Deck 16: Aqueous Ionic Equilibrium
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Deck 16: Aqueous Ionic Equilibrium
1
Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 mol L-1 NH4Cl with 200.0 mL of 0.12 mol L-1 NH3. The Kb for NH3 is 1.8 × 10-5.
A) 9.06
B) 9.45
C) 4.55
D) 4.74
E) 9.26
A) 9.06
B) 9.45
C) 4.55
D) 4.74
E) 9.26
9.06
2
Calculate the pH of a solution formed by mixing 200.0 mL of 0.30 mol L-1 HClO with 100.0 mL of 0.20 mol L-1 KClO. The Ka for HClO is 2.9 × 10-8.
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
7.06
3
If the pKa of HCOOH is 3.74 and the pH of an HCOOH/HCOONa buffer solution is 3.74, which of the following is TRUE?
A) [HCOOH] > [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] < [HCOONa]
D) [HCOOH] << [HCOONa]
E) [HCOOH] >> [HCOONa]
A) [HCOOH] > [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] < [HCOONa]
D) [HCOOH] << [HCOONa]
E) [HCOOH] >> [HCOONa]
[HCOOH] = [HCOONa]
4
Calculate the pH of a buffer that is 0.058 mol L-1 HF and 0.058 mol L-1 LiF. The Ka for HF is 3.5 × 10-4.
A) 2.86
B) 9.31
C) 10.54
D) 3.46
E) 4.69
A) 2.86
B) 9.31
C) 10.54
D) 3.46
E) 4.69
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5
Calculate the pH of a buffer that is 0.105 mol L-1 CH3COOH and 0.146 mol L-1 CH3COOK. The Ka for CH3COOH is 1.8 × 10-5.
A) 4.89
B) 9.11
C) 4.74
D) 9.26
E) 4.60
A) 4.89
B) 9.11
C) 4.74
D) 9.26
E) 4.60
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6
Calculate the pH of a solution formed by mixing 100.0 mL of 0.20 mol L-1 HClO with 200.0 mL of 0.30 mol L-1 KClO. The Ka for HClO is 2.9 × 10-8.
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
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7
Calculate the pH of a buffer that is 0.040 mol L-1 HF and 0.020 mol L-1 LiF. The Ka for HF is 3.5 × 10-4.
A) 2.06
B) 4.86
C) 3.15
D) 3.46
E) 3.76
A) 2.06
B) 4.86
C) 3.15
D) 3.46
E) 3.76
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8
Which one of the following statements is TRUE?
A) A buffer is an aqueous solution composed of two weak acids.
B) A buffer can absorb an unlimited amount of acid or base.
C) A buffer resists pH change by neutralizing added acids and bases.
D) A buffer does not change pH when large amounts of a strong acid or a strong base are added.
E) The common ion in a buffer solution does not have any effect on the dissociation of the acidic component of the buffer solution.
A) A buffer is an aqueous solution composed of two weak acids.
B) A buffer can absorb an unlimited amount of acid or base.
C) A buffer resists pH change by neutralizing added acids and bases.
D) A buffer does not change pH when large amounts of a strong acid or a strong base are added.
E) The common ion in a buffer solution does not have any effect on the dissociation of the acidic component of the buffer solution.
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9
Calculate the pH of a buffer that is 0.225 mol L-1 CH3COOH and 0.162 mol L-1 CH3COOK. The Ka for CH3COOH is 1.8 × 10-5.
A) 4.89
B) 9.11
C) 4.74
D) 9.26
E) 4.60
A) 4.89
B) 9.11
C) 4.74
D) 9.26
E) 4.60
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10
If the pKa of HCOOH is 3.74 and the pH of an HCOOH/HCOONa solution is 3.11, which of the following is TRUE?
A) [HCOOH] < [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] << [HCOONa]
D) [HCOOH] > [HCOONa]
E) [HCOOH] >> [HCOONa]
A) [HCOOH] < [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] << [HCOONa]
D) [HCOOH] > [HCOONa]
E) [HCOOH] >> [HCOONa]
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11
Calculate the pH of a buffer that is 0.020 mol L-1 HF and 0.040 mol L-1 LiF. The Ka for HF is 3.5 × 10-4.
