Deck 11: Acids and Bases
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Deck 11: Acids and Bases
1
Which of the following compounds is not an Arrhenius acid?
A) HCl
B) H2SO4
C) H2O
D) FeCl3
E) H2S
A) HCl
B) H2SO4
C) H2O
D) FeCl3
E) H2S
FeCl3
2
Which of the following compounds is not an Arrhenius base?
A) NaOH
B) Al(OH)3
C) Ca(OH)2
D) H2O
E) NH3
A) NaOH
B) Al(OH)3
C) Ca(OH)2
D) H2O
E) NH3
NH3
3
Consider the following reaction:
H2PO4-(aq) + HCO3-(aq)
H2CO3(aq) + HPO42-(aq)
Brønsted would identify the acidic species as:
A) H2PO4- and H2CO3
B) H2PO4- and HPO42-
C) HCO3- and H2CO3
D) HCO3- and HPO42-
E) H2CO3 and HPO42-
H2PO4-(aq) + HCO3-(aq)

Brønsted would identify the acidic species as:
A) H2PO4- and H2CO3
B) H2PO4- and HPO42-
C) HCO3- and H2CO3
D) HCO3- and HPO42-
E) H2CO3 and HPO42-
H2PO4- and H2CO3
4
Which compound cannot act as a Brønsted base?
A) NH3
B) H2O
C) CH4
D) F-
E) H2S
A) NH3
B) H2O
C) CH4
D) F-
E) H2S
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5
Which of the following compounds cannot be a base?
A) H2O
B) NH3
C) CO32-
D) OH-
E) NH4+
A) H2O
B) NH3
C) CO32-
D) OH-
E) NH4+
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6
Which of the following isn't a Brønsted base?
A) PF5
B) H2O
C) NH3
D) S2-
E) CN-
A) PF5
B) H2O
C) NH3
D) S2-
E) CN-
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7
What is the conjugate acid of hydrogen carbonate ion, HCO3 - ?
A) H3O+
B) OH -
C) H2O
D) CO32 -
E) H2CO3
A) H3O+
B) OH -
C) H2O
D) CO32 -
E) H2CO3
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8
What is the conjugate base of thiocyanic acid, HSCN?
A) H3O+
B) OH -
C) SCN -
D) CN -
E) H2SCN+
A) H3O+
B) OH -
C) SCN -
D) CN -
E) H2SCN+
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9
The dihydrogen phosphate ion, H2PO4 - , can behave as both an acid and as a base. What is the chemical formula of the conjugate acid of dihydrogen phosphate? What is the chemical formula of the conjugate base of dihydrogen phosphate?
A) conjugate acid = H3PO4 conjugate base = HPO42 -
B) conjugate acid = H2PO4+ conjugate base = H2PO42 -
C) conjugate acid = HPO42 - conjugate base = H3PO4
D) conjugate acid = H3PO4 conjugate base = PO43 -
E) none of these
A) conjugate acid = H3PO4 conjugate base = HPO42 -
B) conjugate acid = H2PO4+ conjugate base = H2PO42 -
C) conjugate acid = HPO42 - conjugate base = H3PO4
D) conjugate acid = H3PO4 conjugate base = PO43 -
E) none of these
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10
Ethanol (CH3CH2OH), like water, can behave both as an acid or as a base. Which of the following structures corresponds to the Brønsted conjugate acid and conjugate base of ethanol?

A)
B)
C)
D)
E) none of these

A)

B)

C)

D)

E) none of these
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11
What is the conjugate base of HSO4-?
A) H2O
B) H2SO4
C) HSO4-
D) SO3
E) none of the above
A) H2O
B) H2SO4
C) HSO4-
D) SO3
E) none of the above
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12
Methanol is described by the following skeleton structure.
Which substance is formed when CH3OH acts as a Brønsted base?
A) CH3O-
B) CH3OH
C) CH3OH2+
D) CH3OH.
E) H3O+

Which substance is formed when CH3OH acts as a Brønsted base?
A) CH3O-
B) CH3OH
C) CH3OH2+
D) CH3OH.
E) H3O+
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13
The compound HB can be represented as
where
represent B- and
represents H+. Given this, ___ would represent the conjugate acid of HB and ____ would represent the conjugate base.
A) 1,2
B) 1,5
C) 3,4
D) 1,3
E) None of the above.




