Exam 10: Elimination Reactions of Alkyl Halides Competition Between Substitution and Elimination

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Which of the following is least likely to be found in the product mixture which results when the alkyl iodide below is heated in water? Which of the following is least likely to be found in the product mixture which results when the alkyl iodide below is heated in water?    Which of the following is least likely to be found in the product mixture which results when the alkyl iodide below is heated in water?

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Supply the missing alkyl halide reactant in the elimination reactions shown below. Supply the missing alkyl halide reactant in the elimination reactions shown below.

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What mechanism predominates in the reaction below? What mechanism predominates in the reaction below?

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Which of the following statements correctly describe(s)E1 reactions of alkyl halides (RX)? I. Rate = k[base] II. Rate = k[base][RX] III. Rate = k[RX] IV. The reactions occur in two distinct steps. V. Rearrangements are sometimes seen.

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List the following compounds in order of increasing reactivity in an E1 elimination. CH3CH2CHBrCH3, CH3CH2CH2CH2Br, (CH3)3CBr

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Provide the major organic product(s)in the reaction below. Provide the major organic product(s)in the reaction below.

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Which of the following are the elimination products of the reaction shown below? CH3CH2Br + -OH → ?

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What is the major product of the following E2 reaction? What is the major product of the following E2 reaction?

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Which of the following statements is true concerning the E2 reactions of alkyl fluorides?

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What is/are the product(s)of the following reaction? What is/are the product(s)of the following reaction?

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Give the major product for the following E1 reaction. Give the major product for the following E1 reaction.

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Which of the following is least likely to be found in the product mixture which results when 2-iodopentane reacts with sodium ethoxide in ethanol?

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What reaction mechanism predominates when 1-bromo-1-propylcyclopentane is heated in ethanol?

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What is the major product of the following reaction? What is the major product of the following reaction?

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A primary kinetic isotope effect could most likely be observed in which of the following mechanisms?

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What is the major product of the following reaction? What is the major product of the following reaction?

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Which of the following alkyl halides undergoes E1 reactions with the fastest rate?

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Give the major product for the E2 reaction. Give the major product for the E2 reaction.

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Provide the structure of the major organic product which results when 2-bromo-2-methylbutane is treated with sodium ethoxide.

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Which of the following halides is most reactive in an E2 reaction with sodium methoxide?

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