Deck 15: Aqueous Equilibria: Acids and Bases
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Deck 15: Aqueous Equilibria: Acids and Bases
1
Identify the conjugate acid/base pairs present in an aqueous solution of hydrogen sulfate ion,HSO4-.
A)HSO4-/SO42- and H3O+/H2O
B)H2SO4/HSO4- and H2O/OH-
C)HSO4-/H2O and H3O+/SO42-
D)HSO4-/H2O and H2SO4/OH-
A)HSO4-/SO42- and H3O+/H2O
B)H2SO4/HSO4- and H2O/OH-
C)HSO4-/H2O and H3O+/SO42-
D)HSO4-/H2O and H2SO4/OH-
HSO4-/SO42- and H3O+/H2O
2
Using the conjugate acid-base pairs listed below,complete the following equation with the pair that gives an equilibrium constant Kc > 1. ________ + H2CO3 ⇌ ________ + HCO3-
A)HF/F-
B)HCl/Cl-
C)HOCl/OCl-
D)HSO42-/SO42-
A)HF/F-
B)HCl/Cl-
C)HOCl/OCl-
D)HSO42-/SO42-
HOCl/OCl-
3
From the following chemical reactions determine the relative Br∅nsted-Lowry base strengths (strongest to weakest). HNO3(aq)+ H2O(l)→ H3O+(aq)+ NO3-(aq)
HF(aq)+ H2O(l)⇌ H3O+(aq)+ F-(aq)
A)HNO3 > H3O+ > HF
B)NO3- > H2O > F-
C)F- > H2O > NO3-
D)F- > NO3- > H2O
HF(aq)+ H2O(l)⇌ H3O+(aq)+ F-(aq)
A)HNO3 > H3O+ > HF
B)NO3- > H2O > F-
C)F- > H2O > NO3-
D)F- > NO3- > H2O
F- > H2O > NO3-
4
Which of the following Br∅nsted-Lowry acids does not behave as a strong acid when it is dissolved in water?
A)HBr
B)HCl
C)HNO2
D)HClO4
A)HBr
B)HCl
C)HNO2
D)HClO4
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5
When dissolved in water,which of the following compounds is an Arrhenius acid?
A)HCN
B)NaOH
C)NaF
D)CH3CH2OH
A)HCN
B)NaOH
C)NaF
D)CH3CH2OH
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6
What are the Br∅nsted-Lowry bases in the following chemical reaction? C5H5N(aq)+ H2O(l)⇌ C5H5NH+(aq)+ OH-(aq)
A)C5H5N,H2O
B)C5H5N,C5H5NH+
C)C5H5N,OH-
D)C5H5N,H2O,OH-
A)C5H5N,H2O
B)C5H5N,C5H5NH+
C)C5H5N,OH-
D)C5H5N,H2O,OH-
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7
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest). HClO4(sol)+ CH3COOH(l)→ CH3C2(OH)2+(sol)+ ClO4-(aq)
H2SO4(sol)+ CH3COOH(l)⇌ CH3C(OH)2+(sol)+ HSO4-(sol)
A)HClO4 > H2SO4 > CH3COOH
B)HClO4 > H2SO4 > CH3C(OH)2+
C)HClO4 > CH3COOH > H2SO4
D)HClO4 > CH3C(OH)2+ > H2SO4
H2SO4(sol)+ CH3COOH(l)⇌ CH3C(OH)2+(sol)+ HSO4-(sol)
A)HClO4 > H2SO4 > CH3COOH
B)HClO4 > H2SO4 > CH3C(OH)2+
C)HClO4 > CH3COOH > H2SO4
D)HClO4 > CH3C(OH)2+ > H2SO4
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8
What are the Br∅nsted-Lowry acids in the following chemical reaction? HBr(sol)+ CH3COOH(sol)⇌ CH3C(OH)2+(sol)+ Br-(sol)
A)HBr,CH3COOH
B)HBr,CH3C(OH)2+
C)CH3COOH,CH3C(OH)2+
D)CH3COOH,Br-
A)HBr,CH3COOH
B)HBr,CH3C(OH)2+
C)CH3COOH,CH3C(OH)2+
D)CH3COOH,Br-
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9
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest). HClO4(aq)+ H2O(l)→ H3O+(aq)+ ClO4-(aq)
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq)
A)HClO4 > H3O+ > HNO2
B)HClO4 > HNO2 > H3O+
C)H3O+ > HClO4 > HNO2
D)H3O+ > HNO2 > HClO4
HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq)
A)HClO4 > H3O+ > HNO2
B)HClO4 > HNO2 > H3O+
C)H3O+ > HClO4 > HNO2
D)H3O+ > HNO2 > HClO4
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10
Arrange the acids in order of increasing acid strength.
