Exam 10: Bonding and Molecular Structure Orbital Hybridization and Molecular Orbitals

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In the NO2- ion, each atom can be viewed as sp2 hybridized. Thus, each atom has one remaining unhybridized p orbital. How many π2p molecular orbitals (including both bonding and antibonding orbitals) are formed using the unhybridized p orbitals?

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to Diagram 9-1. According to molecular orbital theory, which of the following species will be paramagnetic? -Refer to Diagram 9-1. According to molecular orbital theory, which of the following species will be paramagnetic?

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What is the maximum number of hybridized orbitals that can be formed by afluorine atom?

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In the context of valence shell electron pair repulsion (VSEPR) theory, what is the molecular geometry around a central atom that is sp3 hybridized and has one lone pair of electrons?

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Which of the following does not contain at least one pi bond?

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The hybridization of the carbon atom in CF3+ is ________.

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The hybridization of the nitrogen atom in NH3 is _____.

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What is the hybridization of an atom that has 3 σ bonds, 0 π bonds, and 0 lone pair?

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What is the hybridization of the nitrogen atom in NO+?

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Nitric acid, HNO3, dissociates in water to form nitrate ions and hydronium ions. What change in hybridization of the nitrogen atom occurs in this dissociation?

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What is the hybridization of each carbon atom in benzene, C6H6? Benzene contains a six-member carbon ring.

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Ammonia reacts with oxygen and water to produce nitric acid. What change in hybridization of the nitrogen atom occurs in this reaction?

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to Diagram 9-1. According to molecular orbital theory, what is the bond order of Ne<sub>2</sub>2+? -Refer to Diagram 9-1. According to molecular orbital theory, what is the bond order of Ne22+?

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Which of the following is the bond order of Li2 molecule?

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What does the following figure represent? What does the following figure represent?

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What is the hybridization of the central nitrogen atom in N2O?

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Which molecule will have the following valence molecular orbital energy level diagram? Which molecule will have the following valence molecular orbital energy level diagram?

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to Diagram 9-1. What is the molecular orbital configuration of N<sub>2</sub><sup>2+</sup>? -Refer to Diagram 9-1. What is the molecular orbital configuration of N22+?

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Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules Diagram 9-1 The molecular orbital diagram below may be used for the following problem(s). For oxygen and fluorine, the σ2p orbital should be lower in energy than the π2p orbitals. However, the diagram will still yield correct bond order and magnetic behavior for these molecules   -Refer to diagram 9-1. Identify the molecule with the shortest bond length. -Refer to diagram 9-1. Identify the molecule with the shortest bond length.

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How many sigma (σ) bonds and pi (π) bonds are present in the given molecule? How many sigma (σ) bonds and pi (π) bonds are present in the given molecule?

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