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For Which of the Following Reactions Would the Transition State \rightarrow

Question 15

Multiple Choice

For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH3) 2CH-H CH3CH2CH2-H H-F
(413 kJ mol-1) (423 kJ mol-1) (570 kJ mol-1)
H-Cl H-Br
(432 kJ mol-1) (366 kJ mol-1)


A)
 For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH<sub>3</sub>) <sub>2</sub>CH-H CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>-H H-F (413 kJ mol<sup>-1</sup>)  (423 kJ mol<sup>-1</sup>)  (570 kJ mol<sup>-1</sup>)  H-Cl H-Br (432 kJ mol<sup>-1</sup>)  (366 kJ mol<sup>-1</sup>)  A)    B)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + F·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HF C)    D)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Cl·  \rightarrow  CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HCl E)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Br·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HBr
B) CH3CH2CH3 + F· \rightarrow CH3CH2CH2· + HF
C)
 For which of the following reactions would the transition state most resemble the products? The following bond dissociation energies may be useful. (CH<sub>3</sub>) <sub>2</sub>CH-H CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>-H H-F (413 kJ mol<sup>-1</sup>)  (423 kJ mol<sup>-1</sup>)  (570 kJ mol<sup>-1</sup>)  H-Cl H-Br (432 kJ mol<sup>-1</sup>)  (366 kJ mol<sup>-1</sup>)  A)    B)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + F·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HF C)    D)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Cl·  \rightarrow  CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HCl E)  CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub> + Br·  \rightarrow CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>· + HBr
D) CH3CH2CH3 + Cl· \rightarrow CH3CH2CH2· + HCl
E) CH3CH2CH3 + Br· \rightarrow CH3CH2CH2· + HBr

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