A) 1,2
B) 1,5
C) 3,4
D) 1,3
E) None of the above.
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14
Which of the following is the conjugate base of a strong acid?
A) OH-
B) HSO4-
C) NH2-
D) S2-
E) H3O+
A) OH-
B) HSO4-
C) NH2-
D) S2-
E) H3O+
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15
Which of the following represents a conjugate acid/base pair?
A) H+, OH-
B) H3O+, OH-
C) NH3, NH4+
D) NaOH, HCl
E) All of the above are conjugate acid/base pairs.
A) H+, OH-
B) H3O+, OH-
C) NH3, NH4+
D) NaOH, HCl
E) All of the above are conjugate acid/base pairs.
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16
A solution is known to have a hydronium ion concentration of 1.0 x 10-6 M. What percentage of the total H3O+ ion concentration comes from the dissociation of water?
A) 1%
B) 3%
C) 5%
D) 10%
E) 100%
A) 1%
B) 3%
C) 5%
D) 10%
E) 100%
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17
What is the [H3O+] concentration of a solution with a pH of 8.75?
A) 1.8 x 10 - 9M
B) 9.4 x 10 - 1M
C) 8.7 x 10-5M
D) 5.6 x 108M
E) This is a basic solution, [H3O+] cannot be determined.
A) 1.8 x 10 - 9M
B) 9.4 x 10 - 1M
C) 8.7 x 10-5M
D) 5.6 x 108M
E) This is a basic solution, [H3O+] cannot be determined.
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18
A solution of weak base is added to a beaker of water. Which of the following will be true as the base is added to the water?
A) [H3O+] increases [OH - ] decreases pH increases
B) [H3O+] decreases [OH -F ] increases pH decreases
C) [H3O+] decreases [OH - ] decreases pH increases
D) [H3O+] remains constant [OH - ] increases pH increases
E) none of these
A) [H3O+] increases [OH - ] decreases pH increases
B) [H3O+] decreases [OH -F ] increases pH decreases
C) [H3O+] decreases [OH - ] decreases pH increases
D) [H3O+] remains constant [OH - ] increases pH increases
E) none of these
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19
Determine the [OH ] for an aqueous solution at 25
C with a pH of 4.80.
A) 6.3x10 10M
B) 1.6x10 5M
C) 1.6x10 9M
D) 8.0x10 8M
E) none of these
![<strong>Determine the [OH <sup></sup> ] for an aqueous solution at 25 C with a pH of 4.80.</strong> A) 6.3x10 <sup></sup> <sup>10</sup>M B) 1.6x10 <sup></sup> <sup>5</sup>M C) 1.6x10 <sup></sup> <sup>9</sup>M D) 8.0x10 <sup></sup> <sup>8</sup>M E) none of these](https://storage.examlex.com/TB9692/11ee9f01_38f8_89d9_9fac_1f2262b4b888_TB9692_11.jpg)
A) 6.3x10 10M
B) 1.6x10 5M
C) 1.6x10 9M
D) 8.0x10 8M
E) none of these
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20
A strong acid is added to water. Which of the following will be true?
A) [H3O+] increases, [OH - ] decreases, pH increases
B) [H3O+] decreases, [OH - ] increases, pH decreases
C) [H3O+] decreases, [OH - ] decreases, pH decreases
D) [H3O+] increases, [OH - ] increases, pH increases
E) none of these
A) [H3O+] increases, [OH - ] decreases, pH increases
B) [H3O+] decreases, [OH - ] increases, pH decreases
C) [H3O+] decreases, [OH - ] decreases, pH decreases
D) [H3O+] increases, [OH - ] increases, pH increases
E) none of these
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21
What is the H3O+ ion concentration in a solution that has a pH of 5.75?
A) 5.8 x 10-5 M
B) 3.2 x 10-3 M
C) 0.75 x 10-5 M
D) 3.6 x 10-7 M
E) 1.8 x 10-6 M
A) 5.8 x 10-5 M
B) 3.2 x 10-3 M
C) 0.75 x 10-5 M
D) 3.6 x 10-7 M
E) 1.8 x 10-6 M
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22
What is the pH of a solution that is 1.7 x 10-4 M in H3O+?
A) 3.77
B) 4.77
C) 4.23
D) 10.23
E) none of these
A) 3.77
B) 4.77
C) 4.23
D) 10.23
E) none of these
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23
What is the hydroxide ion concentration in a pH = 5.14 solution?
A) 1.0 x 10-14
B) 1.4 x 10-9
