Exam 14: Solutions and Their Behavior

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The standard enthalpy of formation of RbF(s) is -557.7kJ/mol and the standard enthalpy of formation of RbF(aq, 1 m) is -583.8 kJ/mol. Determine the enthalpy of solution of RbF and indicate whether the solution temperature will increase or decrease when RbF is dissolved in water.

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What is the mass of H2SO4 in a 38.2-mL sample of concentrated sulfuric acid that has a density of 1.84 g/mL and consists of 98.3% H2SO4?

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A concentrated nitric acid solution has a density of 1.41 g/mL at 25°C and is 15.8 M. What is the percent by mass of HNO3 in the solution?

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If 27.9 g LiCl is dissolved in 175 g H2O, what is the weight percent of LiCl in the solution?

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What is the mole fraction of urea, CH4N2O, in an aqueous solution that is 49% urea by mass?

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What is the molality of ethanol (C2H5OH) in an aqueous solution that is 39.8% ethanol by mass?

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Assuming ideal behavior, which of the following aqueous solutions would be expected to exhibit the smallest freezing-point lowering?

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The osmotic pressure of blood is 7.65 atm at 37 °C. What mass of glucose (C6H12O6, molar mass = 180.2 g/mol) is needed to prepare 2.25 L of solution for intravenous injection? The osmotic pressure of the glucose solution must equal the osmotic pressure of blood. (R = 0.08206 L⋅atm/mol⋅K)

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Which of the following favor(s) the solubility of an ionic solid in a liquid solvent?

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According to the National Institute of Standards webbook, the Henry's Law constant for O2 gas is 0.0013 mol/kg?bar at 25°C What is the Henry's law constant in units of mol/kg?mmHg? (1 bar = 0.9869 atm; 1 atm = 760 mmHg)

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A surfactant used for cleaning is called a(n) ________.

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A solution is prepared by dissolving 5.88 g of an unknown nonelectrolyte in enough water to make 0.355 L of solution. The osmotic pressure of the solution is 1.21 atm at 27 °C. What is the molar mass of the solute? (R = 0.08206 L⋅atm/mol⋅K)

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What concentration of silver nitrate (in ppm) is present in 7.1 × 10-7 M AgNO3(aq)? For very dilute aqueous solutions, you can assume the solution's density is 1.0 g/mL. The molar mass of AgNO3 is 169.9 g/mol.

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The vapor pressure of water at 90°C is 0.692 atm. What is the vapor pressure (in atm) of a solution made by dissolving 2.91 mole(s) of CsF(s) in 1.00 kg of water? Assume that Raoult's law applies.

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A 3.0 g sample of a small protein having a molecular weight of 42,000 g/mol is dissolved in 52.8 mL of water at 21°C. What is the osmotic pressure of the solution? (R = 0.0821 L · atm/K·mol, 1 atm = 760 mmHg)

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What partial pressure of oxygen gas is required in order for 0.00284 g of the gas to dissolve in 15.9 mL of pure water? The Henry's law constant for oxygen gas is 1.3 × 10-3 M atm-1.

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How many milliliters of 11.7 M H2SO4 are needed to prepare 600.0 mL of 0.10 M H2SO4?

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What is the vapor pressure at 20°C of an ideal solution prepared by the addition of 4.50 g of the nonvolatile solute urea, CO(NH2)2, to 22.7 g of methanol, CH3OH? The vapor pressure of pure methanol at 20°C is 89.0 mmHg.

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The change in energy accompanying the equation below is the _____ of MX. MX(s) → M+(aq) + X−(aq)

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Which of the following is a colligative property?

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