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Question 55

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A solution contains 0.021 mol L-1 Cl⁻ and 0.017 mol L-1 I⁻. A solution containing copper(I) ions is added to selectively precipitate one of the ions. At what concentration of copper(I) ion will a precipitate begin to form? What is the identity of the precipitate? Ksp(CuCl) = 1.0 × 10-6, Ksp(CuI) = 5.1 × 10-12.


A) 3.0 × 10-10 mol L-1, CuI
B) 3.0 × 10-10 mol L-1, CuCl
C) 4.8 × 10-5 mol L-1, CuCl
D) 4.8 × 10-5 mol L-1, CuI
E) 3.0 × 10-5 mol L-1, both CuCl and CuI are in the precipitate

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