A)D < C < A < B
B)D < C < B < A
C)D < B < A < C
D)D < A < C < B
A)D < C < A < B
B)D < C < B < A
C)D < B < A < C
D)D < A < C < B
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11
What is the conjugate acid of the Br∅nsted-Lowry base HAsO42-?
A)H2AsO4-
B)AsO43-
C)H2O
D)H3O+
A)H2AsO4-
B)AsO43-
C)H2O
D)H3O+
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12
Write a balanced equation for the dissociation of the Br∅nsted-Lowry acid HSO4- in water.
A)HSO4-(aq)+ H2O(l)⇌ H2SO4(aq)+ OH-(aq)
B)HSO4-(aq)+ H2O(l)⇌ SO42-(aq)+ H3O+(aq)
C)HSO4-(aq)+ H2O(l)⇌ SO32-(aq)+ OH-(aq)
D)HSO4-(aq)+ H2O(l)⇌ SO3(g)+ OH-(aq)+ H2O(l)
A)HSO4-(aq)+ H2O(l)⇌ H2SO4(aq)+ OH-(aq)
B)HSO4-(aq)+ H2O(l)⇌ SO42-(aq)+ H3O+(aq)
C)HSO4-(aq)+ H2O(l)⇌ SO32-(aq)+ OH-(aq)
D)HSO4-(aq)+ H2O(l)⇌ SO3(g)+ OH-(aq)+ H2O(l)
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13
From the following chemical reactions determine the relative Br∅nsted-Lowry base strengths (strongest to weakest). 2 NaH(s)+ H2O(l)→ 2 NaOH + H2(g)
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)H- > OH- > NH3
B)H- > NH3 > OH-
C)OH-> H- > NH3
D)OH- > NH3 > H-
NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)H- > OH- > NH3
B)H- > NH3 > OH-
C)OH-> H- > NH3
D)OH- > NH3 > H-
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14
From the following chemical reactions determine the relative Br∅nsted-Lowry acid strengths (strongest to weakest). HCl(aq)+ H2O(l)→ H3O+(aq)+ Cl-(aq)
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCl > HCN > H3O+
B)HCl > H3O+ > HCN
C)H3O+ > HCl > HCN
D)HCN > H3O+ > HCl
HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq)
A)HCl > HCN > H3O+
B)HCl > H3O+ > HCN
C)H3O+ > HCl > HCN
D)HCN > H3O+ > HCl
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15
What is the conjugate base of the Br∅nsted-Lowry acid HPO42-?
A)H3PO4
B)H2PO4-
C)HPO42-
D)PO43-
A)H3PO4
B)H2PO4-
C)HPO42-
D)PO43-
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16
The following pictures represent aqueous solutions of binary acids of the type HA where the water molecules have been omitted for clarity. 
Determine the strongest acid of the set.
A)A
B)B
C)C
D)D

Determine the strongest acid of the set.
