Deck 9: Hydrocarbons: An Introduction to Organic Molecules
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Deck 9: Hydrocarbons: An Introduction to Organic Molecules
1
The following molecule contains two functional groups, a haloalkane group and an alkyne.
CH3-CHBr-CH=CH2
CH3-CHBr-CH=CH2
False
2
The following represents trans-2,3-dimethyl-2-pentene. 

False
3
Carbon atoms involved in double bonds exhibit a trigonal planar arrangement.
True
4
The two compounds shown below have the same molecular formula.
CH3-CH2-O-CH2-CH2-CH3 CH3-CH2-CH2-CH2-CH2-OH
CH3-CH2-O-CH2-CH2-CH3 CH3-CH2-CH2-CH2-CH2-OH
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5
The following compound is classified as an alkane. 

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6
One of the reasons that carbon forms such a large number of compounds is due its ability to form long chains and rings.
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7
How many hydrogen atoms would be needed to complete the following structure? 
A)6
B)7
C)9
D)10

A)6
B)7
C)9
D)10
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8
The following two substances would have the same physical properties. 

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9
The compound shown below is an isomer of 2,2-dimethylbutane. 

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10
The correct IUPAC name of the following compound is methylcyclohexane. 

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11
The two compounds shown below would be expected to exhibit similiar properties.
CH3-CH2-O-CH2-CH2-CH3 CH3-CH2-CH2-CH2-CH2-OH
CH3-CH2-O-CH2-CH2-CH3 CH3-CH2-CH2-CH2-CH2-OH
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12
The following compound contains four tetrahedrally arranged atoms. 

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13
The following compound would be classified as an: 
A)alkane
B)alkene
C)alkyne
D)aromatic

A)alkane
B)alkene
C)alkyne
D)aromatic
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14
The compound below is unlikely to exist. 

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15
In propyne, the arrangement of bonds around all of the carbon atoms is shown below. 

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16
The following structure illustrates a trans isomer. 

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17
Examine the structure shown below.
The compound is a hydrocarbon and an aromatic compound

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18
The line structure for
is shown below. 


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19
The structure for 2,2,3,3-tetramethylbutane is: 

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20
The following compound would be correctly classified as an alkyne. 

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21
What is the IUPAC name for compound represented below? 
A)isopropylbenzene
B)propylcyclohexane
C)propylbenzene
D)propylcyclohexene

A)isopropylbenzene
B)propylcyclohexane
C)propylbenzene
D)propylcyclohexene
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22
Of the compounds listed here, which one is not a constitutional isomer of the other three?
A)2,3-dimethylpentane
B)3-methylhexane
C)3-ethylpentane
D)2,2-dimethylbutane
A)2,3-dimethylpentane
B)3-methylhexane
C)3-ethylpentane
D)2,2-dimethylbutane
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23
Which of the following is(are) constitutional isomer(s) of hexane?
A)
B)
C)
D)both a and b
A)

B)

C)

D)both a and b
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24
Which of the following hydrocarbons is most likely to be a gas at room temperature?
A)butene
B)1-hexene
C)2-octene
D)4-decene
A)butene
B)1-hexene
C)2-octene
D)4-decene
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25
Consider the compounds given in the choices. Which would have the lowest melting point?
A)
B)
C)
D)All have about the same melting point.
A)

B)

C)

D)All have about the same melting point.
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26
A student named a particular compound 2-ethyl-3-methyl-2-butene. Assuming that the student's choice actually corresponded to the correct distribution of the double bond and the substituents, what is the correct IUPAC name for this compound?
A)2-ethyl-3-methyl-2-butene
B)3,4-dimethyl-3-pentene
C)2,3-dimethyl-2-pentene
D)2,3-dimethyl-1-pentene
A)2-ethyl-3-methyl-2-butene
B)3,4-dimethyl-3-pentene
C)2,3-dimethyl-2-pentene
D)2,3-dimethyl-1-pentene
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27
Which of the following line structures represents butane?
A)
B)
C)
D)
A)

B)

C)

D)

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28
Which of the following is probably soluble in water?
A)ethylbenzene
B)xylene
C)2,2-dimethylbenzene
D)All are insoluble in water.
A)ethylbenzene
B)xylene
C)2,2-dimethylbenzene
D)All are insoluble in water.
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29
The IUPAC name of the following contains an ethyl group located at position 
A)1.
B)2.
C)3.
D)4.

