Exam 16: Aqueous Ionic Equilibrium

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A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in LiF.Calculate the pH of the solution after the addition of 0.150 moles of solid LiOH.Assume no volume change upon the addition of base.The Ka for HF is 3.5 × 10-4.

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What is the pH at the equivalence point of a weak base-strong acid titration if 20.00 mL of NaOCl requires 28.30 mL of 0.50 M HCl? Ka = 3.0 × 10-8 for HOCl.

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Which solution is a buffer?

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Which of the following compounds solubility will not be affected by a low pH in solution?

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Match the following. -pH < 7

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Give the expression for the solubility product constant for Cr2(CO3)3.

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A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH.Determine the pH of the solution after the addition of 100.0 mL of KOH.The Ka of HF is 3.5 × 10-4.

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What is the pH of a solution made by mixing 25.00 mL of 0.100 M HCl with 40.00 mL of 0.100 M KOH? Assume that the volumes of the solutions are additive.

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Which of the following is true?

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Determine the molar solubility of Fe(OH)2 in pure water.Ksp (Fe(OH)2)= 4.87 × 10-17.

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What is the [CH3CO2-]/[CH3CO2H] ratio necessary to make a buffer solution with a pH of 4.34? Ka = 1.8 × 10-5 for CH3CO2H.

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A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution before the addition of any HNO3.The Kb of NH3 is 1.8 × 10-5.

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Formic acid (HCO2H,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the formic acid solution requires 29.80 mL of 0.0567 M NaOH to reach the equivalence point?

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Calculate the Ksp of Fe2S3 in pure water.The molar solubility is 1.05 × 10-18.

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If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.74,which of the following is true?

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A solution contains 3.8 × 10-2 M in Al3+ and 0.29 M in NaF.If the Kf for AlF63- is 7 × 1019,how much aluminum ion remains at equilibrium?

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Which of the following compounds will have the highest molar solubility in pure water?

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous hydrofluoric acid requires 30.00 mL of 0.400 M NaOH? Ka = 6.76 × 10-4 for HF.

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Determine the molar solubility of BaF2 in a solution containing 0.0750 M LiF.Ksp (BaF2)= 1.7 × 10-6.

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Which of the following solutions is a good buffer system?

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