A)A
B)B
C)C
D)D
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17
What are the conjugate acid-base pairs in the following chemical reaction? NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq)
A)NH3,H2O and NH4+,OH-
B)NH3,NH4+ and H2O,OH-
C)NH3,OH- and H2O,NH4+
D)NH3 and NH4+
A)NH3,H2O and NH4+,OH-
B)NH3,NH4+ and H2O,OH-
C)NH3,OH- and H2O,NH4+
D)NH3 and NH4+
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18
What is the strongest Br∅nsted-Lowry acid in the chemical reaction shown below? 2 HNO3(aq)+ Ba(OH)2(aq)→ Ba(NO3)2(aq)+ 2 H2O(l)
A)HNO3
B)Ba(OH)2
C)Ba(NO3)2
D)H2O
A)HNO3
B)Ba(OH)2
C)Ba(NO3)2
D)H2O
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19
The equilibrium constant,K,for the reaction shown below has a value 1.8 × 10-5.In this reaction which is the strongest acid and which is the strongest base? CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq)
A)CH3CO2H and CH3CO2-
B)CH3CO2H and H2O
C)H3O+ and H2O
D)H3O+ and CH3CO2-
A)CH3CO2H and CH3CO2-
B)CH3CO2H and H2O
C)H3O+ and H2O
D)H3O+ and CH3CO2-
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20
Using the conjugate acid-base pairs listed below,complete the following equation with the pair that gives an equilibrium constant Kc > 1. ________ + HSO3- ⇌ ________ + H2SO3
A)CH3CO2H/ CH3CO2-
B)HCO2H/ HCO2-
C)HNO2/NO2-
D)HNO3/NO3-
A)CH3CO2H/ CH3CO2-
B)HCO2H/ HCO2-
C)HNO2/NO2-
D)HNO3/NO3-
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21
What is the strongest acid of the following?
A)HOI
B)HOBr
C)HOCl
D)All are equivalent.
A)HOI
B)HOBr
C)HOCl
D)All are equivalent.
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22
Calculate the pH for an aqueous solution of pyridine that contains 2.15 × 10-4 M hydroxide ion.
A)4.65 × 10-11
B)2.15 × 10-4
C)3.67
D)10.33
A)4.65 × 10-11
B)2.15 × 10-4
C)3.67
D)10.33
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23
An acidic solution at 25°C has
A)[H3O+] > [OH-] > 1 × 10-7 M.
B)[H3O+] > 1 × 10-7 M > [OH-].
C)[H3O+] = [OH-] > 1 × 10-7 M.
D)[H3O+] < 1 × 10-7 M > [OH-].
A)[H3O+] > [OH-] > 1 × 10-7 M.
B)[H3O+] > 1 × 10-7 M > [OH-].
C)[H3O+] = [OH-] > 1 × 10-7 M.
D)[H3O+] < 1 × 10-7 M > [OH-].
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24
What is the weakest acid among the following?
A)SiH4
B)PH3
C)H2S
D)HCl
A)SiH4
B)PH3
C)H2S
D)HCl
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25
What is the hydronium ion concentration of an acid rain sample that has a pH of 3.15?
A)1.41 × 10-11 M
B)7.08 × 10-4 M
C)3.15 M
D)10.85 M
A)1.41 × 10-11 M
B)7.08 × 10-4 M
C)3.15 M
D)10.85 M
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26
Calculate the pH for an aqueous solution of acetic acid that contains 2.15 × 10-3 M hydronium ion.
A)4.65 × 10-12
B)2.15 × 10-3
C)2.67
D)11.33
A)4.65 × 10-12
B)2.15 × 10-3
C)2.67
D)11.33
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27
If the ionization constant of water,Kw,at 40°C is 2.92 × 10-14,then what is the hydronium ion concentration and pH for an acidic solution?
A)[H3O+] > 1.71 × 10-7 M and pH > 6.77
B)[H3O+] > 1.71 × 10-7 M and pH < 6.77
C)[H3O+] < 1.71 × 10-7 M and pH > 6.77
D)[H3O+] < 1.71 × 10-7 M and pH < 6.77
A)[H3O+] > 1.71 × 10-7 M and pH > 6.77
B)[H3O+] > 1.71 × 10-7 M and pH < 6.77
C)[H3O+] < 1.71 × 10-7 M and pH > 6.77
D)[H3O+] < 1.71 × 10-7 M and pH < 6.77
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28
What is the strongest acid among the following?
A)H2O
B)H2S
C)H2Se
D)H2Te
A)H2O
B)H2S
C)H2Se
D)H2Te
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29
If the ionization constant of water,Kw,at 40°C is 2.92 × 10-14,then what is the hydronium ion concentration for a neutral solution?