C) 1.0 x 10-7
D) 7.2 x 10-6
E) 1.4 x 10-2
A) 1.0 x 10-14
B) 1.4 x 10-9
C) 1.0 x 10-7
D) 7.2 x 10-6
E) 1.4 x 10-2
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24
Which equation best describes a 0.10 M solution of a strong acid such as hydroiodic acid (HI: Ka = 3 x 109)?
A) [H3O+] = initial concentration of HI
B) [H3O+] [OH-]
C) [H3O+] final concentration of HI
D) [H3O+] [H2O]
E) [H3O+] Ka.[OH-]
A) [H3O+] = initial concentration of HI
B) [H3O+] [OH-]
C) [H3O+] final concentration of HI
D) [H3O+] [H2O]
E) [H3O+] Ka.[OH-]
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25
Which of the following acids would have the strongest conjugate base?
A) HOCl (Ka = 2.9 x 10-8)
B) HOBr (Ka = 2.4 x 10-9)
C) HOI (Ka = 2.3 x 10-11)
D) H2O2 (Ka = 2.2 x 10-12)
E) H2O (Ka = 1.8 x 10-16)
A) HOCl (Ka = 2.9 x 10-8)
B) HOBr (Ka = 2.4 x 10-9)
C) HOI (Ka = 2.3 x 10-11)
D) H2O2 (Ka = 2.2 x 10-12)
E) H2O (Ka = 1.8 x 10-16)
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26
Using a table of Ka's, determine which of the following is the strongest Brønsted acid.
A) NH4+
B) HCl
C) HNO3
D) HSO4-
E) HClO4
A) NH4+
B) HCl
C) HNO3
D) HSO4-
E) HClO4
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27
Using a table of Ka's, determine which of the following is the strongest base.
A) I-
B) NO3-
C) HS-
D) O2-
E) OH-
A) I-
B) NO3-
C) HS-
D) O2-
E) OH-
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28
Using a table of Ka's, determine which of the following is the strongest acid.
A) NH2-
B) HS-
C) H2O
D) CH4
E) NH4+
A) NH2-
B) HS-
C) H2O
D) CH4
E) NH4+
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29
If the strength of the following acids increases from left to right
CH3NH2 < CH3NH3+ < C6H5NH3 + < C6H5CO2H < HCl
The order of increasing base strength, reading from left to right, must be:
A) CH3NH- < CH3NH2 < C6H5NH2 < C6H5CO2- < Cl-
B) Cl- < C6H5CO2- < C6H5NH2 < CH3NH2 < CH3NH-
C) C6H5NH2 < CH3NH2 < Cl- < C6H5CO2- < CH3NH-
D) CH3NH- < C6H5CO2- < Cl- < CH3NH2 < C6H5NH2
E) none of the above
CH3NH2 < CH3NH3+ < C6H5NH3 + < C6H5CO2H < HCl
The order of increasing base strength, reading from left to right, must be:
A) CH3NH- < CH3NH2 < C6H5NH2 < C6H5CO2- < Cl-
B) Cl- < C6H5CO2- < C6H5NH2 < CH3NH2 < CH3NH-
C) C6H5NH2 < CH3NH2 < Cl- < C6H5CO2- < CH3NH-
D) CH3NH- < C6H5CO2- < Cl- < CH3NH2 < C6H5NH2
E) none of the above
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30
Explain the following observation: Water becomes acidic when CO2 is bubbled into it.
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31
Which of the following is the weakest acid?
A) HClO4
B) HCl
C) HF
D) HI
E) HBr
A) HClO4
B) HCl
C) HF
D) HI
E) HBr
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32
Arrange the following bases in order of increasing strength: NH3, PH3, H2O and H2S.
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33
Which of the following statements is true?
A) H2O is a stronger acid than HF(aq).
B) H2O is a stronger acid than H2S(aq).
C) H2O is a stronger acid than the H3O+(aq) ion.
D) H2O is a stronger acid than NH3(aq).
E) None of the above are true.
A) H2O is a stronger acid than HF(aq).
B) H2O is a stronger acid than H2S(aq).
C) H2O is a stronger acid than the H3O+(aq) ion.
D) H2O is a stronger acid than NH3(aq).
E) None of the above are true.
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34
What can be correctly concluded from the fact that the following acid-base reaction proceeds to the right, as written?
NH2-(aq) + HSO4-(aq)
NH3(aq) + SO42-(aq)
A) NH3 is a stronger base than NH2-.
B) NH3 is a stronger acid than HSO4-.
C) NH3 is a weaker acid than NH2-.
D) NH3 is a weaker base than HSO4-.
E) NH3 is a weaker acid than HSO4-.
NH2-(aq) + HSO4-(aq)

