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Consider Two Complexes: (I) [Fe(CN)6]4-, and (II) [Fe(H2O)6]2+

Question 81

Multiple Choice

Consider two complexes: (I) [Fe(CN) 6]4-, and (II) [Fe(H2O) 6]2+. In view of the spectrochemical series, which one of the following sets of predictions is most likely correct?
Spectrochemical Series
I- < Br - < Cl- < F- < OH- < H2O < NH3 < NO2- < CN- < CO


A) I is low spin, II is high spin, and II absorbs light at the shorter wavelength.
B) I is low spin, II is high spin, and I absorbs light at the shorter wavelength.
C) I is high spin, II is low spin, and I absorbs light at the shorter wavelength.
D) Both have 6 d electrons, so both are high spin.
E) Both have 6 d electrons, so both are low spin.

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