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A Possible Reaction Mechanism for the Reaction of Nitrogen Dioxide

Question 26

Multiple Choice

A possible reaction mechanism for the reaction of nitrogen dioxide with carbon monoxide is
2NO2(g) NO3(g) +NO(g) (slow) NO3(g) +CO(g) NO2(g) +CO2(g) (fast) \begin{array}{l}2 \mathrm{NO}_{2}(g) \rightarrow \mathrm{NO}_{3}(g) +\mathrm{NO}(g) &(slow) \\\mathrm{NO}_{3}(g) +\mathrm{CO}(g) \rightarrow \mathrm{NO}_{2}(g) +\mathrm{CO}_{2}(g) &(fast) \end{array}

What is the overall reaction and the most probable rate law for the reaction?


A) NO2(g) + CO(g) ? NO(g) + CO2(g) ;rate = k[NO2]
B) NO2(g) + CO(g) ? NO(g) + CO2(g) ;rate = k[NO2]2
C) NO2(g) + CO(g) ? NO(g) + CO2(g) ;rate = k[NO3]×[CO]
D) 2NO2(g) + CO(g) ? NO(g) + CO2(g) ;rate = k[NO2]×[ NO3]×[CO]
E) 2NO2(g) + CO(g) ? NO(g) + CO2(g) ;rate = k[NO3]×[CO]

Correct Answer:

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