A)1.
B)2.
C)3.
D)4.
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30
Consider the structure of the compound shown below.
This compound is correctly characterized as:
A)branched alkane
B)saturated
C)aromatic
D)all of the above

A)branched alkane
B)saturated
C)aromatic
D)all of the above
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31
Which of the following line structures is 4-isopropyloctane?
A)
B)
C)
D)
A)

B)

C)

D)

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32
Which of the following is a correct structure for methylcyclopentane?
A)
B)
C)
D)All are correct representations.
A)

B)

C)

D)All are correct representations.
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33
Which of the following is a correct IUPAC name?
A)1-methylhexane
B)2-ethylhexane
C)3-propylhexane
D)None, they are all incorrect.
A)1-methylhexane
B)2-ethylhexane
C)3-propylhexane
D)None, they are all incorrect.
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34
What is the IUPAC name for the following alkane? 
A)2-ethylpropane
B)methylbutane
C)pentane
D)3,3-dimethylpropane

A)2-ethylpropane
B)methylbutane
C)pentane
D)3,3-dimethylpropane
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35
What must be the name for the missing hydrocarbon in the following combustion reaction? _______ + 3 O2 → 2 CO2 + 2 H2O
A)ethane
B)ethene
C)ethyne
D)More than one hydrocarbon is possible.
A)ethane
B)ethene
C)ethyne
D)More than one hydrocarbon is possible.
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36
What is line bond formula for the following full structural formula? 
A)
B)
C)
D)

A)

B)

C)

D)

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37
Give the IUPAC name for the following 
A)3,6-diethyl 3-methylnonane
B)2,2,5,6-tetraethylhexane
C)2,2,5-triethyloctane
D)none are correct

A)3,6-diethyl 3-methylnonane
B)2,2,5,6-tetraethylhexane
C)2,2,5-triethyloctane
D)none are correct
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38
Which of the following would show the most similar chemical behavior to 1-butanol, which is shown below? CH3CH2CH2CH2-OH
A)
B)
C)
D)
A)

B)

C)

D)

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39
Given the structure below, what is the IUPAC name for the compound? 
A)2,5-dimethyl-3-heptyne
B)5-ethyl-2-methyl-3-hexyne
C)3,7-dimethyl-4-heptyne
D)1,1,5-trimethyl-2-hexyne

A)2,5-dimethyl-3-heptyne
B)5-ethyl-2-methyl-3-hexyne
C)3,7-dimethyl-4-heptyne
D)1,1,5-trimethyl-2-hexyne
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40
Which of the following is could not be used to represent the same compound?
A)
B)CH3-CH2-CH2-CH2-CH3
C)C5H12
D)All could represent the same compound.
A)

B)CH3-CH2-CH2-CH2-CH3
C)C5H12
D)All could represent the same compound.
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41
Examine the following structures.
Fill in the blanks with the appropriate letter (A,B,C,....).
The balanced equation for the combustion of structure _______________________ would required the largest coefficient for O2.

The balanced equation for the combustion of structure _______________________ would required the largest coefficient for O2.
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42
Consider the following structures.
Fill in the blanks with the appropriate letters (A,B,C,or D).
Structure C is identical to Structure _____________________.

Structure C is identical to Structure _____________________.
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43
Consider the following structure.
This substance would be classified as a(n)
A)alkane.
B)alkene.
C)alkyne.
D)aromatic hydrocarbon.
E)cycloalkane.

A)alkane.
B)alkene.
C)alkyne.
D)aromatic hydrocarbon.
E)cycloalkane.
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44
Consider the following molecules.
Fill in the blanks with the appropriate terms from the list below.
alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure B is classified as a(n) _________________________.

alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure B is classified as a(n) _________________________.
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45
Consider the following molecules.
Fill in the blanks with the appropriate terms from the list below.
alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure C is classified as a(n) _________________________.

alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure C is classified as a(n) _________________________.
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46
Consider the following structures.
Fill in the blanks with the appropriate letters (A,B,C,or D).
Structure ______________________ is a stereoisomer of cis-2-hexene.

Structure ______________________ is a stereoisomer of cis-2-hexene.
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47
Consider the following molecule of the birth control drug known as RU 486.
Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the circle is a(n)_____________________.

Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the circle is a(n)_____________________.

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48
Consider the following structure.
What is the relationship to the structure given below?
CH3-CH2-CH2-CH=CH-CH2-CH2-CH3
A)constitutional isomers.
B)cis-trans isomers.
C)same compound.
D)cycloalkane.
E)different compound.