A)[H3O+] < 1.00 × 10-7 M
B)[H3O+] > 1.71 × 10-7 M
C)[H3O+] = 1.71 × 10-7 M
D)[H3O+] < 1.71 × 10-7 M
A)[H3O+] < 1.00 × 10-7 M
B)[H3O+] > 1.71 × 10-7 M
C)[H3O+] = 1.71 × 10-7 M
D)[H3O+] < 1.71 × 10-7 M
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30
Human tears have a concentration of H3O+ that is 3.16 × 10-8.The concentration of OH- in human tears is
A)greater than 3.16 × 10-7 and tears are acidic.
B)greater than 3.16 ×10-7 and tears are basic.
C)less than 3.16 × 10-7 and tears are acidic.
D)less than 3.16 × 10-7 and tears are basic.
A)greater than 3.16 × 10-7 and tears are acidic.
B)greater than 3.16 ×10-7 and tears are basic.
C)less than 3.16 × 10-7 and tears are acidic.
D)less than 3.16 × 10-7 and tears are basic.
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31
Calculate the hydroxide ion concentration in an aqueous solution that contains 3.50 × 10-3 M in hydronium ion.
A)2.86 × 10-4 M
B)2.86 × 10-11 M
C)2.86 × 10-12 M
D)3.50 × 10-12 M
A)2.86 × 10-4 M
B)2.86 × 10-11 M
C)2.86 × 10-12 M
D)3.50 × 10-12 M
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32
A solution with a hydrogen ion concentration of 3.25 × 10-2 M is ________ and has a hydroxide concentration of ________.
A)acidic,3.08 × 10-12 M
B)acidic,3.08 × 10-13 M
C)basic,3.08 × 10-12 M
D)basic,3.08 × 10-13 M
A)acidic,3.08 × 10-12 M
B)acidic,3.08 × 10-13 M
C)basic,3.08 × 10-12 M
D)basic,3.08 × 10-13 M
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33
Calculate the hydronium ion concentration in an aqueous solution that contains 2.50 × 10-4 M in hydroxide ion.
A)4.00 × 10-9 M
B)4.00 × 10-10 M
C)4.00 × 10-11 M
D)5.00 × 10-11 M
A)4.00 × 10-9 M
B)4.00 × 10-10 M
C)4.00 × 10-11 M
D)5.00 × 10-11 M
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34
What is the strongest acid among the following?
A)HF
B)HCl
C)HBr
D)HI
A)HF
B)HCl
C)HBr
D)HI
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35
At 50°C the value of Kw is 5.5 × 10-14.A basic solution at 50°C has
A)[H3O+] < [OH-] < 2 × 10-7 M.
B)[H3O+] < 2 × 10-7 M < [OH-].
C)[H3O+] = [OH-] < 2 × 10-7 M.
D)[H3O+] > 2 × 10-7 M < [OH-].
A)[H3O+] < [OH-] < 2 × 10-7 M.
B)[H3O+] < 2 × 10-7 M < [OH-].
C)[H3O+] = [OH-] < 2 × 10-7 M.
D)[H3O+] > 2 × 10-7 M < [OH-].
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36
What is the hydronium ion concentration and the pH for an aqueous solution of NH3 that has a hydroxide ion concentration of 2.25 × 10-3 M?
A)4.44 × 10-11 M,3.65
B)4.44 × 10-11 M,10.35
C)4.44 × 10-12 M,2.65
D)4.44 × 10-12 M,11.35
A)4.44 × 10-11 M,3.65
B)4.44 × 10-11 M,10.35
C)4.44 × 10-12 M,2.65
D)4.44 × 10-12 M,11.35
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37
Which of the following should have the lowest bond strength?
A)HOI
B)HOCl
C)HOAt
D)HOBr
A)HOI
B)HOCl
C)HOAt
D)HOBr
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38
An acidic solution at 25°C will have a hydronium ion concentration ________ and a pH value ________.
A)[H3O+] > 1 × 10-7 M,pH > 7.00
B)[H3O+] > 1 × 10-7 M,pH < 7.00
C)[H3O+] < 1 × 10-7 M,pH > 7.00
D)[H3O+] < 1 × 10-7 M,pH < 7.00
A)[H3O+] > 1 × 10-7 M,pH > 7.00
B)[H3O+] > 1 × 10-7 M,pH < 7.00
C)[H3O+] < 1 × 10-7 M,pH > 7.00
D)[H3O+] < 1 × 10-7 M,pH < 7.00
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39
A solution with a hydroxide ion concentration of 4.15 × 10-4 M is ________ and has a hydrogen ion concentration of ________.
