Exam 16: Aqueous Ionic Equilibrium

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Calculate the percent ionization of nitrous acid in a solution that is 0.249 mol L-1 in nitrous acid. The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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C

In which of the following solutions would solid PbBr2 be expected to be the least soluble at 25 °C?

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The molar solubility of CuI is 2.26 × 10-6 mol L-1 in pure water. Calculate the Ksp for CuI.

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A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 100.0 mL of NaOH.

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What is the pH of a solution made by mixing 10.00 mL of 0.10 mol L-1 acetic acid with 10.00 mL of 0.10 mol L-1 KOH? Assume that the volumes of the solutions are additive. Ka = 1.8 × 10-5 for CH3COOH.

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Calculate the pH of a buffer that is 0.225 mol L-1 CH3COOH and 0.162 mol L-1 CH3COOK. The Ka for CH3COOH is 1.8 × 10-5.

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A 1.0 L buffer solution is 0.250 mol L-1 CH3COOH and 0.050 mol L-1 CH3COOLi. Which of the following actions will exceed the capacity of the buffer?

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Identify the expression for the solubility product constant for Cr2(CO3)3.

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Identify the expression for the solubility product constant for BaF2.

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Give the name of the compound that is in antifreeze and is toxic to pets.

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Which of the following compounds will have the highest molar solubility in pure water?

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Identify the salts that are in hard water.

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A 1.0 L buffer solution is 0.050 mol L-1 CH3COOH and 0.250 mol L-1 CH3COOLi. Which of the following actions will destroy the buffer?

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Identify a good buffer.

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Calculate the pH of a buffer that is 0.058 mol L-1 HF and 0.058 mol L-1 LiF. The Ka for HF is 3.5 × 10-4.

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A sample contains Ba3(PO4)2, CdS, AgCl, NH4Cl, and ZnS. Identify the precipitate formed upon the addition of 6 mol L-1 HCl.

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A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 66.67 mL of NaOH (this is the equivalence point).

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Determine the molar solubility of PbSO4 in pure water. Ksp (PbSO4)= 1.82 × 10-8.

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Determine the molar solubility of Fe(OH)2 in pure water. Ksp for Fe(OH)2 = 4.87 × 10-17.

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A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in LiF. Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH. Assume no volume change upon the addition of the base. The Ka for HF is 3.5 × 10-4.

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