CH3-CH2-CH2-CH=CH-CH2-CH2-CH3
A)constitutional isomers.
B)cis-trans isomers.
C)same compound.
D)cycloalkane.
E)different compound.
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49
Consider the following molecule of the birth control drug known as RU 486.
Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the oval is a(n)_________________________.

Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the oval is a(n)_________________________.

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50
Consider the following molecule of the birth control drug known as RU 486.
Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the triangle is a(n)_____________________.

Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the triangle is a(n)_____________________.

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51
Which of the following is the appropriate ending for the name of an alkane?
A)ane
B)ene
C)benzene
D)yne
A)ane
B)ene
C)benzene
D)yne
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52
Examine the following structures.
Fill in the blanks with the appropriate letter (A,B,C,....).
Structure ____________________ will have the lowest melting point.

Structure ____________________ will have the lowest melting point.
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53
Consider the following structures.
Fill in the blanks with the appropriate letters (A,B,C,or D).
Structure A is a constitutional isomer of Structure _____________________.

Structure A is a constitutional isomer of Structure _____________________.
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54
Consider the formula given below. C4H8
This following represents the molecular formula of an
A)alkyne
B)alkene
C)alkane
D)none of these
This following represents the molecular formula of an
A)alkyne
B)alkene
C)alkane
D)none of these
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55
Consider the following molecule of the birth control drug known as RU 486.
Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the square is a(n)_________________________.

Fill in the blanks with the appropriate term from the list below.
alkane
cycloalkane
alkene
cycloalkene
alkyne
aromatic
haloalkane
The functional group enclosed in the square is a(n)_________________________.

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56
Consider the following molecules.
Fill in the blanks with the appropriate terms from the list below.
alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure D is classified as a(n) _________________________.

alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure D is classified as a(n) _________________________.
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57
What is the name of a branch on the principal carbon chain that contains three carbon atoms?
A)pentyl
B)propyl
C)ethyl
D)methyl
A)pentyl
B)propyl
C)ethyl
D)methyl
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58
Examine the following structures.
Fill in the blanks with the appropriate letter (A,B,C,....).
Structure ______________________is most likely to be least reactive.

Structure ______________________is most likely to be least reactive.
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59
Consider the following structure.
What is the relationship to the name given below?
2,3-dimethylhexane
A)constitutional isomers
B)cis-trans isomers
C)same compound
D)cycloalkane
E)diffferent compound

2,3-dimethylhexane
A)constitutional isomers
B)cis-trans isomers
C)same compound
D)cycloalkane
E)diffferent compound
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60
Consider the following molecules.
Fill in the blanks with the appropriate terms from the list below.
alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure A is classified as a(n) _________________________.

alkane
cycloalkane
alkene
alkyne
aromatic compound
Structure A is classified as a(n) _________________________.
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61
What is the name of the following compound? 

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62
During the complete combustion of benzene, if 9.55 g of benzene were consumed what mass of oxygen in grams would be needed?
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63
Draw the condensed structural formula of 3-ethyl-3-methylhexane.
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64
Examine the following structure.
Complete the following statements about this structure.
If the hydrogen atom numbered "1" replaced by a methyl group, the IUPAC name of the new compound would be ____________.

If the hydrogen atom numbered "1" replaced by a methyl group, the IUPAC name of the new compound would be ____________.
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65
Examine the following structure.
Complete the following statements about this structure.
The IUPAC name for this substance is____________.

The IUPAC name for this substance is____________.
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66
What is the condensed structural formula for the following substance?


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67
What is the molecular formula for the following substance? 

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68
Examine the following structures.
Fill in the blanks with the appropriate letter (A,B,C,....).
Structure ______________________ would have chemical and physical properties closest to that of 2-hexene.

Structure ______________________ would have chemical and physical properties closest to that of 2-hexene.
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69
Examine the following structure.
Complete the following statements about this structure.
The arrangement of atoms about each of the carbon atoms is a ____________.

The arrangement of atoms about each of the carbon atoms is a ____________.
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70
Examine the following structure.
Complete the following statements about this structure.
If all three numbered hydrogen atoms were replaced by a methyl group, the IUPAC name of the new compound would be ____________.

If all three numbered hydrogen atoms were replaced by a methyl group, the IUPAC name of the new compound would be ____________.
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71
Using molecular formula, write the balance equation for the complete combustion of benzene.
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72
Examine the following structure.
Complete the following statements about this structure.
If the hydrogen atom numbered "2" replaced by a methyl group, the IUPAC name of the new compound would be ____________.

If the hydrogen atom numbered "2" replaced by a methyl group, the IUPAC name of the new compound would be ____________.
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