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A Possible Mechanism for the Decomposition of Ozone to Oxygen

Question 21

Multiple Choice

A possible mechanism for the decomposition of ozone to oxygen in the atmosphere is O3( g) O2( g) +O (fast equilibrium)  O+O3( g) 2O2( g)  (slow)  \begin{array}{l}\mathrm{O}_{3}(\mathrm{~g}) \rightleftharpoons \mathrm{O}_{2}(\mathrm{~g}) +\mathrm{O}& \text { (fast equilibrium) } \\\mathrm{O}+\mathrm{O}_{3}(\mathrm{~g}) \rightarrow 2 \mathrm{O}_{2}(\mathrm{~g}) & \text { (slow) }\end{array}

What is a rate law that is consistent with this mechanism?


A) rate = k[O3]
B) rate = k[O3]2
C) rate = k[O3] × [O]
D) rate = k[O3]2 × [O2]
E) rate = k[O3]2 × [O2]?1

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