A) 2.06
B) 4.86
C) 3.16
D) 3.46
E) 3.76
A) 2.06
B) 4.86
C) 3.16
D) 3.46
E) 3.76
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12
You wish to prepare a buffer containing CH3COOH with a pH of 5.44. If the pKa of acetic acid is 4.74, what ratio of [CH3COO⁻]/[CH3COOH] must you use?
A) 0.70
B) 0.20
C) 1.4
D) 5.0
E) 1.1
A) 0.70
B) 0.20
C) 1.4
D) 5.0
E) 1.1
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13
Calculate the pH of a buffer that is 0.158 mol L-1 HClO and 0.099 mol L-1 NaClO. The Ka for HClO is 2.9 × 10-8.
A) 7.54
B) 6.67
C) 3.77
D) 6.46
E) 7.33
A) 7.54
B) 6.67
C) 3.77
D) 6.46
E) 7.33
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14
You wish to prepare a buffer containing CH3COOH with a pH of 4.24. If the pKa of acetic acid is 4.74, what ratio of [CH3COO⁻]/[CH3COOH] must you use?
A) 0.10
B) 0.50
C) 0.32
D) 2.0
E) 2.8
A) 0.10
B) 0.50
C) 0.32
D) 2.0
E) 2.8
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15
Identify a good buffer.
A) a solution containing small amounts of both a weak acid and its conjugate base
B) a solution containing significant amounts of both a strong acid and a strong base
C) a solution containing small amounts of both a strong acid and a strong base
D) a solution containing significant amounts of both a weak acid and a strong acid
E) a solution containing significant amounts of both a weak acid and its conjugate base
A) a solution containing small amounts of both a weak acid and its conjugate base
B) a solution containing significant amounts of both a strong acid and a strong base
C) a solution containing small amounts of both a strong acid and a strong base
D) a solution containing significant amounts of both a weak acid and a strong acid
E) a solution containing significant amounts of both a weak acid and its conjugate base
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16
Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 mol L-1 NH4Cl with 100.0 mL of 0.20 mol L-1 NH3. The Kb for NH3 is 1.8 × 10-5.
A) 9.13
B) 9.25
C) 9.53
D) 4.74
E) 8.98
A) 9.13
B) 9.25
C) 9.53
D) 4.74
E) 8.98
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17
Which of the following solutions represents a good buffer system?
A) a solution that is 0.10 mol L-1 CH3COOH and 0.10 mol L-1 CH3COOLi
B) a solution that is 0.10 mol L-1 HF and 0.10 mol L-1 CH3COONa
C) a solution that is 0.10 mol L-1 HCl and 0.10 mol L-1 NH4+
D) a solution that is 0.10 mol L-1 NaOH and 0.10 mol L-1 KOH
E) a solution that is 0.10 mol L-1 HCl and 0.10 mol L-1 KCl
A) a solution that is 0.10 mol L-1 CH3COOH and 0.10 mol L-1 CH3COOLi
B) a solution that is 0.10 mol L-1 HF and 0.10 mol L-1 CH3COONa
C) a solution that is 0.10 mol L-1 HCl and 0.10 mol L-1 NH4+
D) a solution that is 0.10 mol L-1 NaOH and 0.10 mol L-1 KOH
E) a solution that is 0.10 mol L-1 HCl and 0.10 mol L-1 KCl
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18
A buffer solution is 0.100 mol L-1 in both C6H5COOH and C6H5COOLi and has a pH of 4.19. Which of the following pH values would you expect after the addition of a small amount of a strong base?
A) 3.89
B) 3.69
C) 5.69
D) 4.49
E) 8.89
A) 3.89
B) 3.69
C) 5.69
D) 4.49
E) 8.89
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19
Which of the following solutions is a good buffer system?
A) a solution that is 0.10 mol L-1 NaCl and 0.10 mol L-1 HCl
B) a solution that is 0.10 mol L-1 HCN and 0.10 mol L-1 LiCN
C) a solution that is 0.10 mol L-1 NaOH and 0.10 mol L-1 HNO3
D) a solution that is 0.10 mol L-1 HNO3 and 0.10 mol L-1 KNO3
E) a solution that is 0.10 mol L-1 HCN and 0.10 mol L-1 NaCl
A) a solution that is 0.10 mol L-1 NaCl and 0.10 mol L-1 HCl
B) a solution that is 0.10 mol L-1 HCN and 0.10 mol L-1 LiCN
C) a solution that is 0.10 mol L-1 NaOH and 0.10 mol L-1 HNO3
D) a solution that is 0.10 mol L-1 HNO3 and 0.10 mol L-1 KNO3
E) a solution that is 0.10 mol L-1 HCN and 0.10 mol L-1 NaCl
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20
If the pKa of HCOOH is 3.74 and the pH of an HCOOH/HCOONa buffer solution is 3.89, which of the following is TRUE?