A)acidic,2.41 × 10-10 M
B)acidic,2.41 × 10-11 M
C)basic,2.41 × 10-10 M
D)basic,2.41 × 10-11 M
A)acidic,2.41 × 10-10 M
B)acidic,2.41 × 10-11 M
C)basic,2.41 × 10-10 M
D)basic,2.41 × 10-11 M
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40
What is the hydroxide ion concentration and the pH for a hydrochloric acid solution that has a hydronium ion concentration of 1.50 × 10-4 M?
A)6.67 × 10-10 M,4.82
B)6.67 × 10-10 M,9.18
C)6.67 × 10-11 M,3.82
D)6.67 × 10-11 M,10.18
A)6.67 × 10-10 M,4.82
B)6.67 × 10-10 M,9.18
C)6.67 × 10-11 M,3.82
D)6.67 × 10-11 M,10.18
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41
What is the pH of a solution made by mixing 100.0 mL of 0.10 M HNO3,50.0 mL of 0.20 M HCl,and 100.0 mL of water? Assume that the volumes are additive.
A)0.30
B)0.82
C)1.00
D)1.10
A)0.30
B)0.82
C)1.00
D)1.10
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42
What is the pH of a solution prepared by diluting 25.00 mL of 0.020 M Ba(OH)2 with enough water to produce a total volume of 250.00 mL?
A)2.40
B)2.70
C)11.30
D)11.60
A)2.40
B)2.70
C)11.30
D)11.60
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43
What is the hydroxide ion concentration of a lye solution that has a pH of 11.20?
A)6.31 × 10-12 M
B)1.58 × 10-3 M
C)2.80 M
D)11.20 M
A)6.31 × 10-12 M
B)1.58 × 10-3 M
C)2.80 M
D)11.20 M
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44
What is the pH of a solution made by mixing 100.00 mL of 0.20 M HCl with 50.00 mL of 0.10 M HCl? Assume that the volumes are additive.
A)0.15
B)0.52
C)0.78
D)1.70
A)0.15
B)0.52
C)0.78
D)1.70
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45
What is the pH of a 0.020 M Ba(OH)2 solution?
A)1.40
B)1.70
C)12.30
D)12.60
A)1.40
B)1.70
C)12.30
D)12.60
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46
At 25°C,the pH of a vinegar solution is 2.60.What are the values of [H3O+] and [OH-] in the solution?
A)3.99 × 10-12 M,2.51 × 10-3 M
B)2.51 × 10-3 M,3.98 × 10-12 M
C)2.51 × 10-3 M,11.40 M
D)2.60 M,11.40 M
A)3.99 × 10-12 M,2.51 × 10-3 M
B)2.51 × 10-3 M,3.98 × 10-12 M
C)2.51 × 10-3 M,11.40 M
D)2.60 M,11.40 M
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47
Which of the following solutions has the highest concentration of hydroxide ions [OH-]?
A)pH = 3.21
B)pH = 7.83
C)pH = 10.93
D)pH = 12.04
A)pH = 3.21
B)pH = 7.83
C)pH = 10.93
D)pH = 12.04
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48
Which of the following indicates the most basic solution?
A)[H+] = 1 × 10-10 M
B)pOH = 6.7
C)[OH-] = 7 × 10-5 M
D)pH = 4.2
A)[H+] = 1 × 10-10 M
B)pOH = 6.7
C)[OH-] = 7 × 10-5 M
D)pH = 4.2
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49
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)3.2 - 4.4
B)4.8 - 6.0
C)6.0 - 7.6
D)8.2 - 10.0

A)3.2 - 4.4
B)4.8 - 6.0
C)6.0 - 7.6
D)8.2 - 10.0
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50
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)4.8 - 6.0
B)6.0 - 7.6
C)7.6 - 8.2
D)> 8.2

A)4.8 - 6.0
B)6.0 - 7.6
C)7.6 - 8.2
D)> 8.2
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51
The pH of 0.255 M HCN is 4.95.What is the value of Ka for hydrocyanic acid?
