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The Data Below Were Determined for the Reaction Shown Below \rarr

Question 66

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The data below were determined for the reaction shown below.S2O82- + 3I - (aq) \rarr 2SO42- + I3-

 Expt. # [S2O82][I] Initial Rate 10.0380.0601.4×105M/s20.0760.0602.8×105M/s30.0760.0301.4×105M/s\begin{array}{lccc}\text { Expt. \# } & \left[\mathrm{S}_{2-} \mathrm{O}_{8}{ }^{2}\right] & {[I-]} & \text { Initial Rate } \\\hline 1 & 0.038 & 0.060 & 1.4 \times 10^{-5} \mathrm{M} / \mathrm{s} \\2 & 0.076 & 0.060 & 2.8 \times 10^{-5} \mathrm{M} / \mathrm{s} \\3 & 0.076 & 0.030 & 1.4 \times 10^{-5} \mathrm{M} / \mathrm{s}\end{array} The rate law for this reaction must be:


A) rate = k[S2O82- ][I -]3
B) rate = k[S2O82-]
C) rate = k[S2O82-]2[I -]2
D) rate = k[I -]
E) rate = k[S2O82-][I -]

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