Exam 17: Additional Aspects of Aqueous Equilibria

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A 25.0 mL sample of 0.723 M HClO4 is titrated with a 0.273 M KOH solution. The H3O+ concentration after the addition of 60.0 mL of KOH is __________ M.

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C

Of the following solutions, which has the greatest buffering capacity?

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B

Suppose you have just added 100.0 ml of a solution containing 0.5000 moles of acetic acid per liter to 400.0 ml of 0.5000 M NaOH. What is the final pH? The Ka of acetic acid is 1.77 × 10-5.

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13.48

In which one of the following solutions is silver chloride the most soluble?

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Calculate the pH of a solution prepared by dissolving 0.150 mol of acetic acid and 0.300 mol of sodium acetate in water sufficient to yield 1.00 L of solution. The Ka of acetic acid is 1.76 × 10-5.

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Of the following solutions, which has the greatest buffering capacity?

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Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO2)and 0.290 M in potassium nitrite (KNO2). The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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A 25.0 mL sample of 0.150 M hypochlorous acid is titrated with a 0.150 M NaOH solution. What is the pH after 26.0 mL of base is added? The Ka of hypochlorous acid is 3.0 × 10-8.

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In which of the following aqueous solutions would you expect CuBr to have the highest solubility?

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The concentration of fluoride ions in a saturated solution of barium fluoride is __________ M. The solubility product constant of BaF2 is 1.7 × 10-6.

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The pH of a solution prepared by dissolving 0.350 mol of solid dimethylamine hydrochloride ((CH3)2NH2Cl)in 1.00 L of 1.10 M dimethylamine ((CH3)2NH)is __________. The Kb for methylamine is 5.40 × 10-4. (Assume the final volume is 1.00 L.)

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The Kb of ammonia is 1.76 × 10-5. The pH of a buffer prepared by combining 50.0 mL of 1.00 M ammonia and 50.0 mL of 1.00 M ammonium nitrate is __________.

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A solution containing which one of the following pairs of substances will be a buffer solution?

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Why does fluoride treatment render teeth more resistant to decay?

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The addition of hydrofluoric acid and __________ to water produces a buffer solution.

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Calculate the percent ionization of formic acid (HCO2H)in a solution that is 0.311 M in formic acid and 0.189 M in sodium formate (NaHCO2). The Ka of formic acid is 1.77 × 10-4.

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The pH of a solution that contains 0.818 M acetic acid (Ka = 1.76 × 10-5)and 0.182 M sodium acetate is __________.

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For which salt should the aqueous solubility be most sensitive to pH?

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Human blood is __________.

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What is the molar solubility of silver sulfate (Ag2SO4)in water? The solubility-product constant for Ag2SO4 is 1.5 × 10-5 at 25°C.

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