A) NH3 is a stronger base than NH2-.
B) NH3 is a stronger acid than HSO4-.
C) NH3 is a weaker acid than NH2-.
D) NH3 is a weaker base than HSO4-.
E) NH3 is a weaker acid than HSO4-.
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35
Which of the following statements is true?
A) H2O is a weaker acid than NH3.
B) PH3 is a weaker acid than NH3.
C) OH- is a weaker base than H2O.
D) NH2- is the conjugate acid of NH3.
E) ClO- is a stronger base than ClO4-.
A) H2O is a weaker acid than NH3.
B) PH3 is a weaker acid than NH3.
C) OH- is a weaker base than H2O.
D) NH2- is the conjugate acid of NH3.
E) ClO- is a stronger base than ClO4-.
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36
The hydride ion, (H-), is a stronger base than the hydroxide ion, (OH-). The products of the reaction between H- (aq) and H2O(l) would be.
A) H2O(aq)
B) OH- (aq) + H2(g)
C) OH- (aq) + 2H+(aq)
D) H2O2(aq)
E) No reaction would occur.
A) H2O(aq)
B) OH- (aq) + H2(g)
C) OH- (aq) + 2H+(aq)
D) H2O2(aq)
E) No reaction would occur.
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37
Which of the following structural factors is primarily responsible for H2Se being a stronger acid than H2S?
A) bond polarity
B) size of the anion
C) electron withdrawing effect of oxygen
D) electric charge on the acid
E) sulfur has d electrons
A) bond polarity
B) size of the anion
C) electron withdrawing effect of oxygen
D) electric charge on the acid
E) sulfur has d electrons
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38
Which of the following is the best Lewis structure for carbonic acid (H2CO3)?
A)
B)
C)
D)
E)
A)

