Exam 16: Aqueous Ionic Equilibrium

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A solution is prepared by dissolving 0.23 mol of hydrazoic acid and 0.27 mol of sodium azide in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of NaOH to this buffer solution causes the pH to increase slightly.The pH does not increase drastically because the NaOH reacts with the ________ present in the buffer solution.The Ka of hydrazoic acid is 1.9 × 10-5.

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Calculate the percent ionization of nitrous acid in a solution that is 0.222 M in nitrous acid (HNO2)and 0.278 M in potassium nitrite (KNO2).The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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Which metal hydroxide is most soluble in water?

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A 1.00 L buffer solution is 0.250 M in HF and 0.250 M in NaF.Calculate the pH of the solution after the addition of 100.0 mL of 1.00 M HCl.The Ka for HF is 3.5 × 10-4.

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Which of the following solutions is a good buffer system?

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Which one of the following statements is true?

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What is the hydronium ion concentration in a solution prepared by mixing 50.00 mL of 0.10 M HCN with 50.00 mL of 0.030 M NaCN? Assume that the volumes of the solutions are additive and that Ka = 4.9 × 10-10 for HCN.

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Which of the following compounds will have the highest molar solubility in pure water?

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Determine the molar solubility of AgI in pure water.Ksp (AgI)= 8.51 × 10-17.

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A buffer solution is 0.100 M in both HC7H5O2 and LiC7H5O2 and has a pH of 4.19.Which of the following pH values would you be most likely to see from the addition of a small amount of a dilute solution of a strong base?

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The molar solubility of CuI is 2.26 × 10-6 M in pure water.Calculate the Ksp for CuI.

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M HCHO2 with 100.0 mL of 0.20 M LiCHO2.The Ka for HCHO2 is 1.8 × 10-4.

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What is the molar solubility of Mg(OH)2 in a basic solution with a pH of 12.50? Ksp for Mg(OH)2 is 5.6 × 10-12.

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A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution after the addition of 150.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.

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Match the following. -pH = pKa

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What is the pH of a solution prepared by mixing 50.00 mL of 0.10 M methylamine,CH3NH2,with 20.00 mL of 0.10 M methylammonium chloride,CH3NH3Cl? Assume that the volume of the solutions are additive and that Kb = 3.70 × 10-4 for methylamine.

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Explain the common ion effect with respect to molar solubility.

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Which buffer controls the pH of blood?

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What volume of 5.00 × 10-3 M HNO3 is needed to titrate 80.00 mL of 5.00 × 10-3 M Ca(OH)2 to the equivalence point?

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A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH.Determine the pH of the solution after the addition of 100.0 mL of LiOH.

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