Exam 20: Principles of Chemical Reactivity: Electron Transfer Reactions

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Which of the following statements is true concerning the electrochemical cell Zn(s) | Zn2+(aq, 1.0 M) || Ca2+(aq, 1.0 M) | Ca(s) The standard reduction potentials are given follows: Zn2+(aq) + 2 e− → Zn(s); E° = -0.76 V Ca2+(aq) + 2 e− → Ca(s); E° = -2.87 V

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Which of the following statements is true concerning the voltaic cell shown below? Which of the following statements is true concerning the voltaic cell shown below?

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Which of the following is true for a product-favored reaction at equilibrium?

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Write a balanced half-reaction for the reduction of hydrogen peroxide to water in an acidic solution.

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For the following cell reaction, the standard cell potential is 1.34 V. To determine the cell potential at nonstandard conditions, what is the value that should be used for n in the Nernst equation? 2MnO4(aq)+5H2SO3(aq)2Mn2+(aq)+5SO42(aq)+4H+(aq)+3H2O(l)2 \mathrm { MnO } _ { 4 } ^ { - } ( \mathrm { aq } ) + 5 \mathrm { H } _ { 2 } \mathrm { SO } _ { 3 } ( \mathrm { aq } ) \rightarrow 2 \mathrm { Mn } ^ { 2 + } ( \mathrm { aq } ) + 5 \mathrm { SO } _ { 4 } ^ { 2 - } ( \mathrm { aq } ) + 4 \mathrm { H } ^ { + } ( \mathrm { aq } ) + 3 \mathrm { H } _ { 2 } \mathrm { O } ( \mathrm { l } )

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Calculate ΔrG° for the disproportionation reaction of copper(I) ion (Cu+) at 25 °C. 2 Cu+(aq) → Cu2+(aq) + Cu(s) The standard reduction potentials are as follows: Cu+(aq) + e- → Cu(s) E° = +0.518 V Cu2+(aq) + 2 e- → Cu(s) E° = +0.337 V

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Which of the following statements concerning voltaic cells is not true?

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Which of the following is the cell notation for a cell in which the hydrogen electrode is the anode and the cathode half-reaction is Co3+(aq) + e− → Co2+(aq)?

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The standard reduction potentials are as follows: Cr3+(aq) + 3 e- → Cr(s); E° = -0.74 V Fe2+(aq) + 2 e- → Fe(s); E° = -0.41 V Calculate the standard Gibbs free energy change for the following reaction. 2 Cr(s) + 3 Fe2+ → 3 Fe(s) + 2 Cr3+(aq)

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Balance the following half-reaction occurring in an acidic solution. NO3-(aq) → NO(aq)

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Batteries used in watches contain mercury(II) oxide. As the current flows, mercury(II) oxide is reduced to mercury according to the following reaction: HgO(s) + H2O( \ell ) + 2 e- ? Hg( \ell ) + 2 OH-(aq) If 2.3 × 10-5 amperes flows continuously for 1200 days, calculate the mass of mercury, Hg( \ell ), produced.

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The standard cell potential of the given electrochemical cell is 0.19 V. Pt | Sn4+(aq, 1.0 M), Sn2+(aq, 1.0 M) || Cu2+(aq, 0.200 M) | Cu Which of the following factors will increase the measured cell potential of the given electrochemical cell?

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According to the cell notation below, which of the following species is undergoing reduction? Ni | Ni2+(aq) || Mn2+(aq) | MnO2(s) | Pt(s)

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What half-reaction occurs at the cathode during the electrolysis of molten potassium bromide?

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If ?rG° for the following reaction is -22.2 kJ/mol-rxn, calculate Ecell E _ { \text {cell } } ^ { \circ } for the following reaction: Cu2+(aq) + 2 Ag(s) + 2 Cl-(aq) ? Cu(s) + 2 AgCl(s)

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The cell potential of the following electrochemical cell is determined by using an unspecified concentration of acid. Calculate the pH of the acid solution, given that the measured cell potential is -0.431 V and the anode reduction potential (E°) is 0.222 V at 25 °C. ​ Ag(s) | AgCl(s) | Cl−(aq, 1.0 M) || H+(aq) | H2(g, 1.0 atm) | Pt(s) ​

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Calculate Ecell for the following electrochemical cell at 25 °C Pt(s) | H2(g, 1.00 atm) | H+(aq, 1.00 M) || Sn2+(aq, 0.350 M), Sn4+(aq, 0.020 M) | Pt(s) The standard reduction potentials are as follows: Sn4+(aq) + 2 e- → Sn2+(s) E° = +0.15 V 2 H+(aq) + 2 e- → H2(g) E° = 0.00 V

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The use of electrical energy to produce chemical change is known as _____. An example of this process is the reduction of sodium chloride, NaCl( \ell ), to produce solid sodium.

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Which of the following statements is true for the following reaction, assuming the given reaction proceeds in the forward direction? Fe3+(aq) + Co(s) → Fe2+(aq) + Co2+(aq)

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Which of the following equations represents the Nernst equation?

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