A) [HCOOH] < [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] > [HCOONa]
D) [HCOOH] >> [HCOONa]
E) [HCOOH] << [HCOONa]
A) [HCOOH] < [HCOONa]
B) [HCOOH] = [HCOONa]
C) [HCOOH] > [HCOONa]
D) [HCOOH] >> [HCOONa]
E) [HCOOH] << [HCOONa]
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21
Define buffer capacity.
A) Buffer capacity is the amount of acid or base that can be added to a buffer without destroying its effectiveness.
B) Buffer capacity is the amount of acid that can be added until all the base in the buffer is consumed.
C) Buffer capacity is the amount of base that can be added until all the acid in the buffer is consumed.
D) Buffer capacity is the amount of acid that can be added until all the acid in the buffer is consumed.
E) Buffer capacity is the amount of base that can be added until all the base in the buffer is consumed.
A) Buffer capacity is the amount of acid or base that can be added to a buffer without destroying its effectiveness.
B) Buffer capacity is the amount of acid that can be added until all the base in the buffer is consumed.
C) Buffer capacity is the amount of base that can be added until all the acid in the buffer is consumed.
D) Buffer capacity is the amount of acid that can be added until all the acid in the buffer is consumed.
E) Buffer capacity is the amount of base that can be added until all the base in the buffer is consumed.
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22
A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in LiF. Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH. Assume no volume change upon the addition of the base. The Ka for HF is 3.5 × 10-4.
A) 3.46
B) 4.06
C) 2.85
D) 3.63
E) 4.24
A) 3.46
B) 4.06
C) 2.85
D) 3.63
E) 4.24
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23
Calculate the mole ratio of HCOONa to HCOOH required to make a buffer with pH of 3.62. Ka of HCOOH is 1.8 × 10-4.
A) 0.122
B) 3.00
C) 0.75
D) 1.22
E) 10.0
A) 0.122
B) 3.00
C) 0.75
D) 1.22
E) 10.0
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24
Which of the following acids (listed with pKa values) and its conjugate would be the best choice to make a buffer with a pH of 10.40?
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
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25
Which of the following acids (listed with pKa values) and its conjugate would be the best choice to make a buffer with a pH of 5.20?
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
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26
Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 8.10?
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
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27
Which of the following acids (listed with pKa values) and its conjugate would be the best choice to make a buffer with a pH of 2.12?
A) HC7H5O2, pKa = 4.19
B) CH3COOH, pKa = 4.74
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
A) HC7H5O2, pKa = 4.19
B) CH3COOH, pKa = 4.74
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
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28
Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 10.40?
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
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29
Which of the following is TRUE?
A) An effective buffer has a [base]/[acid] ratio in the range of 10-100.
B) A buffer is most resistant to pH change when [acid] = [conjugate base].
C) An effective buffer has very small absolute concentrations of acid and conjugate base.
D) The capacity of a buffer cannot be exceeded by adding too much strong base. It can only be exceeded by adding too much strong acid.
E) A buffer has the best resistance to pH change when the buffer's pH is significantly lower than the pKa of the acid used to make the buffer solution.
A) An effective buffer has a [base]/[acid] ratio in the range of 10-100.
B) A buffer is most resistant to pH change when [acid] = [conjugate base].
C) An effective buffer has very small absolute concentrations of acid and conjugate base.
D) The capacity of a buffer cannot be exceeded by adding too much strong base. It can only be exceeded by adding too much strong acid.
E) A buffer has the best resistance to pH change when the buffer's pH is significantly lower than the pKa of the acid used to make the buffer solution.
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30
A 1.50 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in NaF. Calculate the pH of the solution after the addition of 0.0500 moles of solid NaOH. Assume no volume change upon the addition of the base. The Ka for HF is 3.5 × 10-4.
