Exam 2: Acids and Bases

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Which is the proper reaction mechanism for the reaction of boron trifluoride and diethyl ether? Assume that the charges are correct and add electron pairs, if needed. Also consider how many electrons should be in the outer shell of boron trifluoride to make it neutral. Which is the proper reaction mechanism for the reaction of boron trifluoride and diethyl ether? Assume that the charges are correct and add electron pairs, if needed. Also consider how many electrons should be in the outer shell of boron trifluoride to make it neutral.

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B

What is the role of methanol (CH3OH) in the following reaction? What is the role of methanol (CH<sub>3</sub>OH) in the following reaction?

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B

The equilibrium constant will be greater than 1.0 for the following reaction The equilibrium constant will be greater than 1.0 for the following reaction

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False

Which are acid-base reactions according to Lewis theory but not according to the Brønsted-Lowry theory? Which are acid-base reactions according to Lewis theory but not according to the Brønsted-Lowry theory?

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Which are acid-base reactions according to Brønsted-Lowry theory? Which are acid-base reactions according to Brønsted-Lowry theory?

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Which of these has the lowest numerical value of pKa and is therefore the strongest acid?

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Arrange the following species in order of increasing basicity (weakest to strongest). I. OH- II. Cl- III. H2O IV. NH3

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List the bonds in order of decreasing acidity (most to least). List the bonds in order of decreasing acidity (most to least).

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Lewis bases donate electrons when reacting.

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The strongest acid in the following list is sodium bicarbonate. The strongest acid in the following list is sodium bicarbonate.

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Ammonia acts as a Brønsted-Lowry base in the following reaction. Ammonia acts as a Brønsted-Lowry base in the following reaction.

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Which is the stronger base if the equilibrium lies to the right? (Sec. 2.4, HARD) Which is the stronger base if the equilibrium lies to the right? (Sec. 2.4, HARD)

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Complete the following reaction scheme with the appropriate equilibrium arrow (indicating the higher concentrations at equilibrium). Complete the following reaction scheme with the appropriate equilibrium arrow (indicating the higher concentrations at equilibrium).

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Which equilibria have equilibrium constants greater than 1.0? Which equilibria have equilibrium constants greater than 1.0?

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Identify the acid, base, conjugate acid, conjugate base in the following reaction. Identify the acid, base, conjugate acid, conjugate base in the following reaction.

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Which is the order of decreasing acid strength of the following compounds (greatest first)? Which is the order of decreasing acid strength of the following compounds (greatest first)?

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What is the role of water in the following reaction? What is the role of water in the following reaction?

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Which statements about acid-base equilibria are true? I. The pKa is the negative log10 of the acid equilibrium constant. II. A stronger acid has a pKa with a smaller value than a weaker acid. III. The stronger the base, the smaller the pKa of its conjugate acid. IV. The Ka = K [HA].

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Identify the Arrhenius bases: I. NH3 II. NaOH III. HI IV. Ca(OH)2

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Which equilibria have equilibrium constants smaller than 1.0? Which equilibria have equilibrium constants smaller than 1.0?

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