B)

C)

D)

E)

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39
Of the following, which is the strongest acid (lone pairs omitted for clarity)?
A)
B)
C)
D)
A)

B)

C)

D)

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40
Which of the following structural factors is primarily responsible for H2AsO4 - being a stronger acid than HAsO42 - ?
A) bond polarity
B) size of the anion
C) electron withdrawing effect of oxygen
D) electric charge on the acid
E) arsenic has d electrons
A) bond polarity
B) size of the anion
C) electron withdrawing effect of oxygen
D) electric charge on the acid
E) arsenic has d electrons
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41
Which of the following would you expect to be the strongest acid?
A) NH3
B) PH3
C) H2O
D) H2S
E) CH4
A) NH3
B) PH3
C) H2O
D) H2S
E) CH4
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42
Which of the following would be the weakest Brønsted acid?
A) H2Se
B) H2S
C) H2O
D) SH-
E) OH-
A) H2Se
B) H2S
C) H2O
D) SH-
E) OH-
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43
Which of the following would be the strongest Brønsted base?
A) HSO3-
B) HSO4-
C) H2SO3
D) SO32-
E) SO42-
A) HSO3-
B) HSO4-
C) H2SO3
D) SO32-
E) SO42-
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44
Which of the following would be the strongest Brønsted base?
A) H2O
B) SH-
C) OH-
D) S2-
E) O2-
A) H2O
B) SH-
C) OH-
D) S2-
E) O2-
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45
What is the pOH of a 0.025M solution of hydrobromic acid (Ka = 1 x 109)?
A) 0.025
B) 1.60
C) 12.40
D) 9.00
E) 5.00
A) 0.025
B) 1.60
C) 12.40
D) 9.00
E) 5.00
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46
What is the pH of a 0.0250 M HClO4 solution.
A) 2.50
B) -2.50
C) 1.60
D) 12.40
E) none of these
A) 2.50
B) -2.50
C) 1.60
D) 12.40
E) none of these
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47
Which of the following statements should be true for a 1.0x 10 - 4 M solution of a strong acid HBr?
A) [Br - ] >> [H3O+]
B) pH = 4.00
C) [HBr] = 1.0 x 10 - 4M
D) [Br - ] = [HBr]
E) pH = 1.00
A) [Br - ] >> [H3O+]
B) pH = 4.00
C) [HBr] = 1.0 x 10 - 4M
D) [Br - ] = [HBr]
E) pH = 1.00
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48
Which of the following statements is true for a 1.0 M solution of the strong acid HCl in water?
A) [Cl - ] > [H3O+]
B) The pH is 1.00
C) [H3O+] = 1.0 M
D) [HCl] = 1.0 M
E) [H3O+] = [OH - ]
A) [Cl - ] > [H3O+]
B) The pH is 1.00
C) [H3O+] = 1.0 M
D) [HCl] = 1.0 M
E) [H3O+] = [OH - ]
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49
Assume a solution is prepared by adding 1.0 x 10-3 moles of a weak monoprotic acid (Ka = 2.0 x 10-4) to enough water to give a liter of solution. If you want to compute the H3O+ ion concentration with an error of 5% or less, you can legitimately ignore:
A) both the contribution of the dissociation of water and the C term.
B) neither the dissociation of water nor the C term.
C) the dissociation of water but not the C term.
D) the C term but not the dissociation of water.
E) You can't compute the H3O+ concentration with an error of less than 5%.
A) both the contribution of the dissociation of water and the C term.
B) neither the dissociation of water nor the C term.
C) the dissociation of water but not the C term.
D) the C term but not the dissociation of water.
E) You can't compute the H3O+ concentration with an error of less than 5%.
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50
When 1.0 x 10-5 mole of HOCl (Ka = 3.5 x 10-8) is dissolved in pure water and diluted to 1.00 L, which assumption can't be applied in the calculation of the pH of this solution?
A) that the initial concentration of HOCl is much larger than the total H3O+ ion concentration
B) that the H3O+ ion concentration from the dissociation of water can be ignored.
C) that the total H3O+ ion concentration is the sum of the concentrations from the dissociation of HOCl and water
D) all of these assumptions are valid
E) none of these assumptions are valid
A) that the initial concentration of HOCl is much larger than the total H3O+ ion concentration
B) that the H3O+ ion concentration from the dissociation of water can be ignored.
C) that the total H3O+ ion concentration is the sum of the concentrations from the dissociation of HOCl and water
D) all of these assumptions are valid
E) none of these assumptions are valid
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51
For a particular weak acid, HA, in pure water, as the initial concentration of the weak acid increases, the acid-dissociation equilibrium constant of that acid should
A) increase.
B) decrease.
C) remain the same.
D) increase until the ionization of water can be neglected.
E) decrease until the ionization of water can be neglected.
A) increase.
B) decrease.
C) remain the same.
D) increase until the ionization of water can be neglected.
E) decrease until the ionization of water can be neglected.
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52
What would happen if more formic acid (HCO2H) was added to the following solution at equilibrium?
HCO2H(aq) + H2O(l)
H3O+(aq) + HCO2-(aq)
A) [H2O] should increase.
B) [H3O+] and [HCO2-] should both increase.
C) [H3O+] and [HCO2-] should both decrease.
D) [H3O+] should increase but [HCO2-] should decrease.
