Exam 15: Enolate Anions

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How many possible aldol products can be formed when acetone and ethanal are mixed in the presence of base?(Hint: Assume that no more than two molecules react with each other at a time.)

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Which compounds will undergo decarboxylation upon heating? Which compounds will undergo decarboxylation upon heating?

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The self condensation of Acetyl-CoA to Acetoacetyl-CoA is a Claisen reaction.

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The major product of the following sequence of reactions is

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The major product of the following reaction between acetone and ethyl benzoate (1:1 ratio) is? The major product of the following reaction between acetone and ethyl benzoate (1:1 ratio) is?

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Order the molecules according to decreasing acidity. Order the molecules according to decreasing acidity.

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Which is the product of the reaction of ethyl 3-phenylpropanoate with 1) sodium ethoxide, 2) aqueous Sodium hydroxide, 3) aqueous hydrochloric acid, and 4) heat? Which is the product of the reaction of ethyl 3-phenylpropanoate with 1) sodium ethoxide, 2) aqueous Sodium hydroxide, 3) aqueous hydrochloric acid, and 4) heat?

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What is the main product of the following reaction sequence? What is the main product of the following reaction sequence?

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The major product of the following reaction is The major product of the following reaction is

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Which of the following compounds can be used in an aldol self reaction to make a product with 5 or more carbon atoms? I. ethanal II. propanone (acetone) III. benzaldehyde IV. acetophenone

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Which is the major product of the following series of reactions? Which is the major product of the following series of reactions?    Which is the major product of the following series of reactions?

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The Michael addition of dimethylamine and 3-buten-2-one produces the following product The Michael addition of dimethylamine and 3-buten-2-one produces the following product

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Which is the major product formed in the following reaction? Which is the major product formed in the following reaction?

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The starting material that completes the following reaction is, The starting material that completes the following reaction is,

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What is the main product of the following reaction sequence? What is the main product of the following reaction sequence?

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Acetone reacts with 2 equivalents of molecular bromine (Br2) in aqueous solution in the presence of sulfuric acid. What is the major product of this reaction sequence?

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What is the starting material of this reaction? What is the starting material of this reaction?

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What is the main product of the following reaction sequence? What is the main product of the following reaction sequence?

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Which ester is likely to undergo a Claisen condensation to give this product? Which ester is likely to undergo a Claisen condensation to give this product?

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Which pair of esters is most likely to provide a useful Claisen synthesis?

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