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    Exam 15: Dienes and Aromaticity
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    1,3-Cyclopentadiene Is Unusually Acidic, with a PK<sub>a</sub> of ~16
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1,3-Cyclopentadiene Is Unusually Acidic, with a PKa of ~16

Question 17

Question 17

Essay

1,3-Cyclopentadiene is unusually acidic, with a pKa of ~16. On the other hand, 1,3,5-cyclohepatriene is much less acidic, with a pKa of ~36. Explain why the compounds have such differing acidities.
1,3-Cyclopentadiene is unusually acidic, with a pK<sub>a</sub> of ~16. On the other hand, 1,3,5-cyclohepatriene is much less acidic, with a pKa of ~36. Explain why the compounds have such differing acidities.

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Deprotonation of one of the sp3 hydrogens...

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