A) 3.34
B) 3.46
C) 3.57
D) 3.63
E) 2.89
A) 3.34
B) 3.46
C) 3.57
D) 3.63
E) 2.89
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31
A 1.00 L buffer solution is 0.250 mol L-1 in HF and 0.250 mol L-1 in NaF. Calculate the pH of the solution after the addition of 100.0 mL of 1.00 mol L-1 HCl. The Ka for HF is 3.5 × 10-4.
A) 3.09
B) 4.11
C) 3.82
D) 3.46
E) 2.78
A) 3.09
B) 4.11
C) 3.82
D) 3.46
E) 2.78
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32
Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 mol L-1 HCOOH with 100.0 mL of 0.20 mol L-1 HCOOLi. The Ka for HCHO2 is 1.8 × 10-4.
A) 3.87
B) 3.74
C) 10.53
D) 3.47
E) 10.13
A) 3.87
B) 3.74
C) 10.53
D) 3.47
E) 10.13
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33
Calculate the pH of a solution formed by mixing 200.0 mL of 0.30 mol L-1 HClO with 300.0 mL of 0.20 mol L-1 KClO. The Ka for HClO is 2.9 × 10-8.
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
A) 5.99
B) 8.01
C) 7.54
D) 7.06
E) 6.46
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34
Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 2.34?
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
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35
Which of the following acids (listed with Ka values) and their conjugate base would be the best choice to make a buffer with a pH of 5.20?
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
A) C6H5COOH, Ka = 6.5 × 10-5
B) HF, Ka = 3.5 × 10-4
C) HClO, Ka = 2.9 × 10-8
D) HCN, Ka = 4.9 × 10-10
E) HClO2, Ka = 1.1 × 10-2
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36
What is the maximum ratio of conjugate base to acid in an effective buffer?
A) 2
B) 5
C) 10
D) 20
E) 15
A) 2
B) 5
C) 10
D) 20
E) 15
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37
Which of the following acids (listed with pKa values) and its conjugate would be the best choice to make a buffer with a pH of 8.10?
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
A) HC7H5O2, pKa = 4.19
B) HF, pKa = 3.46
C) HClO, pKa = 7.54
D) HCN, pKa = 9.31
E) HClO2, pKa = 1.96
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38
A 1.00 L buffer solution is 0.150 mol L-1 in C6H5COOH and 0.250 mol L-1 in C6H5COOLi. Calculate the pH of the solution after the addition of 100.0 mL of 1.00 mol L-1 HCl. The Ka for HC7H5O2 is 6.5 × 10-5.
A) 4.19
B) 5.03
C) 4.41
D) 3.34
E) 3.97
A) 4.19
B) 5.03
C) 4.41
D) 3.34
E) 3.97
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39
Calculate the mole ratio of CH3COONa to CH3COOH required to make a buffer with pH of 4.83. Ka of CH3COOH is 1.8 × 10-5.
A) 0.122
B) 3.00
C) 0.75
D) 1.22
E) 10.0
A) 0.122
B) 3.00
C) 0.75
D) 1.22
E) 10.0
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40
Calculate the pH of a solution formed by mixing 150.0 mL of 0.10 mol L-1 C6H5COOH with 100.0 mL of 0.30 mol L-1 C6H5COONa. The Ka for C6H5COOH is 6.5 × 10-5.
A) 4.19
B) 9.69
C) 4.49
D) 4.31
E) 10.51
A) 4.19
B) 9.69
C) 4.49
D) 4.31
E) 10.51
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41
The titration of 80.0 mL of an unknown concentration H3PO4 solution requires 126 mL of 0.218 mol L-1 KOH solution. What is the concentration of the H3PO4 solution (in mol L-1)?
A) 1.03 mol L-1
B) 0.343 mol L-1
C) 0.114 mol L-1
D) 0.138 mol L-1
E) 0.0461 mol L-1
A) 1.03 mol L-1
B) 0.343 mol L-1
C) 0.114 mol L-1
D) 0.138 mol L-1
E) 0.0461 mol L-1
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42
A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 30.0 mL of NaOH.
A) 0.86
B) 1.21
C) 2.00
D) 1.12
E) 2.86
A) 0.86
B) 1.21
C) 2.00
D) 1.12
E) 2.86
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43
A 100.0 mL sample of 0.180 mol L-1 HClO4 is titrated with 0.270 mol L-1 NaOH. Determine the pH of the solution after the addition of 75.0 mL of NaOH.