A)1.3 × 10-10
B)4.9 × 10-10
C)1.1 × 10-5
D)4.4 × 10-5
A)1.3 × 10-10
B)4.9 × 10-10
C)1.1 × 10-5
D)4.4 × 10-5
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52
What is the approximate pH of a solution X that gives the following responses with the indicators shown? 
A)3.2 - 4.4
B)4.8 - 6.0
C)6.0 - 7.6
D)8.2 - 10.0

A)3.2 - 4.4
B)4.8 - 6.0
C)6.0 - 7.6
D)8.2 - 10.0
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53
What is the pH of a solution prepared by diluting 25.00 mL of 0.10 M HCl with enough water to produce a total volume of 100.00 mL?
A)1.00
B)1.60
C)2.00
D)3.20
A)1.00
B)1.60
C)2.00
D)3.20
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54
Determine the acid dissociation constant for a 0.10 M acetic acid solution that has a pH of 2.87.Acetic acid is a weak monoprotic acid and the equilibrium equation of interest is CH3COOH(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq).
A)1.3 × 10-2
B)1.3 × 10-3
C)1.8 × 10-5
D)1.8 × 10-6
A)1.3 × 10-2
B)1.3 × 10-3
C)1.8 × 10-5
D)1.8 × 10-6
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55
Determine the acid dissociation constant for a 0.010 M nitrous acid solution that has a pH of 2.70.Nitrous acid is a weak monoprotic acid and the equilibrium equation of interest is HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)8.0 × 10-3
B)2.0 × 10-3
C)5.0 × 10-4
D)4.0 × 10-4
A)8.0 × 10-3
B)2.0 × 10-3
C)5.0 × 10-4
D)4.0 × 10-4
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56
What is the equilibrium constant expression (Ka)for the acid dissociation of hydrocyanic acid HCN? The equation of interest is HCN(aq)+ H2O(l)⇌ H3O+(aq)+ CN-(aq).
A)Ka = ([H3O+][CN-])/([HCN][H2O])
B)Ka = ([H3O+][CN-])/([HCN])
C)Ka = ([HCN][H2O])/([H3O+][CN-])
D)Ka = ([HCN])/([H3O+][CN-])
A)Ka = ([H3O+][CN-])/([HCN][H2O])
B)Ka = ([H3O+][CN-])/([HCN])
C)Ka = ([HCN][H2O])/([H3O+][CN-])
D)Ka = ([HCN])/([H3O+][CN-])
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57
What is the pH of a 0.020 M HClO4 solution?
A)0.020
B)0.040
C)1.70
D)12.30
A)0.020
B)0.040
C)1.70
D)12.30
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58
Determine the acid dissociation constant for a 0.020 M formic acid solution that has a pH of 2.74.Formic acid is a weak monoprotic acid and the equilibrium equation of interest is HCOOH(aq)+ H2O(l)⇌ H3O+(aq)+ HCO2-(aq).
A)1.8 × 10-3
B)1.8 × 10-4
C)3.6 × 10-4
D)3.6 × 10-5
A)1.8 × 10-3
B)1.8 × 10-4
C)3.6 × 10-4
D)3.6 × 10-5
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59
What is the pH of a solution prepared by dissolving 0.15 gram of solid CaO (lime)in enough water to make 2.00 L of aqueous Ca(OH)2 (limewater)? CaO(s)+ H2O(l)→ Ca2+(aq)+ 2 OH-(aq)
A)2.57
B)2.87
C)11.13
D)11.43
A)2.57
B)2.87
C)11.13
D)11.43
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60
What is the equilibrium constant expression (Ka)for the acid dissociation of nitrous acid HNO2? The equation of interest is HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).
A)Ka = ([H3O+][NO2-])/([HNO2][H2O])
B)Ka = ([H3O+][NO2-])/([HNO2])
C)Ka = ([HNO2][H2O])/([H3O+][NO2-])
D)Ka = ([HNO2])/([H3O+][NO2-])
A)Ka = ([H3O+][NO2-])/([HNO2][H2O])
B)Ka = ([H3O+][NO2-])/([HNO2])
C)Ka = ([HNO2][H2O])/([H3O+][NO2-])
D)Ka = ([HNO2])/([H3O+][NO2-])
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61
What is the percent dissociation of a benzoic acid solution with pH = 2.59? The acid dissociation constant for this monoprotic acid is 6.5 × 10-5.
