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    Chemistry Study Set 2
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    Exam 17: Metal Ions: Colorful and Essential
  5. Question
    Explain Why Ni(CN)<sub>4</sub><sup>2</sup><sup>-</Sup> Is Diamagnetic and NiCl<sub>4</sub><sup>2</sup><sup>-</Sup> Is Paramagnetic in Terms
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Explain Why Ni(CN)42- Is Diamagnetic and NiCl42- Is Paramagnetic in Terms

Question 69

Question 69

Essay

Explain why Ni(CN)42- is diamagnetic and NiCl42- is paramagnetic in terms of the possible geometries (tetrahedral and square planar) and the magnitudes of the crystal field splitting?

Correct Answer:

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Ni2+ has 8 d electrons in both complex ion...

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