A) 12.1
B) 2.65
C) 11.35
D) 1.89
E) 13.06
A) 12.1
B) 2.65
C) 11.35
D) 1.89
E) 13.06
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44
A 1.0 L buffer solution is 0.250 mol L-1 CH3COOH and 0.050 mol L-1 CH3COOLi. Which of the following actions will exceed the capacity of the buffer?
A) adding 0.050 moles of CH3COOLi
B) adding 0.050 moles of CH3COOH
C) adding 0.050 moles of HCl
D) adding 0.050 moles of NaCl
E) adding 0.050 moles of NH4Cl
A) adding 0.050 moles of CH3COOLi
B) adding 0.050 moles of CH3COOH
C) adding 0.050 moles of HCl
D) adding 0.050 moles of NaCl
E) adding 0.050 moles of NH4Cl
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45
Identify the indicator that can be used at the lowest pH.
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
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46
Identify the pH of normal blood.
A) 7.0
B) 7.2
C) 7.4
D) 7.6
E) 7.8
A) 7.0
B) 7.2
C) 7.4
D) 7.6
E) 7.8
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47
Calculate the mole ratio of C6H5COONa to C6H5COOH required to make a buffer with pH of 4.68. Ka of C6H5COOH is 6.3 × 10-5.
A) 0.122
B) 3.02
C) 0.75
D) 1.22
E) 10.0
A) 0.122
B) 3.02
C) 0.75
D) 1.22
E) 10.0
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48
A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 66.67 mL of NaOH (this is the equivalence point).
A) 0.97
B) 13.03
C) 2.76
D) 11.24
E) 7.00
A) 0.97
B) 13.03
C) 2.76
D) 11.24
E) 7.00
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49
When titrating a strong monoprotic acid with KOH at 25 °C, the ________.
A) pH will be less than 7 at the equivalence point
B) pH will be greater than 7 at the equivalence point
C) titration will require more moles of base than acid to reach the equivalence point
D) pH will be equal to 7 at the equivalence point
E) titration will require more moles of acid than base to reach the equivalence point
A) pH will be less than 7 at the equivalence point
B) pH will be greater than 7 at the equivalence point
C) titration will require more moles of base than acid to reach the equivalence point
D) pH will be equal to 7 at the equivalence point
E) titration will require more moles of acid than base to reach the equivalence point
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50
Identify the indicator that can be used at the highest pH.
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
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51
Identify the indicator that has two endpoints.
A) phenol red
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
A) phenol red
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
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52
When titrating a monoprotic strong acid with a weak base at 25 °C, the ________.
A) pH will be 7 at the equivalence point
B) pH will be greater than 7 at the equivalence point
C) titration will require more moles of base than acid to reach the equivalence point
D) titration will require more moles of acid than base to reach the equivalence point
E) pH will be less than 7 at the equivalence point
A) pH will be 7 at the equivalence point
B) pH will be greater than 7 at the equivalence point
C) titration will require more moles of base than acid to reach the equivalence point
D) titration will require more moles of acid than base to reach the equivalence point
E) pH will be less than 7 at the equivalence point
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53
The titration of 25.0 mL of an unknown concentration H2SO4 solution requires 83.6 mL of a 0.12 mol L-1 LiOH solution. What is the concentration of the H2SO4 solution (in mol L-1)?
A) 0.20 mol L-1
B) 0.40 mol L-1
C) 0.10 mol L-1
D) 0.36 mol L-1
E) 0.25 mol L-1
A) 0.20 mol L-1
B) 0.40 mol L-1
C) 0.10 mol L-1
D) 0.36 mol L-1
E) 0.25 mol L-1
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54
Which of the following is TRUE?
A) The equivalence point is where the amount of acid equals the amount of base during any acid-base titration.
B) At the equivalence point, the pH is always 7.
C) An indicator is not pH sensitive.
D) A titration curve is a plot of pH vs. the [base]/[acid] ratio.
E) A titration curve is a plot of pH versus titration time.
A) The equivalence point is where the amount of acid equals the amount of base during any acid-base titration.
B) At the equivalence point, the pH is always 7.
C) An indicator is not pH sensitive.
D) A titration curve is a plot of pH vs. the [base]/[acid] ratio.
E) A titration curve is a plot of pH versus titration time.
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55
A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution after the addition of 100.0 mL of NaOH.
