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The Isomerization of Methyl Isocyanide, CH3NC → CH3CN, Follows First-Order

Question 51

Multiple Choice

The isomerization of methyl isocyanide, CH3NC → CH3CN, follows first-order kinetics. The half-lives were found to be 161 min at 199°C and 12.5 min at 230.°C. Calculate the activation energy for this reaction. (R = 8.314 J/mol • K)


A) 6.17 × 10-3 kJ/mol
B) 31.4 kJ/mol
C) 78.2 kJ/mol
D) 124 kJ/mol
E) 163 kJ/mol

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