassium chloride, KCl
C) 0.08 m magnesium chloride, MgCl2
D) 0.04 m sodium sulfate, Na2SO4
E) 0.05 m sodium chloride, NaCl
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55
The aroma from almonds and cherries is due in part to a compound called benzaldehyde. A graph of the natural logarithm of the vapor pressure of benzaldehyde vs. 1/temperature produces a straight line with a slope of -5870.99 K. What is the enthalpy of vaporization of benzaldehyde?
A) +473 kJ/mol
B) -47.3 kJ/mol
C) +47.3 kJ/mol
D) -48.8 kJ/mol
E) +48.8 kJ/mol
A) +473 kJ/mol
B) -47.3 kJ/mol
C) +47.3 kJ/mol
D) -48.8 kJ/mol
E) +48.8 kJ/mol
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56
The smell of fresh-cut pine is due in part to a cyclic alkene called pinene. A graph of the natural logarithm of the vapor pressure of pinene vs. 1/temperature produces a straight line with a slope of -4936.37 K. What is the enthalpy of vaporization of pinene?
A) +397 kJ/mol
B) -39.7 kJ/mol
C) +39.7 kJ/mol
D) -41.0 kJ/mol
E) +41.0 kJ/mol
A) +397 kJ/mol
B) -39.7 kJ/mol
C) +39.7 kJ/mol
D) -41.0 kJ/mol
E) +41.0 kJ/mol
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57
Which statement regarding the fractional distillation of two substances is not correct?
A) The substance with the lower boiling point has a higher concentration in the vapor than in the liquid.
B) The boiling point of the mixture is not constant, changing as the distillation progresses.
C) The substance with the higher vapor pressure has a higher concentration in the vapor than in the liquid.
D) The mole ratio of the two substances in the vapor is not the same as it is in the liquid.
E) Raoult's law does not apply to mixtures of volatile components.
A) The substance with the lower boiling point has a higher concentration in the vapor than in the liquid.
B) The boiling point of the mixture is not constant, changing as the distillation progresses.
C) The substance with the higher vapor pressure has a higher concentration in the vapor than in the liquid.
D) The mole ratio of the two substances in the vapor is not the same as it is in the liquid.
E) Raoult's law does not apply to mixtures of volatile components.
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58
A solution is prepared by adding 1.50 mol glucose, which is not volatile, to 3.50 mol water. What is the vapor pressure of this solution at 25°C given that the vapor pressure of pure water is 23.8 torr?
A) 7.00 torr
B) 16.7 torr
C) 10.2 torr
D) 7.14 torr
E) 34.0 torr
A) 7.00 torr
B) 16.7 torr
C) 10.2 torr
D) 7.14 torr
E) 34.0 torr
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59
Which one of the ionic compounds below would you expect to have the smallest (least negative) lattice energy?
A) MgO
B) CaO
C) SrO
D) BaO
E) BeO
A) MgO
B) CaO
C) SrO
D) BaO
E) BeO
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60
Calculate the molality of a solution containing 0.755 mol glucose and 1.75 kg of water.
A) 0.875 m
B) 0.583 m
C) 0.431 m
D) 580 m
E) 0.850 m
A) 0.875 m
B) 0.583 m
C) 0.431 m
D) 580 m
E) 0.850 m
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61
A 376 mg sample of a nonelectrolyte compound isolated from throat lozenges was dissolved in water to produce 10.0 mL of a solution at 25°C. The osmotic pressure of this solution was measured and found to be 4.89 atm. What is the molar mass of this compound?
A) 489 g/mol
B) 941 g/mol
C) 48.9 g/mol
D) 199 g/mol
E) 188 g/mol
A) 489 g/mol
B) 941 g/mol
C) 48.9 g/mol
D) 199 g/mol
E) 188 g/mol
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62
Identify the following statement as true or false and choose the correct explanation. "For solutions with the same molarity at the same temperature, the pressure needed for reverse osmosis of a sodium chloride solution will always be less than the pressure needed for a calcium chloride solution."
A) True, because the molar mass of sodium chloride is smaller.
B) True, because the van't Hoff factor is smaller for sodium chloride.
C) False, because the van't Hoff factor is smaller for sodium chloride.
D) False, because the van't Hoff factor is larger for sodium chloride.
E) True, because the van't Hoff factor is larger for sodium chloride.
A) True, because the molar mass of sodium chloride is smaller.
B) True, because the van't Hoff factor is smaller for sodium chloride.
C) False, because the van't Hoff factor is smaller for sodium chloride.
D) False, because the van't Hoff factor is larger for sodium chloride.
E) True, because the van't Hoff factor is larger for sodium chloride.
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63
Eugenol is one of the compounds responsible for the flavor of cloves. A 222-mg sample of eugenol was dissolved in 1.00 g of chloroform (Kb = 3.63°C/m), increasing the boiling point of chloroform by 3.68°C. What is the molar mass of eugenol?
A) 82.0 g/mol
B) 125 g/mol
C) 164 g/mol
D) 193 g/mol
E) 219 g/mol
A) 82.0 g/mol
B) 125 g/mol
C) 164 g/mol
D) 193 g/mol
E) 219 g/mol
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64
Identify the following statement as true or false and choose the correct explanation. "For solutions with the same reverse osmotic pressure at the same temperature, the molarity of a sodium chloride solution will always be less than the molarity of a calcium chloride solution."
A) True, because the molar mass of sodium chloride is smaller.