A) 13.1
B) 12.7
C) 1.3
D) 0.9
E) 12.9
A) 13.1
B) 12.7
C) 1.3
D) 0.9
E) 12.9
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56
Identify the most commonly used indicator among the following five.
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
A) alizarin
B) thymol blue
C) crystal violet
D) phenolphthalein
E) alizarin yellow R
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57
When titrating a weak monoprotic acid with NaOH at 25 °C, the ________.
A) pH will be less than 7 at the equivalence point
B) pH will be equal to 7 at the equivalence point
C) pH will be greater than 7 at the equivalence point
D) titration will require more moles of base than acid to reach the equivalence point
E) titration will require more moles of acid than base to reach the equivalence point
A) pH will be less than 7 at the equivalence point
B) pH will be equal to 7 at the equivalence point
C) pH will be greater than 7 at the equivalence point
D) titration will require more moles of base than acid to reach the equivalence point
E) titration will require more moles of acid than base to reach the equivalence point
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58
What is the pH of a solution made by mixing 40.00 mL of 0.100 mol L-1 HCl with 25.00 mL of 0.100 mol L-1 KOH? Assume that the volumes of the solutions are additive.
A) 0.64
B) 1.64
C) 12.36
D) 13.36
E) 10.00
A) 0.64
B) 1.64
C) 12.36
D) 13.36
E) 10.00
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59
A 1.0 L buffer solution is 0.050 mol L-1 CH3COOH and 0.250 mol L-1 CH3COOLi. Which of the following actions will destroy the buffer?
A) adding 0.050 moles of NaOH
B) adding 0.050 moles of HCl
C) adding 0.050 moles of CH3COOH
D) adding 0.050 moles of CH3COOLi
E) adding 0.050 moles of NH4Cl.
A) adding 0.050 moles of NaOH
B) adding 0.050 moles of HCl
C) adding 0.050 moles of CH3COOH
D) adding 0.050 moles of CH3COOLi
E) adding 0.050 moles of NH4Cl.
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60
A 100.0 mL sample of 0.18 mol L-1 HClO4 is titrated with 0.27 mol L-1 NaOH. Determine the pH of the solution before the addition of any NaOH.
A) 1.74
B) 1.05
C) 0.74
D) 0.57
E) 1.57
A) 1.74
B) 1.05
C) 0.74
D) 0.57
E) 1.57
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61
An acid solution is 0.100 mol L-1 in HCl and 0.200 mol L-1
. What volume of a 0.150 mol L-1 KOH solution would completely neutralize 500.0 mL of this solution?
A) 0.700 L
B) 1.98 L
C) 1.67 L
D) 1.02 L
E) 0.250 L


A) 0.700 L
B) 1.98 L
C) 1.67 L
D) 1.02 L
E) 0.250 L
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62
A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH. Determine the pH of the solution after the addition of 200.0 mL of KOH. The Ka of HF is 3.5 × 10-4.
A) 9.62
B) 7.00
C) 3.46
D) 10.54
E) 8.14
A) 9.62
B) 7.00
C) 3.46
D) 10.54
E) 8.14
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63
A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH. Determine the pH of the solution before the addition of any KOH. The Ka of HF is 3.5 × 10-4.
A) 4.15
B) 0.70
C) 2.08
D) 3.46
E) 1.00
A) 4.15
B) 0.70
C) 2.08
D) 3.46
E) 1.00
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64
Identify the salts that are in hard water.
A) CaCO3 and MgCO3
B) MgSO4 and CaSO4
C) NaCl and KBr
D) NaHSO4 and Na2SO4
E) NaOCl and HOCl
A) CaCO3 and MgCO3
B) MgSO4 and CaSO4
C) NaCl and KBr
D) NaHSO4 and Na2SO4
E) NaOCl and HOCl
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65
Which of the following compounds will have the highest molar solubility in pure water?
A) PbSO4, Ksp = 1.82 × 10-8
B) MgCO3, Ksp = 6.82 × 10-6
C) AgI, Ksp = 8.51 × 10-17
D) PbS, Ksp = 9.04 × 10-29
E) FeS, Ksp = 3.72 × 10-19
A) PbSO4, Ksp = 1.82 × 10-8
B) MgCO3, Ksp = 6.82 × 10-6
C) AgI, Ksp = 8.51 × 10-17
D) PbS, Ksp = 9.04 × 10-29
E) FeS, Ksp = 3.72 × 10-19
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66
A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH. Determine the pH of the solution after the addition of 400.0 mL of KOH. The Ka of HF is 3.5 × 10-4.
