Exam 15: Enolate Anions

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Which are the most important contributing structures for the enolate formed by the treatment of 2,4-pentanedione with base? Which are the most important contributing structures for the enolate formed by the treatment of 2,4-pentanedione with base?

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B

The condensation of acetoacetyl-CoA with acetyl-CoA is an Aldol reaction.

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True

Which is the major product of the following series of reactions? Which is the major product of the following series of reactions?

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C

Which is the major product from the reaction of 1,6-cyclodecanedione with hot aqueous NaOH? Which is the major product from the reaction of 1,6-cyclodecanedione with hot aqueous NaOH?

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The starting material that completes the following reaction is The starting material that completes the following reaction is

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The most stable enol form of 2-pentanone is The most stable enol form of 2-pentanone is

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The major product of the following reaction is, The major product of the following reaction is,

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Acetone reacts with 2 equivalents of molecular bromine (Br2) in aqueous solution in the presence of sodium carbonate. What is the major product of this reaction sequence?

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The major product of the following reaction is, The major product of the following reaction is,

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1-Cyclohexenecarbaldehyde can be produced from the following starting material and base. 1-Cyclohexenecarbaldehyde can be produced from the following starting material and base.

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What is the major product of the following reaction? What is the major product of the following reaction?

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Which are the reactants for the aldol product shown? Which are the reactants for the aldol product shown?

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The major enol form of ethyl 3-oxobutanoate is The major enol form of ethyl 3-oxobutanoate is

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What is the main product of the following reaction sequence? What is the main product of the following reaction sequence?

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How would you characterize this reaction forming fructose 1,6-bisphosphate? How would you characterize this reaction forming fructose 1,6-bisphosphate?

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What is the order of increasing acidity for these compounds (least acidic first)? What is the order of increasing acidity for these compounds (least acidic first)?

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Which is the major product of the following series of reactions? Which is the major product of the following series of reactions?

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The starting material that completes the following reaction is, The starting material that completes the following reaction is,

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Which is the major product of the following reaction? Which is the major product of the following reaction?

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What is the major product of the following reaction? What is the major product of the following reaction?

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