A)0.50%
B)1.5%
C)2.5%
D)3.5%
A)0.50%
B)1.5%
C)2.5%
D)3.5%
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62
Benzoic acid (C6H5CO2H = HBz)solutions are sometimes used in experiments to determine the molarity of a basic solution of unknown concentration.What is the pH of a 0.100 M solution of benzoic acid if Ka = 6.5 × 10-5 and the equilibrium equation of interest is HBz(aq)+ H2O(l)⇌ H3O+(aq)+ Bz-(aq).
A)1.00
B)2.59
C)4.19
D)5.19
A)1.00
B)2.59
C)4.19
D)5.19
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63
A tablet containing 500.0 mg of aspirin (acetylsalicylic acid or HC9H7O4)was dissolved in enough water to make 100 mL of solution.Given that Ka = 3.0 × 10-4 for aspirin,what is the pH of the solution?
A)1.57
B)2.54
C)3.52
D)5.08
A)1.57
B)2.54
C)3.52
D)5.08
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64
The pH of 0.150 M CH3CO2H,acetic acid,is 2.78.What is the value of Ka for acetic acid?
A)2.8 × 10-6
B)1.9 × 10-5
C)1.7 × 10-3
D)1.1 × 10-2
A)2.8 × 10-6
B)1.9 × 10-5
C)1.7 × 10-3
D)1.1 × 10-2
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65
Calculate the concentration of bicarbonate ion,HCO3-,in a 0.010 M H2CO3 solution that has the stepwise dissociation constants Ka1 = 4.3 × 10-7 and Ka2 = 5.6 × 10-11.
A)6.6 × 10-5 M
B)4.3 × 10-7 M
C)4.3 × 10-9 M
D)5.6 × 10-11 M
A)6.6 × 10-5 M
B)4.3 × 10-7 M
C)4.3 × 10-9 M
D)5.6 × 10-11 M
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66
The percent dissociation of acetic acid changes as the concentration of the acid decreases.A 100-fold decrease in acetic acid concentration results in a ________ fold ________ in the percent dissociation.
A)10,increase
B)10,decrease
C)100,increase
D)100,decrease
A)10,increase
B)10,decrease
C)100,increase
D)100,decrease
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67
What is the strongest monoprotic acid of the following set if all the acids are at 0.100 M concentration?
A)hydrofluoric acid with Ka = 3.5 × 10-4
B)benzoic acid with Ka = 6.5 × 10-5
C)acetic acid with Ka = 1.8 × 10-5
D)hypochlorous acid with Ka = 3.5 × 10-8
A)hydrofluoric acid with Ka = 3.5 × 10-4
B)benzoic acid with Ka = 6.5 × 10-5
C)acetic acid with Ka = 1.8 × 10-5
D)hypochlorous acid with Ka = 3.5 × 10-8
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68
What is the pH of a 0.10 M H2Se solution that has the stepwise dissociation constants Ka1 = 1.3 × 10-4 and Ka2 = 1.0 × 10-11?
A)2.44
B)3.89
C)4.89
D)5.50
A)2.44
B)3.89
C)4.89
D)5.50
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69
Vinegar is a 5.0% solution by weight of acetic acid (CH3CO2H)in water.Given that Ka = 1.8 × 10-5 for acetic acid and assuming the density of vinegar to be 1.00 g/cm3,what is the pH of this vinegar solution?
A)2.00
B)2.41
C)2.87
D)4.74
A)2.00
B)2.41
C)2.87
D)4.74
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70
What is the hydronium ion concentration of a 0.100 M acetic acid solution with a Ka = 1.8 × 10-5? The equation for the dissociation of acetic acid is: CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq).
A)1.3 × 10-2 M
B)4.2 × 10-2 M
C)1.3 × 10-3 M
D)4.2 × 10-3 M
A)1.3 × 10-2 M
B)4.2 × 10-2 M
C)1.3 × 10-3 M
D)4.2 × 10-3 M
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71
What is the selenide ion concentration [Se2-] for a 0.100 M H2Se solution that has the stepwise dissociation constants of Ka1 = 1.3 × 10-4 and Ka2 = 1.0 × 10-11?
