Exam 16: Aqueous Ionic Equilibrium

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A solution is prepared by dissolving 0.23 mol of benzoic acid and 0.27 mol of sodium benzoate in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution.The Ka of benzoic acid is 1.36 × 10-3.

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When titrating a strong monoprotic acid and KOH at 25°C,the

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Match the following. -pH > 7

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A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH.Determine the pH of the solution before the addition of any KOH.The Ka of HF is 3.5 × 10-4.

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A 25.0-mL sample of 0.150 M hydrazoic acid is titrated with a 0.150 M NaOH solution.What is the pH after 13.3 mL of base is added? The Ka of hydrazoic acid is 1.9 × 10-5.

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A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution after the addition of 50.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.

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If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.11,which of the following is true?

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A 100.0 mL sample of 0.10 M Ca(OH)2 is titrated with 0.10 M HBr.Determine the pH of the solution after the addition of 100.0 mL HBr.

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Which of the following solutions is a good buffer system?

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A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH.Determine the pH of the solution after the addition of 30.0 mL of LiOH.

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What is the pH of a buffer solution that is 0.255 M in hypochlorous acid (HClO)and 0.333 M in sodium hypochlorite? The Ka of hypochlorous acid is 3.8 × 10-8.

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Define a complex ion

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What is the molar solubility of barium fluoride (BaF2)in water? The solubility-product constant for BaF2 is 1.7 × 10-6 at 25°C.

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Calculate the pH of a buffer that is 0.058 M HF and 0.058 M LiF.The Ka for HF is 3.5 × 10-4.

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Define buffer capacity.

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An aqueous solution of 0.01 M NaCl and 0.01 M AgNO3 are mixed.Which statement is true? (Ksp of AgCl = 1.8 × 10-10)

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Calculate the percent ionization of nitrous acid in a solution that is 0.249 M in nitrous acid.The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 100.0 mL of 0.20 M NH3.The Kb for NH3 is 1.8 × 10-5.

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What is the molar solubility of AgCl in 0.30 M NH3? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(NH3)2+ is 1.7 × 107.

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Determine the molar solubility of Co3(AsO4)2 in pure water.Ksp (Co3(AsO4)2)= 6.80 × 10-29.

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