E) [H3O+] should decrease but [HCO2-] should increase.
HCO2H(aq) + H2O(l)
![<strong>What would happen if more formic acid (HCO<sub>2</sub>H) was added to the following solution at equilibrium? HCO<sub>2</sub>H(aq) + H<sub>2</sub>O(l) H<sub>3</sub>O<sup>+</sup>(aq) + HCO<sub>2</sub><sup>-</sup>(aq)</strong> A) [H<sub>2</sub>O] should increase. B) [H<sub>3</sub>O<sup>+</sup>] and [HCO<sub>2</sub><sup>-</sup>] should both increase. C) [H<sub>3</sub>O<sup>+</sup>] and [HCO<sub>2</sub><sup>-</sup>] should both decrease. D) [H<sub>3</sub>O<sup>+</sup>] should increase but [HCO<sub>2</sub><sup>-</sup>] should decrease. E) [H<sub>3</sub>O<sup>+</sup>] should decrease but [HCO<sub>2</sub><sup>-</sup>] should increase.](https://storage.examlex.com/TB9692/11ee9da3_9df0_ade8_9ff6_e3e6f1ad2e34_TB9692_11.jpg)
A) [H2O] should increase.
B) [H3O+] and [HCO2-] should both increase.
C) [H3O+] and [HCO2-] should both decrease.
D) [H3O+] should increase but [HCO2-] should decrease.
E) [H3O+] should decrease but [HCO2-] should increase.
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53
Which of the following equations is valid for a 0.10 M solution of formic acid, HCO2H?
HCO2H(aq) + H2O(l)
HCO2-(aq) + H3O+(aq) Ka = 1.8 x 10-4
A) [H3O+] < [OH-]
B) [H3O+] = [HCO2H]
C) [H3O+] = [HCO2-]
D) [H3O+] = [H2O]
E) [OH-] = [H2O]
HCO2H(aq) + H2O(l)
![<strong>Which of the following equations is valid for a 0.10 M solution of formic acid, HCO<sub>2</sub>H? HCO<sub>2</sub>H(aq) + H<sub>2</sub>O(l) HCO<sub>2</sub><sup>-</sup>(aq) + H<sub>3</sub>O<sup>+</sup>(aq) K<sub>a</sub> = 1.8 x 10<sup>-4</sup></strong> A) [H<sub>3</sub>O<sup>+</sup>] < [OH<sup>-</sup>] B) [H<sub>3</sub>O<sup>+</sup>]<sub> </sub>= [HCO<sub>2</sub>H] C) [H<sub>3</sub>O<sup>+</sup>]<sub> </sub>= [HCO<sub>2</sub><sup>-</sup>] D) [H<sub>3</sub>O<sup>+</sup>] = [H<sub>2</sub>O] E) [OH<sup>-</sup>] = [H<sub>2</sub>O]](https://storage.examlex.com/TB9692/11ee9da3_9df0_ade9_9ff6_9f249b101645_TB9692_11.jpg)
A) [H3O+] < [OH-]
B) [H3O+] = [HCO2H]
C) [H3O+] = [HCO2-]
D) [H3O+] = [H2O]
E) [OH-] = [H2O]
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54
Which of the following isn't true for the H3O+ ion concentration in a
0)0100 M solution of acetic acid (Ka = 1.8 x 10-5)?
A) It is less than the H3O+ concentration in an 0.0100 M solution of HCl.
B) It is equal to the OAc- ion concentration.
C) It is equal to the OH- ion concentration.
D) The pH of the solution is less than 7.0.
E) None of the above are true.
0)0100 M solution of acetic acid (Ka = 1.8 x 10-5)?
A) It is less than the H3O+ concentration in an 0.0100 M solution of HCl.
B) It is equal to the OAc- ion concentration.
C) It is equal to the OH- ion concentration.
D) The pH of the solution is less than 7.0.
E) None of the above are true.
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55
Calculate the approximate pH of a 0.10 M lactic acid solution.
(Ka = 8.4 x 10-4)
A) 2.0
B) 3.0
C) 4.0
D) 7.0
E) 12.0
(Ka = 8.4 x 10-4)
A) 2.0
B) 3.0
C) 4.0
D) 7.0
E) 12.0
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56
Calculate the approximate pH of a 0.100 M solution of formic acid (HCO2H) in water. (HCO2H: Ka = 1.8 x 10-4)
A) 2.4
B) 3.7
C) 4.7
D) 7
E) 11.6
A) 2.4
B) 3.7
C) 4.7
D) 7
E) 11.6
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57
Hydrogen peroxide has been used as a bleach to change hair color, as a disinfectant to treat wounds and as a rocket fuel. It is also a weak acid. Calculate the pH of a 0.018 M H2O2 solution. (H2O2: Ka = 2.2 x 10-12)
A) 0.6
B) 6.7
C) 7.3
D) 11.7
E) 13.4
A) 0.6
B) 6.7
C) 7.3
D) 11.7
E) 13.4
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58
A 0.10 M solution of a weak acid, HA, is found to be 1.50% ionized. Calculate Ka for this acid.
A) 1.5
B) 2.3 x 10-1
C) 2.3 x 10-5
D) 2.3 x 10-6
E) none of the above
A) 1.5
B) 2.3 x 10-1
C) 2.3 x 10-5
D) 2.3 x 10-6
E) none of the above
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59
A solution is prepared by dissolving 1.0 x 10-4 moles of HOBr in water and diluting to 1.00 L. What is the pH of this solution? (HOBr: Ka = 2 x 10-9)
A) 1.3
B) 5.3
C) 6.3
D) 8.7
E) 12.7
A) 1.3
B) 5.3
C) 6.3
D) 8.7
E) 12.7
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60
Which of the following groups contains salts that all form basic solutions in water?
A) NaNO3, NH4CN, NaOAc, NH4Cl
B) Na2CO3, KCl, NaOAc, NH4Cl
C) Na2CO3, NaF, NaOAc, NaCN
D) NaHCO3, NaF, NH4Cl, Na2SO3
E) none of the above
A) NaNO3, NH4CN, NaOAc, NH4Cl
B) Na2CO3, KCl, NaOAc, NH4Cl
C) Na2CO3, NaF, NaOAc, NaCN
D) NaHCO3, NaF, NH4Cl, Na2SO3
E) none of the above
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61
Which of the following compounds aren't acids in water?
(I) NH4Cl (II) HNO3 (III) NH3 (IV) HI (V) K2S
A) I and II
B) II and III
C) III and V
D) I, II and IV
E) all of the above are acids in water
(I) NH4Cl (II) HNO3 (III) NH3 (IV) HI (V) K2S
A) I and II
B) II and III
C) III and V
D) I, II and IV
E) all of the above are acids in water
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62
Kb for methylamine (CH3NH2) is the equilibrium constant for which reaction?
A) CH3NH2 + H2O
CH3NH- + H3O+
B) CH3NH2 + H2O
CH3NH3+ + OH-
C) CH3NH2 + H3O+
CH3NH3+ + H2O
D) CH3NH2 + OH-
CH3NH- + H2O
E) None of the above
A) CH3NH2 + H2O