B) True, because the van't Hoff factor is smaller for sodium chloride.
C) False, because the van't Hoff factor is smaller for sodium chloride.
D) False, because the van't Hoff factor is larger for sodium chloride.
E) True, because the van't Hoff factor is larger for sodium chloride.
A) True, because the molar mass of sodium chloride is smaller.
B) True, because the van't Hoff factor is smaller for sodium chloride.
C) False, because the van't Hoff factor is smaller for sodium chloride.
D) False, because the van't Hoff factor is larger for sodium chloride.
E) True, because the van't Hoff factor is larger for sodium chloride.
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65
What mass of a 0.66 m ammonium nitrate (80.04 g/mol) solution will contain 0.15 mol of solute?
A) 227 g
B) 239 g
C) 440 g
D) 493 g
E) 4453 g
A) 227 g
B) 239 g
C) 440 g
D) 493 g
E) 4453 g
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66
The arrow in the diagram below indicates the direction of solvent flow through a membrane in osmosis. Which solution, A or B, is more concentrated? Explain your reasoning. 

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67
A 15.0 mg sample of a protein was dissolved in water to produce 5.00 mL of solution at 25.1°C. The osmotic pressure of this solution was measured and found to be 6.50 torr. What is the molar mass of this protein?
A) 427 g/mol
B) 941 g/mol
C) 8580 g/mol
D) 4270 g/mol
E) 561 g/mol
A) 427 g/mol
B) 941 g/mol
C) 8580 g/mol
D) 4270 g/mol
E) 561 g/mol
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68
How many moles of solute are there in a 0.155 m glucose solution prepared with 50.0 kg of water?
A) 15.5 mol
B) 15.0 mol
C) 0.155 mol
D) 31.0 mol
E) 7.75 mol
A) 15.5 mol
B) 15.0 mol
C) 0.155 mol
D) 31.0 mol
E) 7.75 mol
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69
Does the temperature of the vapors in a still head increase or decrease as a fractional distillation progresses? Explain.
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70
What is the molarity of a sucrose (C12H22O11) solution that produces an osmotic pressure of 2.65 atm at 25°C?
A) 0.0349 M
B) 0.127 M
C) 0.0127 M
D) 0.108 M
E) 0.398 M
A) 0.0349 M
B) 0.127 M
C) 0.0127 M
D) 0.108 M
E) 0.398 M
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71
A physiological saline solution is 0.92% NaCl by mass. What is the osmotic pressure of such a solution at a body temperature of 37°C?
A) 8.0 atm
B) 3.9 atm
C) 2.3 atm
D) 4.3 atm
E) 4.1 atm
A) 8.0 atm
B) 3.9 atm
C) 2.3 atm
D) 4.3 atm
E) 4.1 atm
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72
A 300-mg sample of caffeine was dissolved in 10.0 g of camphor (Kf = 39.7°C/m), decreasing the freezing point of camphor by 3.07°C. What is the molar mass of caffeine?
A) 47.0 g/mol
B) 194 g/mol
C) 388 g/mol
D) 94.0 g/mol
E) 97.0 g/mol
A) 47.0 g/mol
B) 194 g/mol
C) 388 g/mol
D) 94.0 g/mol
E) 97.0 g/mol
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73
Which has the higher vapor pressure at a given temperature, pure water or salty seawater? Explain.
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74
A mixture of salt and ice is used to chill the contents of old-fashioned, hand-operated ice cream makers. What is the melting point of a mixture of 1.00 lb of sodium chloride and 16.00 lb of ice if exactly half the ice melts? Assume ideal behavior and that all the sodium chloride dissolves in the melted ice water. Kf(water) = 1.86°C/m
A) -8°C
B) -11°C
C) -12°C
D) -21°C
E) -15°C
A) -8°C
B) -11°C
C) -12°C
D) -21°C
E) -15°C
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75
A solution of 5.00 g of sodium chloride in 1.00 kg of water has a freezing point of -0.299°C. What is the actual van't Hoff factor for this salt at this concentration compared to the ideal one of 2? Kf(water) = 1.86°C/m
A) 1.88
B) 1.98
C) 1.93
D) 1.83
E) 1.94
A) 1.88
B) 1.98
C) 1.93
D) 1.83
E) 1.94
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76
The term colligative refers to properties that __________
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77
The freezing point of a 0.0925 m solution of ammonium chloride was found to be -0.325°C. What is the actual van't Hoff factor for this salt at this concentration compared to the ideal one of 2? Kf(water) = 1.86°C/m
A) 1.89
B) 1.95
C) 1.90
D) 1.80
E) 1.97
A) 1.89
B) 1.95
C) 1.90
D) 1.80
E) 1.97
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78
Magnesium chloride is often used to melt ice on sidewalks. Considering that the solubility of magnesium chloride (95.21 g/mol) in water is 54.3 g per 100.0 g of water, what is the lowest temperature that you would expect to be able to melt ice with magnesium chloride? Assume ideal behavior. Kf(water) = 1.86°C/m
A) -40°C
B) -32°C
C) -11°C
D) -25°C
E) -22°C
A) -40°C
B) -32°C
C) -11°C
D) -25°C
E) -22°C
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79
Rank the following ionic compounds in order of increasing lattice energy (largest lattice energy is the most negative): MgF2, MgCl2, MgBr2, and MgI2.
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80
Define the terms enthalpy of solution, enthalpy of hydration, and lattice energy.
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