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Consider the Following Mechanism for the Oxidation of Bromide Ions \to

Question 21

Multiple Choice

Consider the following mechanism for the oxidation of bromide ions by hydrogen peroxide in aqueous acid solution.
H+ + H2O2  Consider the following mechanism for the oxidation of bromide ions by hydrogen peroxide in aqueous acid solution. H<sup>+</sup> + H<sub>2</sub>O<sub>2</sub>   H<sub>2</sub>O<sup>+</sup>-OH (rapid equilibrium)  H<sub>2</sub>O<sup>+</sup>-OH + Br<sup>-</sup>  \to  HOBr + H<sub>2</sub>O (slow)  HOBr + H<sup>+</sup> + Br<sup>-</sup>  \to  Br<sub>2</sub> + H<sub>2</sub>O (fast)  What is the overall reaction equation for this process? A) 2H<sub>2</sub>O<sup>+</sup>-OH + 2Br<sup>-</sup>  \to  H<sub>2</sub>O<sub>2</sub> + Br<sub>2</sub> + 2H<sub>2</sub>O B) 2H<sup>+</sup> + 2Br<sup>-</sup> + H<sub>2</sub>O<sub>2</sub>  \to  Br<sub>2</sub> + 2H<sub>2</sub>O C) 2H<sup>+</sup> + H<sub>2</sub>O<sub>2</sub> + Br<sup>-</sup> + HOBr  \to  H<sub>2</sub>O<sup>+</sup>-OH + Br<sub>2</sub> + H<sub>2</sub>O D) H<sub>2</sub>O<sup>+</sup>-OH + Br<sup>-</sup> + H<sup>+</sup>  \to  Br<sub>2</sub> + H<sub>2</sub>O E) None of these choices is correct.
H2O+-OH (rapid equilibrium)
H2O+-OH + Br- \to HOBr + H2O (slow)
HOBr + H+ + Br- \to Br2 + H2O (fast)
What is the overall reaction equation for this process?


A) 2H2O+-OH + 2Br- \to H2O2 + Br2 + 2H2O
B) 2H+ + 2Br- + H2O2 \to Br2 + 2H2O
C) 2H+ + H2O2 + Br- + HOBr \to H2O+-OH + Br2 + H2O
D) H2O+-OH + Br- + H+ \to Br2 + H2O
E) None of these choices is correct.

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