Exam 4: Acids and Bases

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Provide a brief explanation, based on features of the molecules, for the following trend in pKa values? CH3CH3 > CH2=CH2 > HCCH ethane ethene ethyne (ethylene) (acetylene) 51 44 25

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Which of the following is present in the highest concentration upon dissolution of H2SO4 in water?

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Which of the following is a feature of a Brønsted-Lowry base?

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Which of the following is a feature of a Brønsted-Lowry acid?

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Which of the following is the strongest base?

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Which of the following is the strongest base?

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Which of the following is a definition of the activation energy of a reaction?

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What is the value of the equilibrium constant for the following equilibrium? What is the value of the equilibrium constant for the following equilibrium?

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Which of the following has a pKa value of approximately 16?

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Which of the following energy diagrams best represents the changes in energy during addition of HBr to an alkene? Which of the following energy diagrams best represents the changes in energy during addition of HBr to an alkene?

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Which of the following is the strongest acid?

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An acid with a low pKa is a strong acid and has a weak conjugate base.

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Which of the following concepts can be used to rationalize the observation that acetic acid is a stronger acid than methanol?

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Which of the following is a feature of a Lewis base?

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Which of the following compounds is the strongest acid?

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Consider the following reaction coordinate diagram. Consider the following reaction coordinate diagram.   This reaction is endergonic. This reaction is endergonic.

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Provide a brief explanation, based on features of the molecules, for the following trend in pKa values? CH3CH2OH > CF3CH2OH ethanol 2,2,2-trifluoromethanol 15.9 12.4

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Which of the following compounds is the strongest acid?

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Provide a brief explanation, based on features of the molecules, for the following trend in pKa values? CH3CH2OH > CH3COOH 15.9 4.76

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Which of the following compounds is the strongest acid?

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