A) 13.08
B) 12.60
C) 13.85
D) 12.30
E) 12.78
A) 13.08
B) 12.60
C) 13.85
D) 12.30
E) 12.78
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67
A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 200.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.
A) 6.44
B) 1.48
C) 2.00
D) 12.52
E) 12.00
A) 6.44
B) 1.48
C) 2.00
D) 12.52
E) 12.00
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68
A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 50.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.
A) 4.74
B) 7.78
C) 7.05
D) 9.26
E) 10.34
A) 4.74
B) 7.78
C) 7.05
D) 9.26
E) 10.34
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69
A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr. Determine the pH of the solution after the addition of 400.0 mL HBr.
A) 1.00
B) 1.40
C) 1.22
D) 1.30
E) 2.11
A) 1.00
B) 1.40
C) 1.22
D) 1.30
E) 2.11
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70
A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 150.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.
A) 1.7
B) 6.4
C) 7.6
D) 12.3
E) 2.3
A) 1.7
B) 6.4
C) 7.6
D) 12.3
E) 2.3
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71
A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH. Determine the pH of the solution after the addition of 100.0 mL of KOH. The Ka of HF is 3.5 × 10-4.
A) 2.08
B) 3.15
C) 4.33
D) 3.46
E) 4.15
A) 2.08
B) 3.15
C) 4.33
D) 3.46
E) 4.15
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72
A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution after the addition of 100.0 mL of HNO3. The Kb of NH3 is 1.8 × 10-5.
A) 6.58
B) 10.56
C) 8.72
D) 3.44
E) 5.28
A) 6.58
B) 10.56
C) 8.72
D) 3.44
E) 5.28
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73
A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr. Determine the pH of the solution after the addition of 300.0 mL HBr.
A) 1.60
B) 1.30
C) 1.00
D) 12.40
E) 1.12
A) 1.60
B) 1.30
C) 1.00
D) 12.40
E) 1.12
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74
A 100.0 mL sample of 0.20 mol L-1 HF is titrated with 0.10 mol L-1 KOH. Determine the pH of the solution after the addition of 300.0 mL of KOH. The Ka of HF is 3.5 × 10-4.
A) 12.40
B) 9.33
C) 5.06
D) 8.94
E) 12.00
A) 12.40
B) 9.33
C) 5.06
D) 8.94
E) 12.00
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75
Which of the following compounds' solubility will not be affected by a low pH in solution?
A) AgCl
B) Mg(OH)2
C) CaF2
D) CuS
E) BaCO3
A) AgCl
B) Mg(OH)2
C) CaF2
D) CuS
E) BaCO3
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76
A 100.0 mL sample of 0.10 mol L-1 NH3 is titrated with 0.10 mol L-1 HNO3. Determine the pH of the solution before the addition of any HNO3. The Kb of NH3 is 1.8 × 10-5.
A) 4.74
B) 9.26
C) 11.13
D) 13.00
E) 12.55
A) 4.74
B) 9.26
C) 11.13
D) 13.00
E) 12.55
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77
A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr. Determine the pH of the solution after the addition of 200.0 mL HBr.
A) 2.62
B) 2.00
C) 1.48
D) 12.52
E) 7.00
A) 2.62
B) 2.00
C) 1.48
D) 12.52
E) 7.00
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78
A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr. Determine the pH of the solution before the addition of any HBr.
A) 12.86
B) 13.00
C) 13.30
D) 0.70
E) 1.00
A) 12.86
B) 13.00
C) 13.30
D) 0.70
E) 1.00
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79
A 100.0 mL sample of 0.10 mol L-1 Ca(OH)2 is titrated with 0.10 mol L-1 HBr. Determine the pH of the solution after the addition of 100.0 mL HBr.
A) 2.00
B) 12.00
C) 1.30
D) 12.70
E) 7.00
A) 2.00
B) 12.00
C) 1.30
D) 12.70
E) 7.00
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80
Which of the following compounds will be more soluble in acidic solution than in pure water?
A) PbCl2
B) FeS
C) Ca(ClO4)2
D) CuI
E) AgBr
A) PbCl2
B) FeS
C) Ca(ClO4)2
D) CuI
E) AgBr
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