Exam 17: Equilibrium: the Extent of Chemical Reactions

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The reaction quotient, Qc, for a reaction has a value of 75 while the equilibrium constant, Kc, has a value of 195. Which of the following statements is accurate?

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What is the mass-action expression, Qc, for the following chemical reaction? PbO(s) + CO(g) ⇄ Pb(l) + CO2(g)

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The reaction system CS2(g) + 4H2(g) ⇄ CH4(g) + 2H2S(g) Is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of carbon disulfide is reduced?

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The reaction system POCl3(g) ⇄ POCl(g) + Cl2(g) Is at equilibrium. Which of the following statements describes the behavior of the system if POCl is added to the container?

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The equilibrium constant, Kc, for the decomposition of COBr2 COBr2(g) ⇄ CO(g) + Br2(g) Is 0.190. What is Kc for the following reaction? 2CO(g) + 2Br2(g) ⇄ 2COBr2(g)

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Changing the amount of a solid reactant or product in an equilibrium reaction will not affect the amounts of the other reactants and products present at equilibrium.

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At high temperatures, carbon reacts with O2 to produce CO as follows: C(s) + O2(g) ⇄ 2CO(g). When 0.350 mol of O2 and excess carbon were placed in a 5.00-L container and heated, the equilibrium concentration of CO was found to be 0.060 M. What is the equilibrium constant, Kc, for this reaction?

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At a certain temperature the reaction CO2(g) + H2(g) ⇄ CO(g) + H2O(g)2 Has Kc = 2.50. If 2.00 mol of carbon dioxide and 1.5 mol of hydrogen are placed in a 5.00 L vessel and equilibrium is established, what will be the concentration of carbon monoxide?

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In water, the following equilibrium exists: H+(aq) + OH(aq) ⇄ H2O(l) In pure water at 25°C, the concentration of H+ ions is 1.00 × 107 mol/L. Calculate the value of the equilibrium constant for the reaction as written above.

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Consider the following two equilibria and their respective equilibrium constants: (1) NO(g) + ½O2(g) ⇄ NO2(g) (2) 2NO2(g) ⇄ 2NO(g) + O2(g) Which one of the following is the correct relationship between the equilibrium constants K1 and K2?

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Consider the equilibrium reaction shown below. B2(g) ⇄ 2B(g) If the rate constants are: kfwd = 7.00 × 105s1 and krev = 2.00 × 105 L mol1 s1, what is the value of Kc under these conditions?

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Consider the reversible reaction: 2NO2(g) ⇄ N2O4(g) If the concentrations of both NO2 and N2O4 are 0.016 mol L1, what is the value of Qc?

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When a reaction system reaches equilibrium, the forward and reverse reactions stop.

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Write the mass-action expression, Qc, for the following chemical reaction equation. 2C6H6(g) + 15O2(g) ⇄ 12CO2(g) + 6H2O(g)

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Unless ΔH°rxn = 0, a change in temperature will affect the value of the equilibrium constant Kc.

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The equilibrium constant for the reaction of bromine with chlorine to form bromine monochloride is 58.0 at a certain temperature. Br2(g) + Cl2(g) ⇄ 2BrCl(g) What is the equilibrium constant for the following reaction? BrCl(g) ⇄ ½Br2(g) + ½Cl2(g)

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Consider the equilibrium reaction: H2(g) + Br2(g) ⇄ 2HBr(g) Which of the following correctly describes the relationship between Kc and Kp for the reaction?

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At 850°C, the equilibrium constant Kp for the reaction C(s) + CO2(g) ⇄ 2CO(g) Has a value of 10.7. If the total pressure in the system at equilibrium is 1.000 atm, what is the partial pressure of carbon monoxide?

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Carbon monoxide and chlorine combine in an equilibrium reaction to produce the highly toxic product, phosgene (COCl2) CO(g) + Cl2(g) ⇄ COCl2(g) If the equilibrium constant for this reaction is Kc = 248, predict, if possible, what will happen when the reactants and product are combined with the concentrations shown. [CO] = [Cl2] = 0.0200 M; [COCl2] = 0.0992 M

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Carbon monoxide and chlorine combine in an equilibrium reaction to produce the highly toxic product, phosgene (COCl2) CO(g) + Cl2(g) ⇄ COCl2(g) If the equilibrium constant for this reaction is Kc = 248, predict, if possible, what will happen when the reactants and product are combined with the concentrations shown. [CO] = [Cl2] = 0.010 M; [COCl2] = 0.070 M

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