B) CH3NH2 + H2O

C) CH3NH2 + H3O+

D) CH3NH2 + OH-

E) None of the above
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63
What is the Kb for methylamine (CH3NH2) if a 0.10 M solution of this weak base is 6.8% ionized?
A) 5.0 x 10-4
B) 0.068
C) 4.6 x 10-5
D) 2.0 x 103
E) 1.0
A) 5.0 x 10-4
B) 0.068
C) 4.6 x 10-5
D) 2.0 x 103
E) 1.0
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64
Which of the following won't produce an acidic solution when dissolved in water?
A) HF
B) NH4Cl
C) CH3CO2H
D) CH3CO2Na
E) HClO4
A) HF
B) NH4Cl
C) CH3CO2H
D) CH3CO2Na
E) HClO4
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65
Sodium fluoride, NaF (a soluble salt), is dissolved in water. Which one of the following correctly describes the relationships between the concentrations of the species present at equilibrium?
A) [ F- ] < [HF] and [Na+]
[ F- ]
B) [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Na+] and [H3O+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [F - ]
C) [ F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 0 [HF] and [Na+] < [ F - ]
D) [OH - ] < [HF] and [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [ F - ]
E) none of these
A) [ F- ] < [HF] and [Na+]
![<strong>Sodium fluoride, NaF (a soluble salt), is dissolved in water. Which one of the following correctly describes the relationships between the concentrations of the species present at equilibrium? </strong> A) [ F<sup>-</sup> ] < [HF] and [Na<sup>+</sup>] [ F<sup>-</sup> ] B) [F <sup>-</sup> ] [Na<sup>+</sup>] and [H<sub>3</sub>O<sup>+</sup>] [F <sup>-</sup> ] C) [ F <sup>-</sup> ] 0 [HF] and [Na<sup>+</sup>] < [ F <sup>-</sup> ] D) [OH <sup>-</sup> ] < [HF] and [Na<sup>+</sup>] [ F <sup>-</sup> ] E) none of these](https://storage.examlex.com/TB9692/11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11.jpg)
B) [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Na+] and [H3O+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [F - ]
C) [ F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 0 [HF] and [Na+] < [ F - ]
D) [OH - ] < [HF] and [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [ F - ]
E) none of these
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66
The salt NaF is dissolved in water. Which of the following relationships would be true for the species in solution?
A) [Na+]
[F - ] >> [HF] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+] >> [OH - ]
B) [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [F - ] >> [HF] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
C) [Na+] >> [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [HF] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
D) [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [HF] >> [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
E) none of these
A) [Na+]
![<strong>The salt NaF is dissolved in water. Which of the following relationships would be true for the species in solution?</strong> A) [Na<sup>+</sup>] [F <sup>-</sup> ] >> [HF] [H<sub>3</sub>O<sup>+</sup>] >> [OH <sup>-</sup> ] B) [Na<sup>+</sup>] [F <sup>-</sup> ] >> [HF] [OH <sup>-</sup> ] >> [H<sub>3</sub>O<sup>+</sup>] C) [Na<sup>+</sup>] >> [F <sup>-</sup> ] [HF] [OH <sup>-</sup> ] >> [H<sub>3</sub>O<sup>+</sup>] D) [Na<sup>+</sup>] [HF] >> [F <sup>-</sup> ] [OH <sup>-</sup> ] >> [H<sub>3</sub>O<sup>+</sup>] E) none of these](https://storage.examlex.com/TB9692/11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11.jpg)
B) [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [F - ] >> [HF] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
C) [Na+] >> [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [HF] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
D) [Na+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [HF] >> [F - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] >> [H3O+]
E) none of these
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67
When NH4Cl is dissolved in water the following species will be present: NH4+, Cl - OH - , H3O+, and NH3. Which of the following represents the correct relationship between the species in solution?
A) [NH4+]
[Cl - ] > [OH - ] > [NH3] > [H3O+]
B) [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+] > [OH - ]
C) [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] > [H3O+]
D) [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+]
E) [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OHF - ]
A) [NH4+]
![<strong>When NH<sub>4</sub>Cl is dissolved in water the following species will be present: NH<sub>4</sub><sup>+</sup>, Cl <sup>-</sup> OH <sup>-</sup> , H<sub>3</sub>O<sup>+</sup>, and NH<sub>3</sub>. Which of the following represents the correct relationship between the species in solution?</strong> A) [NH<sub>4</sub><sup>+</sup>] [Cl <sup>-</sup> ] > [OH <sup>-</sup> ] > [NH<sub>3</sub>] > [H<sub>3</sub>O<sup>+</sup>] B) [NH<sub>4</sub><sup>+</sup>] [Cl <sup>-</sup> ] > [NH<sub>3</sub>] [H<sub>3</sub>O<sup>+</sup>] > [OH <sup>-</sup> ] C) [NH<sub>4</sub><sup>+</sup>] [Cl <sup>-</sup> ] > [NH<sub>3</sub>] [OH <sup>-</sup> ] > [H<sub>3</sub>O<sup>+</sup>] D) [NH<sub>3</sub>] [OH <sup>-</sup> ] [Cl <sup>-</sup> ] > [NH<sub>4</sub><sup>+</sup>] [H<sub>3</sub>O<sup>+</sup>] E) [NH<sub>3</sub>] [H<sub>3</sub>O<sup>+</sup>] [Cl <sup>-</sup> ] > [NH<sub>4</sub><sup>+</sup>] [OHF <sup>-</sup> ]](https://storage.examlex.com/TB9692/11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11.jpg)
B) [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+] > [OH - ]
C) [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] > [H3O+]
D) [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OH - ] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+]
E) [NH3] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [H3O+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [Cl - ] > [NH4+] 11ee9f02_5f5c_eb1b_9fac_d5ba514ecb51_TB9692_11 [OHF - ]
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68
What is the value of Kb for the formate (HCO2-) ion if Ka for formic acid (HCO2H) is 1.8x10-4?
A) Kb = Kw x Ka
B) Kb = Ka/Kw
C) Kb = Kw/Ka
D) Kb = Kw + Ka
E) Kb = Kw - Ka
A) Kb = Kw x Ka
B) Kb = Ka/Kw
C) Kb = Kw/Ka
D) Kb = Kw + Ka
E) Kb = Kw - Ka
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69
The base-ionization constants for three bases, A(OH), B(OH), and C(OH), are 1.8 x 10-5, 4.4 x 10-4, and 7.4 x 10-4, respectively. Solutions of the bases having equal molarity have pH values that decrease in the following order:
A) A > B > C
B) B > C > A
C) C > B > A
D) A > C > B
E) B > A > C
A) A > B > C
B) B > C > A
C) C > B > A
D) A > C > B
E) B > A > C
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70
There are many ways of "fluoridating" water. One approach involves adding a salt of the fluoride ion, such as NaF. Calculate the pH of a 0.15 M NaF solution. (HF: Ka = 7.2 x 10-4)
A) 2
B) 5.8
C) 8.2
D) 10.9
E) 12
A) 2
B) 5.8
C) 8.2
D) 10.9
E) 12
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71
Ammonia and the ammonium ion form a conjugate acid-base pair.
NH3(aq) + H2O(l)
NH4+(aq) + OH-(aq)
Calculate the pH of 0.10 M NH3 if Ka for the NH4+ ion is 5.6 x 10-10.
A) 4.7
B) 5.1
C) 5.7
D) 8.9
E) 11.1
NH3(aq) + H2O(l)

