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Biselyngbyolide a Is a Cytotoxic Natural Product That Shows Promise

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Biselyngbyolide A is a cytotoxic natural product that shows promise for the treatment of bone lytic diseases. Shown below is a recent synthesis of this molecule (Org. Lett. 2014, 16, 2858). Give the structure of intermediate 1 and Biselyngbyolide
A. Hint: PPTS is a strong organic acid. Biselyngbyolide A is a cytotoxic natural product that shows promise for the treatment of bone lytic diseases. Shown below is a recent synthesis of this molecule (Org. Lett. 2014, 16, 2858). Give the structure of intermediate 1 and Biselyngbyolide A. Hint: PPTS is a strong organic acid. Biselyngbyolide A is a cytotoxic natural product that shows promise for the treatment of bone lytic diseases. Shown below is a recent synthesis of this molecule (Org. Lett. 2014, 16, 2858). Give the structure of intermediate 1 and Biselyngbyolide A. Hint: PPTS is a strong organic acid.

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The first step is an intramole...

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