Exam 15: Aqueous Equilibria: Acids and Bases

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Calculate the pH of a 0.020 M carbonic acid solution,H2CO3(aq),that has the stepwise dissociation constants Ka1 = 4.3 × 10-7 and Ka2 = 5.6 × 10-11.

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B

BF3 and NH3 undergo a Lewis acid-base reaction forming an adduct.Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction;what is the Lewis acid and the Lewis base? BF<sub>3</sub> and NH<sub>3</sub> undergo a Lewis acid-base reaction forming an adduct.Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction;what is the Lewis acid and the Lewis base?

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B

Which Br∅nsted-Lowry base has the strongest conjugate acid?

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D

What is the approximate pH of a solution X that gives the following responses with the indicators shown? What is the approximate pH of a solution X that gives the following responses with the indicators shown?

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A solution with a hydrogen ion concentration of 3.25 × 10-2 M is ________ and has a hydroxide concentration of ________.

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In the aquation reaction Co2+ + 6 H2O → [Co(H2O)6]2+,the Lewis acid is ________ and the Lewis base is ________.

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Which of the following should have the lowest bond strength?

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What are the Br∅nsted-Lowry acids in the following chemical reaction? HBr(sol)+ CH3COOH(sol)⇌ CH3C(OH)2+(sol)+ Br-(sol)

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What is the pH of a solution made by mixing 100.00 mL of 0.20 M HCl with 50.00 mL of 0.10 M HCl? Assume that the volumes are additive.

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What is the hydronium ion concentration of a 0.100 M acetic acid solution with a Ka = 1.8 × 10-5? The equation for the dissociation of acetic acid is: CH3CO2H(aq)+ H2O(l)⇌ H3O+(aq)+ CH3CO2-(aq).

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Which of the following is a weak diprotic acids?

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If an equal number of moles of the weak acid HF and the strong base KOH are added to water,is the resulting solution acidic,basic,or neutral?

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The following pictures represent solutions of three salts MA;water molecules have been omitted for clarity.Dotted spheres represent Ay- ions;gray spheres represent Mx+ ions;black spheres represent oxygen atoms;and unshaded spheres represent hydrogen atoms. The following pictures represent solutions of three salts MA;water molecules have been omitted for clarity.Dotted spheres represent A<sup>y</sup><sup>-</sup> ions;gray spheres represent M<sup>x+</sup> ions;black spheres represent oxygen atoms;and unshaded spheres represent hydrogen atoms.   -Which picture represents a basic salt? -Which picture represents a basic salt?

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What is the selenide ion concentration [Se2-] for a 0.100 M H2Se solution that has the stepwise dissociation constants of Ka1 = 1.3 × 10-4 and Ka2 = 1.0 × 10-11?

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Which one of the following salts,when dissolved in water,produces the solution with a pH closest to 7.00?

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Calculate the pH of a 0.100 M NaCH3CO2 solution.Ka for acetic acid,CH3CO2H,is 1.8 × 10-5.

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Determine the acid dissociation constant for a 0.010 M nitrous acid solution that has a pH of 2.70.Nitrous acid is a weak monoprotic acid and the equilibrium equation of interest is HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).

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The following pictures represent solutions of three salts MA;water molecules have been omitted for clarity.Dotted spheres represent Ay- ions;gray spheres represent Mx+ ions;black spheres represent oxygen atoms;and unshaded spheres represent hydrogen atoms. The following pictures represent solutions of three salts MA;water molecules have been omitted for clarity.Dotted spheres represent A<sup>y</sup><sup>-</sup> ions;gray spheres represent M<sup>x+</sup> ions;black spheres represent oxygen atoms;and unshaded spheres represent hydrogen atoms.   -Which picture represents a neutral salt? -Which picture represents a neutral salt?

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Calculate the pH for an aqueous solution of pyridine that contains Calculate the pH for an aqueous solution of pyridine that contains   hydroxide ion. hydroxide ion.

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How many grams of pyridine are there in 100 mL of an aqueous solution that has a pH of 9.00? The Kb for pyridine is 1.9 × 10-9 and the equation of interest is C5H5N(aq)+ H2O(l)⇌ C5H5NH+(aq)+ OH-(aq).

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