Calculate the pH of 0.10 M NH3 if Ka for the NH4+ ion is 5.6 x 10-10.
A) 4.7
B) 5.1
C) 5.7
D) 8.9
E) 11.1
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72
Calculate the pH of a solution prepared by dissolving 1.00 x 10-2 moles of sodium hypochlorite (NaOCl) in enough water to produce a 1.00 L of solution. Hypochlorous acid is a weak monoprotic acid with Ka = 3.2 x 10-8.
A) 4.3
B) 4.7
C) 7.5
D) 9.3
E) 9.7
A) 4.3
B) 4.7
C) 7.5
D) 9.3
E) 9.7
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73
What is the OH- ion concentration in a 0.200 M NaOAc solution?
(HOAc: Ka = 1.8 x 10-5)
A) 1.1 x 10-10
B) 5.7 x 10-10
C) 1.8 x 10-6
D) 1.1 x 10-5
E) 1.3 x 10-3
(HOAc: Ka = 1.8 x 10-5)
A) 1.1 x 10-10
B) 5.7 x 10-10
C) 1.8 x 10-6
D) 1.1 x 10-5
E) 1.3 x 10-3
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74
What is the H3O+ ion concentration in a 0.10 M NH3 solution?
(Kb = 1.8 x 10-5)
A) 7.5 x 10-10
B) 3.0 x 10-10
C) 1.8 x 10-6
D) 1.3 x 10-3
E) none of these
(Kb = 1.8 x 10-5)
A) 7.5 x 10-10
B) 3.0 x 10-10
C) 1.8 x 10-6
D) 1.3 x 10-3
E) none of these
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75
HA is a weak monoprotic acid with Ka = 2.4 x 10-6. What is [OH-] in a 0.300 M solution of the salt, NaA?
A) 5.8 x 10-12
B) 2.4 x 10-10
C) 3.5 x 10-5
D) 6.5 x 10-5
E) 1.6 x 10-3
A) 5.8 x 10-12
B) 2.4 x 10-10
C) 3.5 x 10-5
D) 6.5 x 10-5
E) 1.6 x 10-3
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76
Which of the following solutions would have a pH greater than 7.0?
A) NH4Cl
B) NaCl
C) CH3COOH
D) CH3COONa
E) HCl
A) NH4Cl
B) NaCl
C) CH3COOH
D) CH3COONa
E) HCl
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77
Which of the following solutions has a pH greater than 7.0?
A) 0.10 M NH4Cl
B) 0.10 M NH4NO3
C) 0.10 M HCN
D) 0.10 M NaCN
E) none of these
A) 0.10 M NH4Cl
B) 0.10 M NH4NO3
C) 0.10 M HCN
D) 0.10 M NaCN
E) none of these
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78
Predict the products of the following acid-base reaction.
NH4Cl(aq) + NaSH(aq)
NH4Cl(aq) + NaSH(aq)

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79
Which of the following solutions has the highest pH?
A) 0.3 M Na2CO3
B) 1 M HOAc
C) 0.3 M NH4Cl
D) water
E) 10-3 M HCl
A) 0.3 M Na2CO3
B) 1 M HOAc
C) 0.3 M NH4Cl
D) water
E) 10-3 M HCl
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80
The addition of sodium formate (HCO2Na) to a solution containing formic acid (HCO2H: Ka = 1.8 x 10-4) will cause
A) the pH to increase.
B) the pH to decrease.
C) no change in pH.
D) a change in the pH, the direction of which cannot be predicted.
A) the pH to increase.
B) the pH to decrease.
C) no change in pH.
D) a change in the pH, the direction of which cannot be predicted.
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