A)3.6 × 10-3 M
B)1.3 × 10-4 M
C)1.3 × 10-5 M
D)1.0 × 10-11 M
A)3.6 × 10-3 M
B)1.3 × 10-4 M
C)1.3 × 10-5 M
D)1.0 × 10-11 M
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72
Calculate the pH of a 0.20 M H2SO3 solution that has the stepwise dissociation constants Ka1 = 1.5 × 10-2 and Ka2 = 6.3 × 10-8.
A)1.26
B)1.32
C)1.82
D)2.52
A)1.26
B)1.32
C)1.82
D)2.52
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73
Calculate the pH of a 0.020 M carbonic acid solution,H2CO3(aq),that has the stepwise dissociation constants Ka1 = 4.3 × 10-7 and Ka2 = 5.6 × 10-11.
A)1.70
B)4.03
C)6.37
D)10.25
A)1.70
B)4.03
C)6.37
D)10.25
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74
Which of the following can be classified as a weak base?
A)CH3NH2
B)NH2OH
C)Both CH3NH2 and NH2OH
D)Neither CH3NH2 nor NH2OH
A)CH3NH2
B)NH2OH
C)Both CH3NH2 and NH2OH
D)Neither CH3NH2 nor NH2OH
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75
Para-Aminobenzoic acid (PABA),p-H2NC6H4(COOH),is used in some sunscreens and hair conditioning products.Calculate the pH of an aqueous solution with [PABA] = 0.030 M and Ka = 2.2 × 10-5.
A)1.52
B)3.09
C)4.66
D)6.18
A)1.52
B)3.09
C)4.66
D)6.18
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76
Potassium hydrogen phthalate (molar mass = 204.2 g/mol)is one of the most commonly used acids for standardizing solutions containing bases.KHP is a monoprotic weak acid with Ka = 3.91 × 10-6.Calculate the pH of the solution that results when 0.40 g of KHP is dissolved in enough water to produce 25.0 mL of solution.
A)2.10
B)3.26
C)4.30
D)5.41
A)2.10
B)3.26
C)4.30
D)5.41
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77
Vinegar is a 5.0% solution by weight of acetic acid (CH3CO2H)in water.Given that the pH for acetic acid is 2.41,the Ka = 1.8 × 10-5 and assuming the density of vinegar to be 1.00 g/cm3,what is the percent dissociation of acetic acid in vinegar?
A)0.47%
B)1.5%
C)4.0%
D)5.0%
A)0.47%
B)1.5%
C)4.0%
D)5.0%
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78
What is the hydronium ion concentration of a 0.100 M hypochlorous acid solution with Ka = 3.5 × 10-8? The equation for the dissociation of hypochlorous acid is: HOCl(aq)+ H2O(l)⇌ H3O+(aq)+ OCl-(aq).
A)1.9 × 10-4
B)5.9 × 10-4
C)1.9 × 10-5
D)5.9 × 10-5
A)1.9 × 10-4
B)5.9 × 10-4
C)1.9 × 10-5
D)5.9 × 10-5
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79
What is the second stepwise equilibrium constant expression for phosphoric acid H3PO4?
A)Ka2 = ([H3O+][H2PO4-])/([H3PO4])
B)Ka2 = ([H3O+]2[HPO42-])/([H3PO4])
C)Ka2 = ([H3O+]3[PO43-])/([H3PO4])
D)Ka2 = ([H3O+][HPO42-])/([H2PO4-])
A)Ka2 = ([H3O+][H2PO4-])/([H3PO4])
B)Ka2 = ([H3O+]2[HPO42-])/([H3PO4])
C)Ka2 = ([H3O+]3[PO43-])/([H3PO4])
D)Ka2 = ([H3O+][HPO42-])/([H2PO4-])
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80
What is the pH of a 0.100 M NH3 solution that has Kb = 1.8 × 10-5? The equation for the dissociation of NH3 is NH3(aq)+ H2O(l)⇌ NH4+(aq)+ OH-(aq).
A)1.87
B)2.87
C)11.13
D)12.13
A)1.87
B)2.87
C)11.13
D)12.13
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