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Calculate E°cell and Indicate Whether the Overall Reaction Shown Is

Question 31

Multiple Choice

Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. Co3+(aq) + e-
Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. Co<sup>3+</sup>(aq)  + e<sup>-</sup> <sup> </sup>   Co<sup>2+</sup>(aq)  E° = 1.82 V MnO<sub>4</sub><sup>-</sup>(aq)  + 2H<sub>2</sub>O(l)  + 3e<sup>-</sup> MnO<sub>2</sub>(s)  + 4OH<sup>-</sup>(aq)  E° = 0.59 V Overall reaction: MnO<sub>4</sub><sup>-</sup>(aq)  + 2H<sub>2</sub>O(l)  + 3Co<sup>2+</sup>(aq)  → MnO<sub>2</sub>(s)  + 3Co<sup>3+</sup>(aq)  + 4OH<sup>-</sup>(aq)  A)  E°<sub> cell</sub> = -1.23 V, spontaneous B)  E°<sub> cell</sub> = -1.23 V, nonspontaneous C)  E°<sub> cell</sub> = 1.23 V, spontaneous D)  E°<sub> cell</sub> = 1.23 V, nonspontaneous E)  E°<sub> cell</sub> = -0.05 V, nonspontaneous Co2+(aq) E° = 1.82 V
MnO4-(aq) + 2H2O(l) + 3e- MnO2(s) + 4OH-(aq) E° = 0.59 V
Overall reaction:
MnO4-(aq) + 2H2O(l) + 3Co2+(aq) → MnO2(s) + 3Co3+(aq) + 4OH-(aq)


A) E° cell = -1.23 V, spontaneous
B) E° cell = -1.23 V, nonspontaneous
C) E° cell = 1.23 V, spontaneous
D) E° cell = 1.23 V, nonspontaneous
E) E° cell = -0.05 V, nonspontaneous

Correct Answer:

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